Preparation method for corn stalk/recycling waste plastic pencil
A technology of waste plastic and corn stalks, which is applied in non-mechanical pencils, pen holders, printing and other directions, can solve the problems of user pollution, the bond strength of pencil holders is not disclosed, and the content of adhesives is not specified. low cost effect
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Embodiment 1~3
[0033] Preparation of isocyanate-terminated polyurethane: Add toluene diisocyanate and castor oil into the reaction kettle, heat to 70-85°C, keep warm for 180min, cool, and discharge;
[0034] The performance tests of the raw materials and products used in Examples 1 to 3 are shown in Table 1.
[0035] Table 1
[0036]
Embodiment 4~21
[0038] Sieve the recycled waste plastics to remove sand, stones and metal solid impurities, and then grind them into smaller than 1cm 2 flakes, spare;
[0039] Drying the corn stalks until the water content is less than 15%, pulverizing, sieving, collecting the whole corn stalk powder with a particle size of less than 40 mesh, and sealing it for later use;
[0040] Add the dry corn stalk powder and flaky waste plastic fragments into a high-speed mixer, then spray the isocyanate adhesive under high pressure, stir and blend at room temperature for 10 minutes, and obtain the spray adhesive blend;
[0041] Fill the spray glue blend into the pencil molding machine, heat press, feed the pen core, cold press, and paint the exterior;
[0042] The detailed raw materials and consumption of each embodiment are shown in Table 2
[0043] Table 2
[0044]
[0045] Note: the preparation method of isocyanate-terminated polyurethane 1 is shown in Example 1,
Embodiment 2
[0047] See Example 3 for the preparation method of isocyanate-terminated polyurethane 3.
[0048] The corn stalk / recycling waste plastic pencil that embodiment 4~21 makes, detects the binding fastness of pen holder according to the light industry standard QB / T2774-2006 of the People's Republic of China: the pencil that makes is immersed in the water surface of (30 ± 2) ℃ 1h, after taking it out, twist the two ends of the pen barrel in reverse, and there is no glue opening phenomenon in the pen barrel, which has reached the pen barrel bonding fastness standard stipulated in QB / T2774-2006; usage habits.
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