Terpolymer oil soluble viscosity reducer for thick oil exploration and transportation and preparation method thereof
A technology of terpolymer oil and viscosity reducer, which is applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve the problems of shortage of thin oil resources, difficulty in mining, low viscosity reduction effect, etc., and achieve reduction in consumption , Good viscosity reduction effect, and the effect of improving affinity
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Embodiment 1
[0029] The preparation method of the terpolymer oil-soluble viscosity reducer that is used for heavy oil exploitation and transportation, it comprises the steps:
[0030] 1) According to acrylic acid: cetyl alcohol (C 16 Higher alcohol) molar ratio=1.1:1, p-toluenesulfonic acid addition is 0.5% of the total mass of acrylic acid and cetyl alcohol, the addition of hydroquinone is 0.3% of the total mass of acrylic acid and cetyl alcohol, choose acrylic acid 9.9% g, 30.3 g of cetyl alcohol, 0.2 g of p-toluenesulfonic acid, and 0.12 g of hydroquinone; add cetyl alcohol to a three-necked flask equipped with a thermometer, a mechanical stirrer and a reflux condenser, and heat to 60° C. All the hexaols were melted, then molecular sieves, hydroquinone, acrylic acid and p-toluenesulfonic acid were added in sequence, and the reaction was carried out at 110°C for 6 hours under stirring, and the reaction was completed; the molecular sieves were removed, and the unreacted acrylic acid was d...
Embodiment 2
[0037] The preparation method of the terpolymer oil-soluble viscosity reducer that is used for heavy oil exploitation and transportation, it comprises the steps:
[0038] 1) According to acrylic acid: stearyl alcohol (molar ratio) = 1.2: 1, the addition of naphthalenesulfonic acid is 0.6% of the total mass of acrylic acid and stearyl alcohol, and the addition of tert-butylcatechol is 0.6% of the total mass of acrylic acid and stearyl alcohol 0.4%, choose acrylic acid 10.8g, stearyl alcohol 33.8g, naphthalenesulfonic acid 0.27 and tert-butylcatechol 0.18g; Dissolve all stearyl alcohol at 65°C, then add molecular sieves, tert-butylcatechol, acrylic acid and naphthalenesulfonic acid in sequence, react at 120°C for 7 hours under stirring, and the reaction is complete; remove the molecular sieves, and evaporate unreacted acrylic acid under reduced pressure , to obtain a crude product, the crude product was washed with 7wt% sodium hydroxide solution until it was colorless, then repe...
Embodiment 3
[0045] The preparation method of the terpolymer oil-soluble viscosity reducer that is used for heavy oil exploitation and transportation, it comprises the steps:
[0046] 1) Acrylic acid: behenyl alcohol (molar ratio) = 1.4:1, the amount of benzenesulfonic acid added is 0.8% of the total mass of acrylic acid and behenyl alcohol, and the amount of hydroquinone added is the total amount of acrylic acid and behenyl alcohol 0.5% of the mass, choose 12.6g of acrylic acid, 40.8g of behenyl alcohol, 0.43g of benzenesulfonic acid and 0.27g of hydroquinone; add twenty-two Alcohol, heated to 70°C to dissolve all behenyl alcohol, then add molecular sieve, hydroquinone, acrylic acid and benzenesulfonic acid in sequence, under stirring, react at 130°C for 8 hours, and the reaction is completed; remove the molecular sieve, and distill under reduced pressure Remove unreacted acrylic acid to obtain a crude product, wash the crude product with 10wt% sodium hydroxide solution until it is colorl...
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