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Bicomponent terminal mercapto polyurethane mildewproof sealant and preparation thereof

A polyurethane and sealant technology, used in polyurea/polyurethane adhesives, chemical instruments and methods, adhesives, etc., can solve the problems of sealant molecular structure erosion, breeding of mold sealing effect, loss of sealing effect, etc., and achieve production costs. Low, good sealing and anti-mildew effect, excellent mechanical properties

Inactive Publication Date: 2009-05-20
HENAN YONGLI CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, most of the research on anti-mold of sealants is concentrated in the fields of aircraft, ships, electronics, machinery, etc., but it is easy to breed mold when used in water conservancy projects, water delivery projects, sewage treatment projects, etc. Anti-mildew sealant products that require extremely high sealing effects are rarely reported
If the sealant used in these fields does not have anti-mold function, it is easy to breed mold, and the growth and spread of mold will erode the internal molecular structure of the sealant, cause degradation and deterioration, affect or even lose the sealing effect

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] Example 1: Two-component mercapto-terminated polyurethane anti-mold sealant and preparation method thereof

[0038] 1. Two-component mercapto-terminated polyurethane anti-mold sealant, including components A and B

[0039] A component: mercapto-terminated polyurethane liquid rubber 80kg, nano calcium carbonate 65kg, active heavy calcium carbonate 45kg, dibutyl phthalate 40kg, octyl phenolic tackifying resin 1.5kg, stearic acid 1.5kg, antioxidant AT-215 1.0kg, ultraviolet absorber UV-327 1.0kg, thiabendazole 1.5kg.

[0040] Component B: 80 kg of manganese dioxide, 30 kg of dibutyl phthalate, 50 kg of furnace carbon black, 40 kg of light calcium carbonate, and 1.5 kg of zinc dibutyl dithiocarbamate.

[0041] 2. The preparation method of two-component mercapto-terminated polyurethane anti-mold sealant, including the separate preparation of components A and B, the specific steps are as follows:

[0042] (1) Preparation of anti-fungal base rubber compound

[0043] Add the anti-m...

Embodiment 2

[0049] Example 2: Two-component mercapto-terminated polyurethane anti-mold sealant and preparation method thereof

[0050] 1. Two-component mercapto-terminated polyurethane anti-mold sealant, including components A and B,

[0051] Component A: 85kg of mercapto-terminated polyurethane liquid rubber, 17kg of nano calcium carbonate, 25kg of heavy calcium carbonate, 4kg of titanium dioxide, 30kg of dibutyl phthalate, 1.8kg of octyl phenolic tackifying resin, 2.1kg of stearic acid, Oxygen agent AT-215 1kg, ultraviolet absorber UV-328 1.0kg, thiabendazole 2.5kg.

[0052] Component B: 85 kg of manganese dioxide, 15 kg of dibutyl phthalate, 10 kg of butyl benzyl phthalate, 1.5 kg of zinc dibutyl dithiocarbamate, and 35 kg of light calcium carbonate.

[0053] 2. The preparation method of two-component mercapto-terminated polyurethane anti-mold sealant, including the separate preparation of components A and B, the specific steps are as follows:

[0054] (1) Preparation of anti-fungal base r...

Embodiment 3

[0061] Example 3: Two-component mercapto-terminated polyurethane anti-mold sealant and preparation method thereof

[0062] 1. Two-component mercapto-terminated polyurethane anti-mold sealant, including components A and B

[0063] Component A: Mercapto-terminated polyurethane liquid rubber 90kg, nano calcium carbonate 80kg, heavy calcium carbonate 90kg, dibutyl phthalate 45kg, chlorinated paraffin 5245kg, octyl phenolic tackifying resin 2.2kg, stearic acid 1.4kg , Antioxidant AT-215 1.4kg, UV absorber UV-328 1.1kg, 1,2 benzisothiazolin-3-one 3.5kg.

[0064] B component: manganese dioxide 90kg, chlorinated paraffin 52 55kg, butyl benzyl phthalate 90kg, tetramethylthiuram disulfide 1.8kg, active light calcium carbonate 65kg.

[0065] 2. The preparation method of two-component mercapto-terminated polyurethane anti-mold sealant, including the separate preparation of components A and B, the specific steps are as follows:

[0066] (1) Preparation of anti-fungal base rubber compound

[00...

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Abstract

The invention relates to a dual-component sulfhydryl-terminated polyurethane mildew-proof sealant and a preparation method thereof, wherein, the sealant consists of component A and component B, wherein, according to the parts by weight, the component A comprises 80-120 parts of sulfhydryl-terminated polyurethane liquid rubber, 20-200 parts of filling material, 10-100 parts of plasticizer, 0.5-10 parts of tackifier, 0.1-5 parts of mould inhibitor, 0-5 parts of vulcanization regulator, and 0-5 parts of antioxidant; the component B comprises 80-120 parts of vulcanizing agent, 20-150 parts of plasticizer, 20-200 parts of filling material, and 0-5 parts of vulcanization regulator; and the proportion of component A and component B is 10:0.5-2. The mildew-proof sealant has the tensile strength of 5.0MPa, breaking elongation rate of 1020 percent, the bonding strength with the concrete of 2.5MPa, and the mildew-proof level of being less than or equal to 1; the sealant can be used for the fields such as electrons, mechanicals, and the like, can meet the sealing and mildew-proof requirement under the conditions of long-term water immersion, damp-heat or other conditions where mildews are easy to breed, has no exhaust of three wastes and is friendly to environment.

Description

1. Technical Field: [0001] The invention relates to a sealing material, in particular to a two-component mercapto-terminated polyurethane anti-mold sealant and a preparation method thereof. 2. Background technology: [0002] Sealant is the abbreviation of sealing adhesive, and it is a multi-purpose functional material with both bonding and sealing properties. It can not only prevent internal gas or liquid leakage, but also prevent the intrusion of external dust, moisture, moisture, dirt and chemicals, and can prevent mechanical vibration, impact damage or achieve the effect of sound insulation and heat insulation. The sealant can deform with the shape of the sealing surface, is not easy to flow, and has a certain degree of adhesion. It is widely used in the sealing of civil engineering, electronic appliances, mechanical equipment, transportation equipment and other fields. Sealant is an indispensable and important material for solving running, emitting, dripping and leakage, and ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K3/10C09J175/04
Inventor 赵磊宋秋玲刘海超张丽娜万红云刘英豪
Owner HENAN YONGLI CHEM
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