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Mercaptan-alkene based high-precision ultraviolet imprinting method of continuous embossment micro optical elements

A micro-optical and high-precision technology, applied in optics, technology for producing decorative surface effects, microstructure technology, etc., can solve the problems of non-shrinkage resistance and achieve good anti-etching performance

Active Publication Date: 2011-05-11
HARBIN INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

(V.S.Khire, Y.Yi, N.A.Clark and C.N.Bowman.Formation and surface modification of nanopatterned thiol-ene substrates using Step and Flash Imprint Lithography.Advanced Materials.2008.20(17):3308-+.), the process uses thiol The surface-graftable properties of the nanostructures have achieved further refinement of the nanostructure, but the anti-shrinkage properties have not been further explored

Method used

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  • Mercaptan-alkene based high-precision ultraviolet imprinting method of continuous embossment micro optical elements
  • Mercaptan-alkene based high-precision ultraviolet imprinting method of continuous embossment micro optical elements
  • Mercaptan-alkene based high-precision ultraviolet imprinting method of continuous embossment micro optical elements

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Experimental program
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Effect test

Embodiment 1

[0021] The mercaptan-alkene ultraviolet photoinitiated polymer material prepared by triallyl isocyanurate (TATATO), pentaerythritol tetrakis (3-mercaptopropionate) (PETMP) and photoinitiator Darocur 1173 was used as a resist The ultraviolet embossing process is carried out to produce a continuous relief structure micro-optical element, and the base material is quartz glass. The specific steps are:

[0022] a) Fill the prepared resist material between the stamper and the substrate, apply pressure to compress the substrate and the stamper, and adjust the pressure so that the thickness of the residual adhesive layer is about 500-1000nm.

[0023] b) Use a UV-LED light source to expose the filled resist, and then implement demoulding, and the obtained structure is as follows figure 2 As shown, the profile of the die structure is as figure 2 As shown, the shrinkage error of the micro-optical element with continuous relief structure is less than 3%.

[0024] c) The imprinted str...

Embodiment 2

[0026] Using ethylene glycol dimethacrylate (EGDMA), PETMP, and photoinitiator Darocur 1173 to prepare thiol-alkene UV photoinitiated polymer materials for UV imprinting process, to produce continuous relief structure micro-optical elements, the substrate material is Quartz glass. The specific steps are:

[0027] a) filling the prepared resist material between the stamper and the substrate, applying pressure to compress the substrate and the stamper, and adjusting the pressure so that the thickness of the residual adhesive layer is about 500-1000nm;

[0028] b) Use a UV-LED light source to expose the filled resist, and then implement demoulding, and the obtained structure is as follows Figure 4 As shown, the die structure is as Figure 4 As shown, the shrinkage error of the micro-optical element with continuous relief structure is less than 3%.

Embodiment 3

[0030] The mercaptan-alkene UV photoinitiated polymer material prepared by triallyl cyanurate (TTT), PETMP, and photoinitiator Darocur 1173 was used for UV imprinting process to produce continuous relief structure micro-optical elements and substrate materials For quartz glass. The specific steps are:

[0031] a) filling the prepared resist material between the stamper and the substrate, applying pressure to compress the substrate and the stamper, and adjusting the pressure so that the thickness of the residual adhesive layer is about 500-1000nm;

[0032] b) Use a UV-LED light source to expose the filled resist, and then implement demoulding, and the obtained structure is as follows Figure 4 As shown, the die structure is as Figure 4 As shown, the shrinkage error of the micro-optical elements with continuous relief structure is less than 3%.

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Abstract

The invention discloses a mercaptan-alkene based high-precision ultraviolet imprinting method of continuous embossment micro optical elements, belonging to the field of manufacturing micro optical elements. The method provided by the invention is characterized in that based on the traditional ultraviolet imprinting process of continuous embossment micro optical elements, a mercaptan-alkene class ultraviolet light initiated high polymer material is utilized as etchant resist; shrinkage stress generated by etchant resist solidification is relaxed in a fluid flow mode by utilizing a method of adjusting the imprinting pressure and controlling the adhesive residue thickness; the shrinkage error of the continuous embossment micro optical element is lowered to below 3%; and the adhesive residue thickness is 500-1000nm. The method has the characteristics of small copying shrinkage error, good etching selectivity and the like, and can be used for realizing graph transmission to a quartz glass substrate by the continuous embossment micro optical element.

Description

technical field [0001] The invention belongs to a manufacturing method of a micro-optical element, and relates to a method for using a resist material for ultraviolet imprinting based on a thiol-alkene polymer. Background technique [0002] The development of micro-optics has brought profound changes to the optical system. The ultra-fine structure diffractive optical element is an important part to realize the miniaturization, arrayization and integration of the optical system. The processing technology of such diffractive optical elements is one of the key technologies of micro-optics. [0003] The existing microstructured optical element processing technologies mainly include multi-layer overlay technology, grayscale mask technology, electron beam direct writing technology, laser direct writing technology, replication technology, etc. Among them, nanoimprint technology is a high-resolution, low-cost, high-efficiency microstructured optical element processing and replicat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): G03F7/00G03F7/027B81C1/00
Inventor 金鹏刘楠王冠雄谭久彬
Owner HARBIN INST OF TECH