Method for preparing pollution-proof surface material suitably applied in marine environment
A surface material, marine environment technology, applied in antifouling/underwater coatings, paints containing biocides, coatings, etc., can solve the problems of unsatisfactory antifouling effects such as diatoms, and achieve good antifouling effect, adhesion The effect of reducing the number of
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Embodiment 1
[0017] Add 100ml of ethyl acetate / ethanol mixed solvent (volume ratio 6:4), 20g of acrylamide, 2g of polyvinylpyrrolidone, 3mg of azobisisobutyronitrile and vinyltriethoxysilane into a 250mL four-neck flask 1g, in N 2 Stir and heat to 65°C under protection to form a microemulsion and continue to react for 6 hours to obtain a uniformly dispersed milky white dispersion. The dispersion liquid is centrifuged with an ultracentrifuge to obtain polymer microspheres, washed with absolute ethanol and dried to obtain polyacrylamide microspheres. Then, add polyacrylamide microsphere 10g, ethanol 100ml, hydroxyl silicone oil 3g and 0.18g water successively in 250ml four-neck flask, adjust pH value to 2 with hydrochloric acid, in N 2 Stir and heat to 60°C under protection, and react for 3 hours. The reactant is centrifuged with an ultracentrifuge, washed and dried with absolute ethanol to obtain polyacrylamide microcapsules with a diameter between 5 μm and 30 μm.
[0018] 1 part by weig...
Embodiment 2
[0020] Add 100ml of ethyl acetate / ethanol mixed solvent (volume ratio 6:4), 40g of acrylamide, 8g of polyvinylpyrrolidone, 10mg of azobisisobutyronitrile and 1g of vinyltrimethoxysilane in a 250mL four-neck flask , stirred and heated to 65°C under the protection of N2 to form a microemulsion and continue to react for 6 hours to obtain a uniformly dispersed milky white dispersion. The dispersion liquid is centrifuged with an ultracentrifuge to obtain polymer microspheres, washed with absolute ethanol and dried to obtain polyacrylamide microspheres. Then, in a 250ml four-neck flask, add 20g of polyacrylamide microspheres, 100ml of ethanol, 5g of hydroxyl silicone oil and 0.3g of water successively, adjust the pH value to about 2 with hydrochloric acid, and 2 Stir and heat to 60°C under protection, and react for 3 hours. The reactant is centrifuged with an ultracentrifuge, washed and dried with absolute ethanol to obtain polyacrylamide microcapsules with a diameter between 5 μm ...
Embodiment 3
[0023] Add 100ml of ethyl acetate / ethanol mixed solvent (volume ratio 6:4), 30g of acrylamide, 6g of polyvinylpyrrolidone, 7mg of azobisisobutyronitrile and vinyltriethoxysilane into a 250mL four-neck flask 0.5g, in N 2 Stir and heat to 65°C under protection to form a microemulsion and continue to react for 6 hours to obtain a uniformly dispersed milky white dispersion. The dispersion liquid is centrifuged with an ultracentrifuge to obtain polymer microspheres, washed with absolute ethanol and dried to obtain polyacrylamide microspheres. Then, add polyacrylamide microspheres 10g, ethanol 100ml, hydroxyl silicone oil 1g and 0.1g water successively in a 250ml four-necked flask, adjust the pH value to 2 with hydrochloric acid, and 2 Stir and heat to 60°C under protection, and react for 3 hours. The reactant is centrifuged with an ultracentrifuge, washed and dried with absolute ethanol to obtain polyacrylamide microcapsules with a diameter between 5 μm and 30 μm.
[0024] 0.5 p...
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