Sialon complex phase ceramic lift tube and production method thereof

A technology of composite ceramics and riser tubes, which is applied in the field of ceramic materials and preparation of riser tubes, can solve the problems of online service life of only ten days, no mass production, oxidation-reduction reaction, etc., and achieve stable and reliable product performance, Easy to operate, simple process effect

Inactive Publication Date: 2009-04-15
DONGYING XINKEXINTETAO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, most of the risers in China are quartz riser tubes and aluminum titanate riser tubes. Due to their own materials, the riser tubes of these two types of materials are easy to crystallize or undergo oxidation-reduction reactions with aluminum solutions at high temperatures, thus As a result, the online service life is only more than ten days, and the longest is only more than one month
For a long time, domestic research on liquid risers has focused on how to improve the performance and service life of aluminum titanate, and for the development of other high-performance materials, there are only a few domestic research institutes conducting research, such as the development of Northwestern Polytechnical University. The reaction sintered silicon nitride combined with silicon carbide riser has made some progress, but has not yet been mass-produced

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0010] Embodiment 1, the composition of the raw materials of the multiphase ceramic riser and the percentages by weight of various raw materials are: 35% silicon nitride, 20% quartz, 14% aluminum dioxide, 0.05% yttrium oxide, 25% silicon carbide, zirconia 5.2%, acrylamide 0.048%, N,N'-methylenebisacrylamide 0.002%, polymethacrylamine 0.6%, persulfate ammonium 0.1%.

Embodiment 2

[0011] Embodiment 2, the raw material composition of the multiphase ceramic riser and the weight percentages of various raw materials are: silicon nitride 40%, quartz 18%, aluminum dioxide 10%, yttrium oxide 0.05, silicon carbide 25, zirconia 6.2% , Acrylamide 0.048%, N, N'-methylenebisacrylamide 0.002%, polymethacrylic acid amine 0.6%, persulfate amine 0.1%.

[0012] On the basis of the above-mentioned raw material ratio, the ceramic liquid riser with higher performance can be produced by using the existing preparation method through the processes of wet ball milling, injection molding, curing, mold releasing, drying and firing.

Embodiment 3

[0013] Example 3, for the raw material composition of Example 1, the preparation method of the multi-phase ceramic riser is to adopt the near-net size injection molding process, and go through the wet ball milling, injection molding, curing, demoulding, drying and firing processes be made of. Among them: wet ball milling is to add deionized water, acrylamide and N, N'-methylenebisacrylamide in the ball mill in advance as a premixed solution, wherein the amount of deionized water added accounts for 30% by weight of all raw materials, and then Add silicon nitride, quartz and yttrium oxide and ball mill for 3-5 hours, then add aluminum dioxide, silicon carbide and zirconia for ball milling, the total time of ball milling is 15-30 hours. The particle size detected after grinding is <3.0 microns. Injection molding is to put the ball-milled slurry into a vacuum mixer, add ammonium persulfate, vacuumize, remove the gas, and then use a vacuum mixer to inject it into the mold under a ...

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Abstract

The invention relates to a sialon composite ceramic lift tube and a preparation method thereof. The weight percents of the raw materials forming the composite ceramic lift tube are: 25-50 percent of silicon nitride, 15-30 percent of quartz, 5-20 percent of aluminum dioxide, 0.01-0.1 percent of yttria, 20-40 percent of carborundum, 1-10 percent of zirconia, 0.01-0.06 percent of acrylamide, 0.001-0.005 percent of N, N'-methylenebisacrylamide, 0.1-0.7 percent of polymethacrylic acid amine and 0.05-0.2 percent of ammonium persulfate. The preparation method comprises: adding pre-mix liquid to a ball mill in advance, adding the silicon nitride, the quartz, the yttria, the aluminum dioxide, the carborundum and zirconia in sequence and ball-milling for 15-30 hours; adding the ammonium persulfate to the sizing agent, vacuumizing by a vacuum agitator and injecting into a mold to be solidified; demolding, drying and sintering at the temperature of 1300-1600 DEG C to obtain the finished product. The sialon composite ceramic lift tube is characterized by long service life, high strength, strong thermal shock resistance and low cost, which is not infiltrated or reacted with aluminum melt.

Description

Technical field: [0001] The present invention relates to the field of liquid riser ceramic materials and preparation methods, in particular to a Sailong composite ceramic liquid riser (also known as Sailong complex phase ceramic liquid riser) and a preparation method, and its products are mainly used in the production of vehicles with high quality and safety Key components on low-pressure casting machines for structural parts (such as hubs, running parts, etc.) and engine structural parts (especially parts for automobiles and motorcycles). Background technique: [0002] In the 1960s, with the introduction of the concept of ceramic engines, countries around the world researched and developed new ceramic materials, and a large number of high-performance structural ceramic materials emerged, which are widely used in civil and industrial industries such as metallurgy, chemical industry, automobiles, and aerospace. and military fields. With the development of the automobile indu...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/599C04B35/622
Inventor 程之勇扈云强任子文袁海燕谭立英程志兰
Owner DONGYING XINKEXINTETAO
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