MgO-SiC-C material synthesized by forsterite-C and method for preparing same

A technology of forsterite and olivine mineral powder, which is applied in the field of MgO-SiC-C material and its preparation, can solve the problems affecting the high-temperature strength and erosion resistance of materials, the shortage of magnesia resources, and the increase of production cost, and achieve Excellent anti-slag performance, solve the shortage of resources, and prolong the service life

Inactive Publication Date: 2008-11-19
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The existing production and preparation method of MgO-SiC-C composite material is to use magnesia and industrial SiC as the main raw materials, use phenolic resin as the binder, adopt mechanical mixing and then be produced by pressure mechanical pressing (such as ZL200610019553.7 ), the advantage of this type of method is to replace graphite (C) with industrial SiC to ensure the corrosion resistance and thermal shock resistance of the material. The problem is that magnesia resources are becoming increasingly scarce, and the market prices of magnesia and industrial SiC are getting higher and higher , the production cost of MgO-SiC-C composite materials is also continuously increasing; in addition, MgO and SiC are combined by phenolic resin, and the bonding effect of phenolic resin at high temperature is poor, which affects the high temperature strength and erosion resistance of the material

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0014] A method for preparing a forsterite-C synthesized MgO-SiC-C material. First mix 1-1.3mol of forsterite ore powder and 3-3.5mol of C powder according to the molar ratio, add 7-8wt% sodium lignosulfonate and calcium sulfonate of the above-mentioned mixture and prepare an aqueous solution, stir for 10 ~30 minutes, and then dried at 60~90°C for 18~24 hours after compression molding. Then sinter in reducing atmosphere, the sintering temperature is 1680-1700°C, and the holding time is 3-4 hours to obtain MgO-SiC-C composite material.

[0015] Among them: the MgO content of the forsterite mineral powder is ≥38%, and the particle size is 0.2-0mm; the C content of the industrial carbon powder is ≥80%, and the particle size is 0.1-0mm.

Embodiment 2

[0017] A method for preparing a forsterite-C synthesized MgO-SiC-C material. Mix 1-1.5mol of forsterite ore powder and 3.5-4mol of C powder according to the molar ratio, add 7-7.8wt% sodium lignin sulfonate and calcium sulfonate of the above mixture and make it into an aqueous solution, mix and grind 10 to 30 minutes, and then dried at 60 to 90°C for 18 to 24 hours after compression molding. Then sinter in reducing atmosphere, the sintering temperature is 1650-1700°C, and the holding time is 2-3 hours, to obtain MgO-SiC-C composite material. All the other are with embodiment 1.

Embodiment 3

[0019] A method for preparing a forsterite-C synthesized MgO-SiC-C material. First mix 1-1.5mol of forsterite ore powder and 4-4.5mol of C powder according to the molar ratio, add 8-9wt% sulfurous acid pulp waste liquid of the above-mentioned mixture and make it into an aqueous solution, and mix and grind for 10-30 minutes , After being pressed and formed, it is naturally dried indoors for 24 to 36 hours. Then sintering in a reducing atmosphere, the sintering temperature is 1500-1550°C, and the holding time is 6-7 hours to obtain a MgO-SiC-C composite material. All the other are with embodiment 1.

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Abstract

The invention relates to an MgO-SiC-C material synthesized by forsterite and C and a method for making the same. The method adopts the following technical proposal that: according to molar ratio, 1 to 4 mol of forsterite mineral powder and 3 to 6 mol of C powder are mixed, and a bonding agent occupying 4 to 10 percent of the mass percentage content of the mixed materials is added; the mixture is stirred or ground for 10 to 30 minutes, and is dried after press forming; then, sintering is carried out under a reducing atmosphere at a temperature of between 1,450 and 1,700 DEG C with the heat preservation time of between 2 and 8 hours, thereby obtaining an MgO-SiC-C composite material. The industrial carbon powder raw material adopted by the method has wide sources, and the forsterite mine has abundant resources, thereby not only effectively solving the problem of magnesia resource shortage, but also having low production cost; moreover, the made MgO-SiC-C composite material can maintain excellent properties and reduce corrosion wear, thereby prolonging service life.

Description

technical field [0001] The present invention belongs to forsterite (2MgO·SiO 2 ), industrial carbon powder (C) as the composite material field of base material, especially relate to a kind of MgO-SiC-C material synthesized with forsterite and C and its preparation method. Background technique [0002] MgO-SiC-C composite materials have excellent high temperature resistance and thermal stability, can be used in non-ferrous metals and iron and steel smelting equipment, and can also be prepared into high-quality high temperature resistant heat insulation materials and wall materials for high temperature kilns, especially It is suitable for the ladle lining and refining furnace lining of clean steel such as low carbon steel and ultra-low carbon steel, replacing MgO-C material, which is beneficial to the quality of steel and has a good use effect. [0003] The existing production and preparation method of MgO-SiC-C composite material is to use magnesia and industrial SiC as the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/66
Inventor 祝洪喜邓承继白晨
Owner WUHAN UNIV OF SCI & TECH
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