Method for preparing graphene functionalized alginate fibers

A technology of seaweed fiber and ene function, applied in the chemical field, can solve the problems of high cost, seriousness, low strength of seaweed fiber, etc., and achieve the effect of improving tensile strength, high tensile strength and fiber strength enhancement

Active Publication Date: 2011-09-14
QINGDAO UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

At the same time, the development and utilization of seaweed fiber can solve the problems of serious pollution, insufficient raw material sources or high cost in the processing of some recycled fiber products, which is of great significance to promote the sustainable development of the chemical fiber and textile industry
Judging from the development trend at home and abroad and the current status of related technologies, the strength of seaweed fiber is low, so it is limited to the use of medical fibers and cannot be widely used in the field of textile and clothing. The output and application range are very limited.

Method used

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  • Method for preparing graphene functionalized alginate fibers
  • Method for preparing graphene functionalized alginate fibers

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Weigh 30g of sodium alginate and add it to 470ml of distilled water, fully stir and dissolve to obtain a sodium alginate solution with a mass percent concentration of 6%; weigh 0.06g of graphene and add it to the above sodium alginate solution, continue stirring for 30min, and then Sonicate in ultrasonic for 30 minutes to obtain a uniformly dispersed alkene / algae (graphene / sodium alginate) solution. Add hydrogen peroxide to the alkene / algae solution to adjust the viscosity of the solution to 2600mPa·S, then filter and vacuum defoam for 13 hours to obtain the alkene / algae spinning solution. Adjust the temperature of the algae / algae spinning solution to 50°C, use a spinneret with 70 holes and 75 microns to wet spin the spinning solution at a spinning speed of 28 m / min, and then pass the alkene / algae spinning solution through The thin stream formed by the spinneret enters the calcium chloride aqueous solution with a temperature of 40° C. and a mass percentage concentration...

Embodiment 2

[0036] Repeat Example 1, with the following differences: 0.12g of graphene is weighed and added to the sodium alginate solution.

Embodiment 3

[0038] Repeat Example 1, with the following differences: 1.5g of graphene is weighed and added to the sodium alginate solution.

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Abstract

The invention discloses a method for preparing graphene functionalized alginate fibers. The method comprises the following steps: firstly adding a defined amount of graphene to a sodium alginate solution to obtain a graphene/alginate spinning solution; or aminating the defined amount of graphene and then ensuring the aminated graphene to covalently bind with sodium alginate through a chemical reaction to obtain a graphene-alginate spinning solution; then ensuring the graphene/alginate spinning solution or the graphene-alginate spinning solution to respectively undergo a coagulation bath to obtain graphene/alginate as-spun fibers or graphene-alginate as-spun fibers; and then drawing, setting and oiling the graphene/alginate as-spun fibers or graphene-alginate as-spun fibers after ensuring the graphene/alginate as-spun fibers or graphene-alginate as-spun fibers to undergo a preheating bath and a drawing bath respectively to obtain graphene/alginate functionalized fibers or graphene-alginate functionalized fibers which are called graphene functionalized alginate fibers. The prepared graphene functionalized alginate fibers integrate the excellent performances of the graphene and the sodium alginate and have the excellent performances such as high tensile strength, good biocompatibility, antistatic performance, light weight, high elasticity, antibacterial performance and the like.

Description

technical field [0001] The invention relates to a preparation method of graphene-functionalized seaweed fiber. Firstly, the non-covalent or covalent combination of graphene and sodium alginate is used to prepare spinning solution, and then the graphene-functionalized fiber is obtained through wet spinning and stretching setting respectively. The invention discloses chemical seaweed fiber, which belongs to the field of chemistry. Background technique [0002] The nano-carbon material graphene appeared in the laboratory in 2004. At that time, two British scientists, Andre Jem and Kostya Novoselov, discovered that they could obtain more thinner and thinner graphite flakes. The appearance of graphene has stirred up huge waves in the scientific community. It has only been 6 years since the successful preparation of graphene materials, and it won the Nobel Prize in 2010. [0003] Graphene is a simple carbon substance composed of carbon atoms arranged in a hexagonal lattice, and ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F9/04D01F1/10C08B37/04D01D1/02D01D5/06
Inventor 王宗花赵凯迟德玲孙锡泉夏建飞张菲菲李延辉夏延致
Owner QINGDAO UNIV
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