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Solid tantalum electrolytic capacitor and manufacturing method thereof

A tantalum electrolytic capacitor, solid technology, applied in the field of solid tantalum electrolytic capacitors and its preparation, can solve problems such as poor conductivity, achieve the effect of increasing conductivity, increasing specific capacitance, and increasing working life

Inactive Publication Date: 2010-12-22
UNIV OF ELECTRONICS SCI & TECH OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] Although manganese dioxide is regarded as a potential capacitor electrode material, manganese dioxide has poor conductivity and has been replaced by some organic compounds with higher conductivity than manganese dioxide. The electrolyte resistance R has a great influence on the high frequency characteristics of the capacitor, therefore, it is necessary to use a higher conductivity electrolyte to increase the performance of the capacitor

Method used

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  • Solid tantalum electrolytic capacitor and manufacturing method thereof
  • Solid tantalum electrolytic capacitor and manufacturing method thereof
  • Solid tantalum electrolytic capacitor and manufacturing method thereof

Examples

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Embodiment 1

[0037] based on figure 1 Be explained. Wherein, the conductive layer 3 is poly(3,4-ethylenedioxythiophene) doped with 1wt% composite carbon nanotubes, and the composite carbon nanotubes are magnetic Fe with a diameter of 10nm uniformly attached to the surface. 3 o 4 Particles and multi-walled carbon nanotubes of conductive silver particles with a diameter of 10 nm, and the length of the multi-walled carbon nanotubes is 20 μm.

[0038] The preparation method is as follows:

[0039] ① Press nano-tantalum metal particles into blocks, plant cylindrical tantalum wires in the formation of tantalum particles, and sinter them into porous tantalum anode bodies under high temperature and vacuum conditions;

[0040] ② Anodize the sintered tantalum anode body to form a layer of Ta on its surface 2 o 5 Dielectric coating;

[0041] ③ Evenly disperse the composite carbon nanotubes in the mixed solution containing oxidant and poly(3,4-ethylenedioxythiophene) monomer, and the tantalum-co...

Embodiment 2

[0050] The conductive layer 3 is polyaniline doped with 5wt% composite carbon nanotubes, and the composite carbon nanotubes are magnetic gamma-Fe with a diameter of 15nm uniformly attached to the surface 2 o 3 Particles and multi-walled carbon nanotubes of conductive nickel particles with a diameter of 10 nm, the length of the multi-walled carbon nanotubes is 30 μm.

[0051] The preparation method is as follows:

[0052] ① Press nano-tantalum metal particles into blocks, plant cylindrical tantalum wires in the formation of tantalum particles, and sinter them into porous tantalum anode bodies under high temperature and vacuum conditions;

[0053] ② Anodize the sintered tantalum anode body to form a layer of Ta on its surface 2 o 5 Dielectric coating;

[0054] ③ Evenly disperse the composite carbon nanotubes in the mixed solution containing oxidant and polyaniline monomer, and then spray the mixed solution on the tantalum-containing anode body and Ta 2 o 5 On the positive ...

Embodiment 3

[0059] The conductive layer 3 is polypyrrole doped with 10wt% composite carbon nanotubes, and the composite carbon nanotubes are single-walled carbon nanotubes with magnetic nickel particles with a diameter of 20nm and conductive copper particles with a diameter of 20nm uniformly attached to the surface, single-walled carbon nanotubes The tube length is 50 μm.

[0060] The preparation method is as follows:

[0061] ① Press nano-tantalum metal particles into blocks, plant cylindrical tantalum wires in the formation of tantalum particles, and sinter them into porous tantalum anode bodies under high temperature and vacuum conditions;

[0062] ② Anodize the sintered tantalum anode body to form a layer of Ta on its surface 2 o 5 Dielectric coating;

[0063] ③ Evenly disperse the composite carbon nanotubes in the mixed solution containing oxidant and polypyrrole monomer, and then drop-coat the mixed solution on the tantalum-containing anode body and Ta 2 o 5 On the positive sub...

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Abstract

The invention discloses a solid tantalum electrolytic capacitor. The capacitor comprises a tantalum anode body, a Ta2O5 dielectric envelope, a conducting layer, a graphite layer and a silver-coated layer, wherein the Ta2O5 dielectric envelope is positioned on the surface of the tantalum anode body; the conducting layer is positioned on the Ta2O5 dielectric envelope; and the graphite layer and the silver-coated layer are coated on the conducting layer. The capacitor is characterized in that: the conducting layer is a mixed system consisting of a composite carbon nano-tube and a conducting high molecular material; the composite carbon nano-tube is a carbon nano-tube of which the surface is attached to conductive nano-particles and magnetic nano-particles uniformly; and the length direction of the composite carbon nano-tube is vertical to the surface of the tantalum anode body. Directionally-arrayed composite carbon nano-tubes are adopted in the conducting layer, so that the conductivity of the conducting layer is enhanced, the equivalent series resistance of the capacitor is reduced and the high-frequency characteristic of the capacitor is improved; simultaneously, the carbon nano-tube has high thermal conductivity, so that the capacitor has higher heat resistance, the service life of the capacitor is prolonged and the leakage current is reduced.

Description

technical field [0001] The invention relates to the technical field of capacitors, in particular to a solid tantalum electrolytic capacitor and a preparation method thereof. Background technique [0002] In recent years, with the downsizing and weight reduction of electronic devices, small and high-capacity high-frequency capacitors are required, so solid electrolytic capacitors in which a solid electrolytic layer is formed of a solid conductive compound have been proposed. [0003] A solid electrolytic capacitor includes, for example, an Al (aluminum) or Ta (tantalum) metal anode body, a dielectric oxide film formed by oxidation treatment on the surface of the anode body, and a solid conductive compound such as MnO 2 (manganese dioxide), conductive high molecular polymer to the oxide film, and the cathode layer in close contact with the oxide film. Compared with paper dielectric capacitors and film capacitors, electrolytic capacitors are smaller in size and higher in capac...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G9/15H01G9/025H01G9/028
Inventor 于军胜牛连斌周建林蒋亚东
Owner UNIV OF ELECTRONICS SCI & TECH OF CHINA
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