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Post-absorption process of peroxide cross-linking polyethylene insulating material

A technology of cross-linked polyethylene and peroxide, which is applied in the direction of organic insulators, plastic/resin/wax insulators, etc., can solve problems such as high melt viscosity, poor electrical insulation performance, and product quality decline, and achieve control of impurity content, Good electrical insulation performance and the effect of improving electrical performance

Inactive Publication Date: 2011-11-16
JIANGSUSNGSHANG CABLE GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This makes: (1) It is impossible to mix polyethylene and high-melting-point antioxidant at a higher temperature, so that the high-melting-point antioxidant cannot be fully melted and effectively dispersed, so that the mixing of antioxidant and polyethylene is difficult. Uniformity, powdery spots and other phenomena appear, so that the stability and reliability of the insulating material deteriorate, and the electrical performance decreases; (2) It is impossible to mix polyethylene and high melting point antioxidant at a higher temperature, which makes the melting The viscosity of the melt is high and the pressure is high, so it is impossible to filter the impurities in the raw material (such as adding a filter, etc., the low-temperature and high-viscosity melt cannot pass through the filter and purification equipment such as the filter), so there is no filtration step in the traditional post-absorption process , the insulating material produced has high impurity content, poor cleanliness, and poor electrical insulation performance; (3) There is a slight decomposition of DCP in the extrusion granulation process, resulting in pre-crosslinked materials, resulting in a decline in product quality

Method used

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  • Post-absorption process of peroxide cross-linking polyethylene insulating material
  • Post-absorption process of peroxide cross-linking polyethylene insulating material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Main process equipment: the mixing machine is a single-screw extruder, the drying equipment is a centrifugal dehydrator, the filtering equipment is a filter screen, and also includes a mixing silo and a post-absorption silo.

[0025] A post-absorption process for peroxide cross-linked polyethylene insulating materials, which uses polyethylene, antioxidants and peroxide cross-linking agents as raw materials to prepare peroxide cross-linked polyethylene insulating materials, wherein the raw materials are polyethylene, anti-oxidant The weight ratio of the oxygen agent and the peroxide crosslinking agent is 100:0.15:1.6, the antioxidant is powdery No. 300 antioxidant, polyethylene is granular low density polyethylene, and the peroxide crosslinking agent is Filtered liquid dicumyl peroxide, the process steps are as follows:

[0026] (1) Batching: Batch the antioxidant and polyethylene, weigh the antioxidant and polyethylene in proportion, put them into the single-screw extru...

Embodiment 2

[0033] Main process equipment: The mixing machine is a twin-screw extruder, the drying equipment is a fluidized drying bed, the filtering equipment is an industrial filter, and there are mixing silos and post-absorption silos, etc.

[0034]A peroxide cross-linked polyethylene insulating material post-absorption process, which is prepared from polyethylene, an antioxidant and a peroxide cross-linking agent to obtain a peroxide cross-linked polyethylene insulating material, wherein the raw materials polyethylene, anti-oxidant The weight ratio of the oxygen agent and the peroxide crosslinking agent is 100: 0.30: 2.2, the antioxidant is powdery 1010 antioxidant, polyethylene is granular low density polyethylene, and the peroxide crosslinking agent is The liquid double 2 of filtration, 5 vulcanizing agents, described processing step is as follows:

[0035] (1) Batching: Batch the antioxidant and polyethylene, weigh the antioxidant and polyethylene in proportion, put them into the t...

Embodiment 3

[0042] Main process equipment: the mixing machine is a double-stage twin-screw extrusion granulator, the drying equipment is a vacuum dryer, the filtering equipment is a filter screen, and it also includes a mixing silo and a post-absorption silo.

[0043] A peroxide cross-linked polyethylene insulating material post-absorption process, which is prepared from polyethylene, an antioxidant and a peroxide cross-linking agent to obtain a peroxide cross-linked polyethylene insulating material, wherein the raw materials polyethylene, anti-oxidant The weight ratio of the oxygen agent and the peroxide cross-linking agent is 100:0.20:1.8, the antioxidant is powdered 168 antioxidant, the polyethylene is granular low-density polyethylene, and the peroxide cross-linking agent is processed The liquid cumene peroxide of filtering, described processing step is as follows:

[0044] (1) Batching: Batch the antioxidant and polyethylene, weigh the antioxidant and polyethylene in proportion, put ...

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Abstract

The invention relates to an insulating material for electric power cables, in particular to a post-absorption process of a peroxide cross-linking polyethylene insulating material. The process comprises the following steps of: (1) material blending: antioxidant and polyethylene are blended; (2) mixing and pelletizing: the blended materials are mixed in a mixing roll, and the mixed materials are filtered and then extruded and pelletized; (3) dehydrating and drying: the materials derived from pelletizing in the step 2 are dehydrated and dried to obtain an intermediate; (4) remixing: the intermediate derived from the step 3 is mixed with a peroxide cross-linking agent for 5 to 240 minutes at the temperature from 50 DEG C to 80 DEG C; (5) post-absorbing: the material derived from the step 4 is post-absorbed; and (6) cooling: the material derived from the step 5 is cooled to obtain the peroxide cross-linking polyethylene insulating material. The process in the invention is uniform in mixing, good in post-absorption effect and simple and reasonable in process; and the manufactured insulating material has reliable performances and good quality.

Description

technical field [0001] The invention relates to an insulating material for power cables, in particular to a post-absorption process for a peroxide crosslinked polyethylene insulating material. The peroxide cross-linked polyethylene insulating material produced by this process is suitable for high, medium and low voltage power cables, especially for 35kV and below power cables. Background technique [0002] The English name of polyethylene is polyethylene, referred to as PE, which is a thermoplastic resin obtained by polymerization of ethylene. In industry, it also includes copolymers of ethylene and a small amount of α-olefins. Polyethylene is odorless, non-toxic, feels like wax, has excellent low temperature resistance, the lowest operating temperature can reach -70 ~ -100 ° C, good chemical stability, can withstand the erosion of most acids and alkalis, and is not resistant to oxidizing properties. Acid, insoluble in common solvents at room temperature, low water absorp...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/06C08K5/14C08J3/24H01B3/44B29B9/06
Inventor 刘雄军李斌梁福才谢飞
Owner JIANGSUSNGSHANG CABLE GROUP
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