Highly heat conductive polyphenylene sulfide composite material and method for making same
A technology of polyphenylene sulfide and composite materials, which is applied in the field of polymer materials, can solve the problems of no composite materials, achieve high thermal conductivity, excellent physical and mechanical properties, and simple preparation process
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[0022] A preparation method of a high thermal conductivity polyphenylene sulfide composite material, comprising the steps of:
[0023] a: Add 0.5-2.5% of the coupling agent by mass to the heat-conducting agent weighed according to the mass ratio for surface treatment, the treatment temperature is 30-70°C, and the treatment time is 5-15 minutes;
[0024] b: Weigh the polyphenylene sulfide resin according to the weight ratio, and put it into the high-speed mixer together with the treated heat-conducting agent and other additives for 3-5 minutes;
[0025] c: Put the mixed raw materials in b into the feeding hopper of the twin-screw extruder, the glass fiber is added from the glass fiber port, melted and extruded, and granulated; the processing technology is as follows: the temperature in the first zone of the twin-screw extruder is 265- 290°C, the temperature of the second zone is 265-300°C, the temperature of the third zone is 265-300°C, the temperature of the fourth zone is 265...
Embodiment 1
[0027] Firstly, 100 parts of copper powder of heat conduction agent were treated with 2 parts of coupling agent, and then 100 parts of PPS, 50 parts of glass fiber and 0.5 parts of other additives were weighed. The mixed material is put into the hopper of the twin-screw extruder, melted and blended, extruded and granulated to form a composite material. Among them, the temperature settings of each heating zone of the screw are: zone 1 temperature: 270°C; zone 2: 285°C; zone 3: 285°C; zone 4: 290°C; head: 285°C; residence time 2-3min. The pressure is 15MPa.
Embodiment 2
[0029] Firstly, 100 parts of thermal conductive graphite are treated with 2 parts of coupling agent, and then 100 parts of PPS, 50 parts of glass fiber, and 0.5 parts of other additives are weighed. The mixed material is put into the hopper of the twin-screw extruder, melted and blended, extruded and granulated to form a composite material. Among them, the temperature settings of each heating zone of the screw are: zone 1 temperature: 270°C; zone 2: 285°C; zone 3: 285°C; zone 4: 290°C; head: 285°C; residence time 2-3min. The pressure is 15MPa.
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