Novel low-shrinkage amino moulding compound and preparation method thereof

An amino molding compound and low shrinkage technology, which is applied in the field of new low shrinkage amino molding compound and its preparation, can solve the problems of prolonging the production cycle, large amount of addition, high cost, etc., to improve bending strength and impact strength, and improve flow sex, cheap effect

Active Publication Date: 2010-12-22
CHANGZHOU JOEL PLASTIC +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] (3) The internal stress caused by shrinkage causes the workpiece to gradually sag from the surface to the interior in a geometric manner, and the depression is gradually transmitted from the surface to the center of the workpiece to release the internal stress to achieve balance. The result of this release of internal stress leads to large shrinkage, Dimensional loss of control, such as warping and deformation
However, this low-shrinkage agent is added in a large amount (at least 20wt%), so the cost is high, and only dark and specific color products can be produced, and it is not suitable for the advanced production

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Amino molding compound (sample 1) was prepared according to the following raw material formula and process. The formula is:

[0033] Formulation of Table 1 Sample 1

[0034] raw material name

Dosage (parts by weight)

Urea

26

formaldehyde

51

Curing agent system

1.4

Melamine

0.4

Lubricants, Dispersants and Release Agents

1.2

pigment

0.2

filler

2.8

[0035] Cellulose

17

Alkyl isocyanate based elastomer

0

[0036] Preparation:

[0037] (1) Put the formaldehyde, urea, and curing agent system into the vertical reaction kettle in sequence according to the ratio of the above formula, control the temperature at 19°C to 22°C, and fully stir and react for 60 minutes to prepare the resin raw material slurry.

[0038] (2) Inject the raw material slurry into another reaction kettle through the pipeline, set the rotation speed of the stirring...

Embodiment 2

[0042] A new type of low-shrinkage amino molding compound (sample 2) was prepared according to the following raw material formula and process. The formula is:

[0043] Formulation of Table 2 Sample 2

[0044] raw material name

Dosage (parts by weight)

Urea

26

formaldehyde

50.8

Curing agent system

1.4

Melamine

0.4

Lubricants, Dispersants and Release Agents

1.1

pigment

0.2

filler

2.8

Cellulose

17

[0045] Alkyl isocyanate-based elastomer (38% solids)

0.3

[0046] Preparation:

[0047] (1) The preparation of resin raw material slurry is the same as in Example 1.

[0048] (2) The raw material slurry is injected into another reaction kettle through the pipeline, and the rotating speed of the stirring paddle is set to be 38rpm, and the pigment, lubricant, dispersant, mold release agent, alkyl isocyanate-based elastomer, melamine, Filling, fully...

Embodiment 3

[0051] A new type of low-shrinkage amino molding compound (sample 3) was prepared according to the following raw material formula and process. The formula is:

[0052] Formulation of Table 3 Sample 3

[0053] raw material name

Dosage (parts by weight)

Urea

25.7

formaldehyde

50.4

Curing agent system

1.5

Melamine

0.4

Lubricants, Dispersants and Release Agents

0.9

pigment

0.3

filler

2.8

Cellulose

16.8

Alkyl isocyanate-based elastomer (38% solids)

1.2

[0054] Preparation:

[0055] (1) The preparation of resin raw material slurry is the same as in Example 1.

[0056] (2) The raw material slurry is injected into another reaction kettle through the pipeline, and the rotating speed of the stirring paddle is set to be 42rpm, and the pigment, lubricant, dispersant, mold release agent, alkyl isocyanate-based elastomer, melamine, Filling, fully stirred for 2m...

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PUM

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Abstract

The invention relates to a formula and a preparation method of a novel low-shrinkage amino moulding compound. The novel low-shrinkage amino moulding compound comprises urea, formaldehyde, melamine, lubricant, dispersant, release agent, a curing agent system, dye, filler, cellulose and low shrinkage agent. The invention is characterized in that (1) the low shrinkage agent is water-soluble isocyanate elastomer; (2) the low shrinkage agent can be uniformly dispersed in a resin system and improve the surface glossiness of the moulding compound without influencing the coloring property of the dye or other performances of the moulding compound; and (3) a relatively small amount of the low shrinkage agent can meet the shrinkage requirement of the moulding compound. The preparation method of the moulding compound comprises the following steps: proportionally mixing and uniformly stirring the urea, the formaldehyde and the curing agent to prepare resin raw pulp; then transferring the raw pulp into a reaction kettle and adding the low shrinkage agent and other auxiliaries; and performing vacuum kneading and polymerization to prepare the amino moulding compound, wherein the forming shrinkage of the amino moulding compound is less than 0.6%, and the post shrinkage is less than 0.4%.

Description

technical field [0001] The invention relates to a novel low-shrinkage amino molding compound and a preparation method thereof. The shrinkage includes the mold shrinkage during the molding process and the post-shrinkage of the workpiece; the low-shrinkage amino molding compound is mainly used to prepare electrical panels and electrical housings that cooperate with metal devices, as well as high-grade sanitary ware. technical background [0002] Amino molding plastics are cheap raw materials, can be freely colored, have high surface hardness, have heat resistance, flame retardancy and excellent arc resistance characteristics, and are easy to achieve environmental protection in production, so they are widely used. Among them, 50% to 60% of amino molding plastics are used In the electrical and electronic fields, such as electrical switches, small electrical enclosures, sockets, circuit breakers and lighting appliances. [0003] The shrinkage rate of amino molding compound has a...

Claims

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Application Information

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IPC IPC(8): C08L61/24C08L75/04C08L1/02C08G12/12C08K13/02C08J3/24B29B7/86
Inventor 詹茂盛董绪超肖和平陈洪祖曹大伟
Owner CHANGZHOU JOEL PLASTIC
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