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Method for producing cement clinker from coal gangue and metal tailing substituting clay ingredient

A technology for metal tailings and cement clinker, applied in the direction of cement production, etc., can solve the problems of high reaction activation energy, unfavorable clinker sintering, low melting point of metal tailings, ringing and crusting in the kiln, etc., to promote Ca- The effect of Si reaction, obvious energy saving and design yield improvement

Inactive Publication Date: 2012-03-21
ZHEJIANG UNIV
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Problems solved by technology

[0005] However, although most coal gangue and metal tailings can replace clay to produce cement clinker, for some coal gangue, which is an inert raw material, the reaction ability is low, and the high activation energy of reaction is not conducive to clinker firing.
The melting point of some metal tailings is too low, it is easy to make rings and crusts in the kiln, making it difficult to calcine

Method used

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  • Method for producing cement clinker from coal gangue and metal tailing substituting clay ingredient

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Embodiment 1

[0028] For 1000t / d rotary kiln, coal gangue and Zhejiang Zhuji copper-lead-zinc tailings are used instead of clay ingredients. The ratio of raw materials is: the sum of high-calcium limestone and low-calcium limestone is 89.6%, coal gangue is 5.2%, sulfuric acid slag is 1.2%, and copper-lead-zinc tailings are 4%. Grind first to make the raw meal fineness: 80μm sieve allowance is not more than 10%, and then make cement clinker at 1400-1450°C. The performance indicators are shown in Table 3. The heat consumption of the cement clinker produced by this method is reduced from 3250kJ / kg to 2930kJ / kg, which is a decrease of 9.85%, and the output of clinker is increased from 990t / d to 1090t / d, and the output is increased by 10%. . Moreover, the index is also improved compared with the time when coal gangue substitutes clay alone.

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Abstract

The invention discloses a method for producing cement clinker through coal slack and metal tailings instead of clay. The method comprises the following steps: preparing and milling crude materials; and then calcining the crude materials in a dry-process rotary kiln to form the cement clinker. The crude materials comprise the following components in percentage by weight: 85 to 90 percent of limestone, 1 to 2 percent of iron material, 3 to 8 percent of coal slack, and 2 to 5 percent of metal tailings. The metal tailings can be copper tailings, lead zinc tailings or copper lead zinc tailings. The method adopts the coal slack and the metal tailings instead of clay as the crude materials, and activates the reaction activity of the coal slack through the geologic potential of the tailings, thereby having the actions of mutual advantageous complementation. The method has easily obtained and cheap raw materials, easily mastered raw materials preparation, simple process, and obvious energy conservation. The clinker yield is improved by above 10 percent than the designed yield; and the raw material cost is reduced relatively by above 5 percent.

Description

(1) Technical field [0001] The present invention relates to a method for producing cement clinker. (2) Background technology [0002] my country's physical output of cement has ranked first in the world for 22 consecutive years since 1985. In 2007, the total output of cement reached 1.35 billion tons. Most of the cement industry uses high-grade limestone resources and high-quality clay as raw materials. Clay is the main silica-alumina raw material for cement production, and about 0.18 tons of clay are needed for one ton of cement production. Large-scale clay extraction in successive years has caused a large number of fields to be destroyed, forests have been destroyed, and the ecology has been threatened. The development of clay as a substitute raw material has become an urgent task for the cement industry. [0003] The mineral components of coal gangue are mainly kaolin, quartz, montmorillonite, and Yili stone, and the chemical composition is SiO 2 、Al 2 o 3 It account...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B7/36C04B7/24
CPCC04B7/22C04B7/24Y02P40/10
Inventor 施正伦余春江傅圣勇骆仲泱王勤辉王树荣邱坤赞俞寿苗杨国建倪明江
Owner ZHEJIANG UNIV