Cashew phenol modified phenolic resin and method for manufacturing paper-based laminated board
A technology of cashew nut phenol and phenolic resin, which is applied in the production of copper-clad laminates and paper-based laminates. It can solve the problems of not being suitable for lead-free reflow soldering and unsatisfactory performance, and achieve excellent punching and drilling processability. Excellent workability and low water absorption
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specific Embodiment 1
[0025] Put in a 1000 ml three-necked flask successively: 100 grams of phenol, 75 grams of cardanol, 120 grams of formaldehyde (37%), 1.5 grams of ammonia (25%), and 1 gram of triethylamine. Then the temperature is raised to 80-90°C to react for 1-2 hours, the gelation time is controlled to 100-160 seconds / 160±5°C, and then dehydration under reduced pressure. Add a proper amount of methanol to dissolve, and obtain a modified phenolic resin with a solid content of 50-52%. Then used to impregnate 127g / m 2 The bleached wood pulp paper is dried to obtain a prepreg with a glue content of 48-52%. Combine 8 prepregs and 1 rubber-coated copper foil, and press for 1 hour at a temperature of 155±5°C and a unit pressure of 10-12 mpa to obtain a 1.6mm paper-based copper clad laminate, which is used as sample 1. Then test according to the national standard GB / T4723-1992.
specific Embodiment 2
[0026] Put 100 grams of phenol, 100 grams of cashew phenol, 150 grams (37%) of formaldehyde, 1.5 grams (25%) of ammonia water, and 1 gram of triethylamine into a 1,000-ml three-necked flask, and operate according to the process of specific example 1. Get sample 2. Test according to the same standard.
specific Embodiment 3
[0027] Put 100 grams of phenol, 150 grams of cashew phenol, 180 grams (37%) of formaldehyde, 1.5 grams (25%) of ammonia water, and 1.2 grams of triethylamine into a 1,000-ml three-necked flask, and proceed according to the process of specific embodiment 1. Get sample 3. Test according to the same standard.
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