Process method for thermoplastic soft magnetic supramolecular material assembled by complexing subject and object

A process method and supramolecular technology, applied in the field of host-guest complex assembly of thermoplastic soft magnetic supramolecular materials, can solve the problems of inability to realize industrialization, stay in the laboratory, etc., and achieve good mechanical properties and thermal stability. Uniform and compact effect

Active Publication Date: 2011-09-28
YUNNAN INFINE NEO MATERIAL
View PDF3 Cites 4 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Domestic research institutes such as 14th, Zhejiang University and University of Electronic Scien

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A. Put 50g of Fe96Si4 amorphous nanoparticles with a particle size of 20nm into 750ml of 30% (w) tetrafluoroethylene-perfluoron-propyl vinyl ether copolymer (PFA) emulsion, and then disperse it with ultrasonic waves for 120min, and then Add 50g diisopropylamine and 2.5g isooctyl 3-mercaptopropionate (IOMP) to make mixed emulsion;

[0034] B. Add the mixed emulsion of step A into a 1L autoclave, heat up to 165°C at a heating rate of 2°C / min, and then keep it warm for 20 hours under a pressure of 6Mpa to prepare host-guest complex assembly particles;

[0035] C. First wash the assembled particles prepared in step B with deionized water for 5 times, then wash with 99% (v) alcohol for 3 times, and then dry at a pressure of -0.15Mpa and a temperature of 100°C for 4 hours in a vacuum environment;

[0036] D. Pour the dried assembled granules in step C into a vacuum twin-screw extruder for secondary granulation, add 15% (w) ethylenediamine, and extrude at a temperature of 280~...

Embodiment 2

[0042] A. 105g hexagonal square ferrite Ba(Sr)Fe 12 o 19 Nanoparticles were put into 750ml of 30% (w) tetrafluoroethylene-perfluoron-propyl vinyl ether copolymer (PFA) emulsion, and then dispersed by ultrasonic wave for 80min, then 50g of diisopropylamine and 1.6g of alkyl mercaptan were added Prepare mixed emulsion;

[0043] B. Add the mixed emulsion of step A into a 1L autoclave, heat up to 180°C at a heating rate of 3°C / min, and then keep it warm for 18 hours under a pressure of 8Mpa to prepare host-guest complex assembly particles;

[0044] C. First wash the assembled particles prepared in step B with deionized water for 4 times, then wash with 99% (v) alcohol for 2 times, and then dry at a pressure of -0.09Mpa and a temperature of 80°C for 2 hours in a vacuum environment;

[0045] D. Pour the dried assembled granules in step C into a vacuum twin-screw extruder for secondary granulation, adding 7% (w) of (NH 4 ) 2 CO 3 Finally, extrude at a temperature of 290~320°C to...

Embodiment 3

[0051] A. Put 40g of Fe65Co25B10 nanoparticles into 750ml of 30% (w) tetrafluoroethylene-perfluoron-propyl vinyl ether copolymer (PFA) emulsion, then disperse with ultrasonic wave for 15min, then add 9g of ethylenediaminetetraacetic acid Disodium (EDTA), 45g diisopropylamine and 3g isopropanol make mixed emulsion;

[0052] B. Add the mixed emulsion of step A into a 1L autoclave, raise the temperature to 220°C at a heating rate of 0.5°C / min, and keep it warm for 15 hours under a pressure of 10Mpa to prepare host-guest complex assembly particles;

[0053] C. First wash the assembled particles prepared in step B with deionized water for 4 times, then wash with 99% (v) alcohol for 3 times, and then dry for 3 hours under a vacuum environment with a pressure of -0.12Mpa and a temperature of 90°C;

[0054] D. Pour the dried assembled granules in step C into a vacuum twin-screw extruder for secondary granulation, add 12% (w) urea, and extrude at a temperature of 285~300°C to remove su...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention relates to a process method for a thermoplastic soft magnetic supramolecular material assembled by complexing a subject and an object, which belongs to the field of magnetic materials and high molecular materials. The invention relates to a subject provider which is formed by the complex assembly of a tetrafluoroethylene and a perfluoro-n-propyl-vinyl ether copolymer as the subject and the object of the supramolecular material; under the conditions of high temperature and high pressure, a subject-object complex assembled system is formed by absorbing cations or soft magnetic nanometer granules with polarities. After the complex assembly of the subject and the object is completed, washing and drying are carried out, and finally, secondary granulation is carried out by utilizing a vacuum double-screw extrusion machine so as to split a terminal group; and the extruded granules are the thermoplastic soft magnetic supramolecular material product assembled by complexing the subject and the object. The thermoplastic soft magnetic supramolecular material product disclosed by the invention has the advantages of customized magnetic conductive performance, superior electrical performance, fine mechanical performance, fine processability, chemical resistance and thermostability.

Description

technical field [0001] The invention relates to a process method for host-guest complexation assembly of thermoplastic soft magnetic supramolecular materials, which belongs to the field of magnetic materials and polymer materials. Background technique [0002] Supramolecular synthetic chemistry is penetrating into many disciplines such as organic and polymer synthesis, new material technology, biology and bionics, especially in the preparation and synthesis of intelligent functional materials and molecular devices, supramolecular construction and immobilization have become an important way . Compared with traditional polymer synthesis, supramolecular synthesis has the following advantages: (1) Through non-covalent bonding, it is easy to form an ordered structure, and then immobilized to obtain a highly ordered structure similar to biosynthesis; (2) Supramolecular construction can obtain composite polymer systems that cannot be constructed by covalent bond reactions, such as...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
IPC IPC(8): C08K3/34C08L27/18C08K3/38C08K3/22H01F1/42
Inventor 周涛赵蜀春
Owner YUNNAN INFINE NEO MATERIAL
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap