Functional masterbatch of halogen-free intumescent flame retardant, and preparation method thereof
An intumescent flame retardant and functional masterbatch technology, applied in the field of functional polymer materials, can solve the problems of insufficient flame retardant resin, low flame retardant content, performance impact, etc., and achieve no pollution, high economy, Effect of reducing energy consumption and production cost
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Embodiment 1
[0023] According to high degree of polymerization ammonium polyphosphate: pentaerythritol char-forming agent: melamine weight ratio = 65%: 20%: 80 parts by weight of phosphorus nitrogen flame retardant compounded in the ratio of 15%, the polymerization degree of ammonium polyphosphate > 1500 , and 3 parts by weight of hydroxystearic acid were put into a kneader and mixed for about 5 to 7 minutes, and then mixed with 25 parts by weight of polypropylene, 2 parts by weight of maleic anhydride grafted polypropylene, and 1 part by weight of vinyltriethoxysilane After mixing for 9-11 minutes, single-screw extrusion, water-cooling and pelletizing, the flame-retardant functional masterbatch can be obtained. The oxygen index of the masterbatch is 30.0, and the flame retardancy is V-0 level (UL-94, 1.6mm).
Embodiment 2
[0025] Other conditions are the same as in Example 1, but the compounded phosphorus-nitrogen flame retardant is 90 parts by weight, 45 parts by weight of polypropylene, 4 parts by weight of maleic anhydride grafted polypropylene, 5 parts by weight of hydroxystearic acid, vinyl triethylene 5 parts by weight of ethoxysilane. The oxygen index of the masterbatch is 29.3, and the flame retardancy is V-0 grade (UL-94, 1.6mm).
Embodiment 3
[0027] Other conditions are the same as in Example 1, but the compounded phosphorus-nitrogen flame retardant is 85 parts by weight, 40 parts by weight of polypropylene, 5 parts by weight of maleic anhydride grafted polyethylene, 3 parts by weight of stearic acid, vinyl triethyl 4 parts by weight of oxysilane. The oxygen index of the masterbatch is 30.5, and the flame retardancy is V-0 level (UL-94, 1.6mm).
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