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Method for preparing pollution-proof surface material suitably applied in marine environment

A surface material, marine environment technology, applied in antifouling/underwater coatings, paints containing biocides, coatings, etc., can solve the problems of unsatisfactory antifouling effects such as diatoms, and achieve good antifouling effect, adhesion The effect of reducing the number of

Inactive Publication Date: 2009-09-16
725TH RES INST OF CHINA SHIPBUILDING INDAL CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chinese patent CN1392208 discloses a preparation method of a bionic antifouling coating made of alkaloids extracted from marine algae and peptide compounds extracted from sponge organisms and fluorine-containing resins. Experiments and trials of the coating have shown that its It is very effective in preventing the attachment and parasitism of shellfish organisms, but it is greatly affected by the environmental conditions during use
[0005] In summary, in the prior art, antifouling coatings containing organotin and cuprous oxide are generally banned or restricted due to environmental pollution, while the existence of low surface energy silicone antifouling coatings is only effective for barnacles, etc. Good antifouling effect, less than ideal antifouling effect on diatoms, etc.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Add 100ml of ethyl acetate / ethanol mixed solvent (volume ratio 6:4), 20g of acrylamide, 2g of polyvinylpyrrolidone, 3mg of azobisisobutyronitrile and vinyltriethoxysilane into a 250mL four-neck flask 1g, in N 2 Stir and heat to 65°C under protection to form a microemulsion and continue to react for 6 hours to obtain a uniformly dispersed milky white dispersion. The dispersion liquid is centrifuged with an ultracentrifuge to obtain polymer microspheres, washed with absolute ethanol and dried to obtain polyacrylamide microspheres. Then, add polyacrylamide microsphere 10g, ethanol 100ml, hydroxyl silicone oil 3g and 0.18g water successively in 250ml four-neck flask, adjust pH value to 2 with hydrochloric acid, in N 2 Stir and heat to 60°C under protection, and react for 3 hours. The reactant is centrifuged with an ultracentrifuge, washed and dried with absolute ethanol to obtain polyacrylamide microcapsules with a diameter between 5 μm and 30 μm.

[0018] 1 part by weig...

Embodiment 2

[0020] Add 100ml of ethyl acetate / ethanol mixed solvent (volume ratio 6:4), 40g of acrylamide, 8g of polyvinylpyrrolidone, 10mg of azobisisobutyronitrile and 1g of vinyltrimethoxysilane in a 250mL four-neck flask , stirred and heated to 65°C under the protection of N2 to form a microemulsion and continue to react for 6 hours to obtain a uniformly dispersed milky white dispersion. The dispersion liquid is centrifuged with an ultracentrifuge to obtain polymer microspheres, washed with absolute ethanol and dried to obtain polyacrylamide microspheres. Then, in a 250ml four-neck flask, add 20g of polyacrylamide microspheres, 100ml of ethanol, 5g of hydroxyl silicone oil and 0.3g of water successively, adjust the pH value to about 2 with hydrochloric acid, and 2 Stir and heat to 60°C under protection, and react for 3 hours. The reactant is centrifuged with an ultracentrifuge, washed and dried with absolute ethanol to obtain polyacrylamide microcapsules with a diameter between 5 μm ...

Embodiment 3

[0023] Add 100ml of ethyl acetate / ethanol mixed solvent (volume ratio 6:4), 30g of acrylamide, 6g of polyvinylpyrrolidone, 7mg of azobisisobutyronitrile and vinyltriethoxysilane into a 250mL four-neck flask 0.5g, in N 2 Stir and heat to 65°C under protection to form a microemulsion and continue to react for 6 hours to obtain a uniformly dispersed milky white dispersion. The dispersion liquid is centrifuged with an ultracentrifuge to obtain polymer microspheres, washed with absolute ethanol and dried to obtain polyacrylamide microspheres. Then, add polyacrylamide microspheres 10g, ethanol 100ml, hydroxyl silicone oil 1g and 0.1g water successively in a 250ml four-necked flask, adjust the pH value to 2 with hydrochloric acid, and 2 Stir and heat to 60°C under protection, and react for 3 hours. The reactant is centrifuged with an ultracentrifuge, washed and dried with absolute ethanol to obtain polyacrylamide microcapsules with a diameter between 5 μm and 30 μm.

[0024] 0.5 p...

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Abstract

The invention relates to a method for preparing a pollution-proof surface material suitably applied in the marine environment. The method comprises that: vinyl end capped dimethyl silicone polymer, hydrogen contained silicone oil, a platinum catalyst and polyacrylamide microcapsules are evenly mixed and stirred and sulfated at normal temperature to prepare the pollution-proof surface material of which hydrophilic surfaces and hydrophobic surfaces are distributed at intervals; the hydrophilic polyacrylamide microcapsules are evenly distributed on the material surfaces, and after the surface material is soaked in water, a local hydrophilic area with even distribution is formed, and the local hydrophilic area and the hydrophobic organic silicon surfaces are regularly distributed at intervals; polluted marine lives are not easy or not tight to be attached to the hydrophilic-hydrophobic surface, thereby preventing pollution; the pollution-proof surface material can strongly inhibit the attachment of marine lives such as diatom, mussels, and the like, and the attached quantity of mussel byssus is reduced by more than 50 percent; moreover, the surface material is environment friendly, nontoxic and unharmful.

Description

Technical field: [0001] The invention relates to a preparation method of an antifouling surface material suitable for marine environments, in particular to a preparation method of an amphiphilic antifouling material with a hydrophilic and hydrophobic surface interval distribution. The invention belongs to the technical field of protection against marine biological fouling. Background technique: [0002] There are a large number of marine organisms in seawater, and these marine organisms will adhere to the surfaces of ships and structures that have been in the seawater environment for a long time. This adhesion will increase the traveling resistance of the ship, seriously affect the sailing speed of the ship, increase fuel consumption, and at the same time damage the anti-corrosion coating on the surface of the ship and structures, thereby causing corrosion and damage on the surface of the hull and structures, seriously affecting its security. Therefore, it is very importan...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D183/04C09D133/26C09D5/16
Inventor 蔺存国张金伟
Owner 725TH RES INST OF CHINA SHIPBUILDING INDAL CORP
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