Terpolymer oil soluble viscosity reducer for thick oil exploration and transportation and preparation method thereof

A technology of terpolymer oil and viscosity reducer, which is applied in the direction of chemical instruments and methods, drilling compositions, etc., can solve the problems of shortage of thin oil resources, difficulty in mining, low viscosity reduction effect, etc., and achieve reduction in consumption , Good viscosity reduction effect, and the effect of improving affinity

Inactive Publication Date: 2010-09-08
CHINA UNIV OF GEOSCIENCES (WUHAN)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the existing oil-soluble viscosity reducers have low viscosity reduction effect and poor universality, and most of them are only used as fluidity improvers for heavy oil transportation
[0004] At present, in some oilfields in my country, such as Tahe Oilfield, the heavy oil not only has a very high content of heavy components such as colloids and asphaltene, it is a rare super heavy oil in China, but also has a well depth of more than 5,000 meters, which is extremely difficult to mine. The production methods of other shallow heavy oil reservoirs at home and abroad, such as steam huff and puff, steam flooding, SAGD, etc., are not suitable for the production of heavy oil, but compared with them, mixing thin oil in the wellbore to reduce viscosity is a suitable and effective production method , but with the increase of production scale and the increasing shortage of thin oil resources, it is very necessary to seek an oil-soluble viscosity reducer that can not only reduce the amount of thin oil added, but also meet the needs of heavy oil production.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] The preparation method of the terpolymer oil-soluble viscosity reducer that is used for heavy oil exploitation and transportation, it comprises the steps:

[0030] 1) According to acrylic acid: cetyl alcohol (C 16 Higher alcohol) molar ratio=1.1:1, p-toluenesulfonic acid addition is 0.5% of the total mass of acrylic acid and cetyl alcohol, the addition of hydroquinone is 0.3% of the total mass of acrylic acid and cetyl alcohol, choose acrylic acid 9.9% g, 30.3 g of cetyl alcohol, 0.2 g of p-toluenesulfonic acid, and 0.12 g of hydroquinone; add cetyl alcohol to a three-necked flask equipped with a thermometer, a mechanical stirrer and a reflux condenser, and heat to 60° C. All the hexaols were melted, then molecular sieves, hydroquinone, acrylic acid and p-toluenesulfonic acid were added in sequence, and the reaction was carried out at 110°C for 6 hours under stirring, and the reaction was completed; the molecular sieves were removed, and the unreacted acrylic acid was d...

Embodiment 2

[0037] The preparation method of the terpolymer oil-soluble viscosity reducer that is used for heavy oil exploitation and transportation, it comprises the steps:

[0038] 1) According to acrylic acid: stearyl alcohol (molar ratio) = 1.2: 1, the addition of naphthalenesulfonic acid is 0.6% of the total mass of acrylic acid and stearyl alcohol, and the addition of tert-butylcatechol is 0.6% of the total mass of acrylic acid and stearyl alcohol 0.4%, choose acrylic acid 10.8g, stearyl alcohol 33.8g, naphthalenesulfonic acid 0.27 and tert-butylcatechol 0.18g; Dissolve all stearyl alcohol at 65°C, then add molecular sieves, tert-butylcatechol, acrylic acid and naphthalenesulfonic acid in sequence, react at 120°C for 7 hours under stirring, and the reaction is complete; remove the molecular sieves, and evaporate unreacted acrylic acid under reduced pressure , to obtain a crude product, the crude product was washed with 7wt% sodium hydroxide solution until it was colorless, then repe...

Embodiment 3

[0045] The preparation method of the terpolymer oil-soluble viscosity reducer that is used for heavy oil exploitation and transportation, it comprises the steps:

[0046] 1) Acrylic acid: behenyl alcohol (molar ratio) = 1.4:1, the amount of benzenesulfonic acid added is 0.8% of the total mass of acrylic acid and behenyl alcohol, and the amount of hydroquinone added is the total amount of acrylic acid and behenyl alcohol 0.5% of the mass, choose 12.6g of acrylic acid, 40.8g of behenyl alcohol, 0.43g of benzenesulfonic acid and 0.27g of hydroquinone; add twenty-two Alcohol, heated to 70°C to dissolve all behenyl alcohol, then add molecular sieve, hydroquinone, acrylic acid and benzenesulfonic acid in sequence, under stirring, react at 130°C for 8 hours, and the reaction is completed; remove the molecular sieve, and distill under reduced pressure Remove unreacted acrylic acid to obtain a crude product, wash the crude product with 10wt% sodium hydroxide solution until it is colorl...

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Abstract

The invention relates to a terpolymer oil soluble viscosity reducer for thick oil exploration and transportation and a preparation method thereof. The terpolymer oil soluble viscosity reducer for thick oil exploration and transportation is characterized in that the viscosity reducer is prepared from methacrylate ester, N, N'- 2 (methacryloyloxyethyl) diamine, styrene, azobisisbutyronitrile and toluene, and the molar ratio of all the raw materials is as follows: methacrylate ester: N, N'- 2 (methacryloyloxyethyl) diamine: styrene is (4 to 5): (2 to 3): (2 to 4), the added amount of the azobisisbutyronitrile is 0.5 to 2 percent of the total mass of the methacrylate ester, the N, N'- 2 (methacryloyloxyethyl) diamine and the styrene, and toluene serves as the solvent; the methacrylate ester is prepared from acrylic acid, C16 to C22 higher alcohols, sulfoacid catalyst and phenolic inhibitor; and the N, N'- 2 (methacryloyloxyethyl) diamine is prepared from methyl acrylate and diamine. The oil soluble viscosity reducer has the advantages of good effect, strong universality, no pollution and relaxed use conditions, and can simultaneously meet the needs of thick oil exploration and transportation.

Description

technical field [0001] The invention relates to a terpolymer oil-soluble viscosity reducer for heavy oil exploitation and transportation and a preparation method thereof. Background technique [0002] Our country is rich in heavy oil resources and widely distributed, but there are still many problems in production technology such as heavy oil exploitation and gathering and transportation. The main reasons are high colloid and asphaltene content, high viscosity, high density and poor fluidity in heavy oil. [0003] Oil-soluble viscosity reducer can not only effectively reduce the freezing point and viscosity of heavy oil, loosen the structure of heavy oil, improve its fluidity, but also avoid post-processing problems caused by emulsification and viscosity reduction. Viscosity reduction with an agent is an effective method to solve the problems of heavy oil production and transportation. In recent years, the research on oil-soluble viscosity reducers at home and abroad has d...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/588C09K8/52C08F220/18
Inventor 陈艳玲王家松李海军
Owner CHINA UNIV OF GEOSCIENCES (WUHAN)
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