Functional masterbatch of halogen-free intumescent flame retardant, and preparation method thereof

A technology of intumescent flame retardant and functional masterbatch, applied in the field of functional polymer materials, can solve the problems of inability to achieve flame retardant resin, low flame retardant content, performance impact, etc., to achieve no pollution, high economy, The effect of reducing energy consumption and production costs

Active Publication Date: 2011-10-19
SHANGHAI RES INST OF CHEM IND
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] There are also many patents on the preparation of flame-retardant masterbatches, but most of them are halogen-containing flame-retardant masterbatches, such as antimony trioxide-based flame-retardant masterbatches, such as CN200610012872.5, CN200710027466.0 are antimony-based flame-retardant masterbatches agent, causing great pollution to the environment
However, the current halogen-free flame retardant masterbatch is usually based on polyethylene, which may affect the performance of polypropylene resin PP flame retardant, and the content of flame retardant is low, which often fails to achieve flame retardant The effect of resin

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] According to high degree of polymerization ammonium polyphosphate: pentaerythritol char-forming agent: melamine weight ratio = 65%: 20%: 80 parts by weight of phosphorus nitrogen flame retardant compounded in the ratio of 15%, the polymerization degree of ammonium polyphosphate > 1500 , and 3 parts by weight of hydroxystearic acid were put into a kneader and mixed for about 5 to 7 minutes, and then mixed with 25 parts by weight of polypropylene, 2 parts by weight of maleic anhydride grafted polypropylene, and 1 part by weight of vinyltriethoxysilane After mixing for 9-11 minutes, single-screw extrusion, water-cooling and pelletizing, the flame-retardant functional masterbatch can be obtained. The oxygen index of the masterbatch is 30.0, and the flame retardancy is V-0 level (UL-94, 1.6mm).

Embodiment 2

[0025] Other conditions are the same as in Example 1, but the compounded phosphorus-nitrogen flame retardant is 90 parts by weight, 45 parts by weight of polypropylene, 4 parts by weight of maleic anhydride grafted polypropylene, 5 parts by weight of hydroxystearic acid, vinyl triethylene 5 parts by weight of ethoxysilane. The oxygen index of the masterbatch is 29.3, and the flame retardancy is V-0 grade (UL-94, 1.6mm).

Embodiment 3

[0027] Other conditions are the same as in Example 1, but the compounded phosphorus-nitrogen flame retardant is 85 parts by weight, 40 parts by weight of polypropylene, 5 parts by weight of maleic anhydride grafted polyethylene, 3 parts by weight of stearic acid, vinyl triethyl 4 parts by weight of oxysilane. The oxygen index of the masterbatch is 30.5, and the flame retardancy is V-0 level (UL-94, 1.6mm).

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Abstract

The invention relates to functional masterbatch of a halogen-free intumescent flame retardant, and a preparation method thereof. The halogen-free intumescent flame retardant in the functional masterbatch is a phosphorus-nitrogen series intumescent flame retardant, and a matrix in the functional masterbatch is a polyolefin resin. The functional masterbatch comprises, by weight, 50-90 parts of the halogen-free intumescent flame retardant, 20-45 parts of the polyolefin resin, 1-5 parts of a compatibilizer; 1-5 parts of a lubricant and 1-5 parts of a surface treatment agent. According to the present invention, dust pollution due to the flame retardant is fundamentally overcome; the flame-retardant masterbatch and polypropylene have good dispersions, such that purposes of environmental protection and no pollution are achieved; heavy metal contents of the functional masterbatch accord with requirements of the report of societe generale de surveillance S.A. (SGS); and the functional masterbatch has a good flame retardant property and high economy.

Description

1. Technical field [0001] The invention belongs to the field of functional polymer materials, and in particular relates to a functional masterbatch of a halogen-free expansion flame retardant and a preparation method thereof. 2. Background technology [0002] Halogen-free intumescent flame retardants are all added to the plastic matrix in a powder state. When the amount added is small, measurement errors are bound to occur; and when the amount is large, it will cause dust to fly and deteriorate the production and operating conditions. Many plastics are sold in the form of pellets. Mixing the two is not easy to disperse, which will inevitably bring difficulties to molding and even affect product quality. [0003] Flame retardant masterbatches are made from a super-normal amount of flame retardant, dispersant and carrier resin, etc., through dispersion, mixing, plasticization, and granulation. In terms of the concentration of additives in plastic products, masterbatches are t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L51/06C08K3/32C08K5/053C08K5/3492C08K5/5425C08K5/544C08J3/22
Inventor 郝冬梅林倬仕刘彦明陈崇伟尹亮陈涛
Owner SHANGHAI RES INST OF CHEM IND
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