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Monolayer organic solar cell and preparation method thereof

A solar cell and organic technology, applied in circuits, electrical components, photovoltaic power generation, etc., can solve the problems of demanding heterojunction growth control and increasing the complexity of organic solar cell devices, so as to improve energy conversion efficiency and reduce production costs , enhance the effect of the built-in electric field

Active Publication Date: 2015-10-14
OCEANS KING LIGHTING SCI&TECH CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

It is obvious that the introduction of bilayer heterostructures greatly increases the complexity of organic solar cell devices, and since the quality of the heterojunction structure is crucial to the output of the whole cell, the control of heterojunction growth requires relatively harsh

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  • Monolayer organic solar cell and preparation method thereof

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preparation example Construction

[0028] This embodiment also provides a method for preparing a single-layer organic solar cell device, comprising the following steps:

[0029] 1) Obtain a transparent insulating substrate 5;

[0030] 2) forming a transparent anode electrode layer 4 on one side of the transparent insulating substrate 5;

[0031] 3) forming a metal nanoparticle layer 3 on the transparent anode electrode layer 4, the work function value of the metal nanoparticles in the metal nanoparticle layer 3 is higher than the work function value of the transparent anode electrode layer 4;

[0032] 4) Depositing a photosensitive material on the metal nanoparticle layer 3 to form a photosensitive layer 2;

[0033] 5) Depositing a metal or metal oxide thin film on the photosensitive layer 2 to form the cathode electrode layer 1, thereby obtaining the single-layer organic solar cell.

[0034] In above-mentioned step 1), the thickness of transparent insulating substrate 5 is preferably 1.1-1.5mm, and its mater...

Embodiment 1

[0041] The structure of a single-layer organic solar cell is as figure 1 As shown, the high-reflectivity cathode electrode layer 1 adopts an aluminum film electrode, the photosensitive layer 2 adopts a CuPc copper phthalocyanine thin film, the metal nanoparticle layer 3 is a gold nanoparticle, and the transparent transparent anode electrode layer 4 adopts an ITO stripe electrode, and its square resistance is 15 ohm / □, the transparent insulating substrate 5 is made of quartz glass.

[0042] Its specific preparation method is as follows:

[0043] (1) Select polished quartz glass with a thickness of 1.1mm as the transparent insulating substrate 5, and use an ultrasonic method to clean the quartz glass for 2-3 hours;

[0044] (2) adopt the method for sputtering to grow one deck ITO conductive thin film on one surface of quartz glass, and the thickness of ITO thin film is 120nm;

[0045] (3) Photoetching the ITO conductive film into the required striped electrode pattern as the t...

Embodiment 2

[0051] like figure 1 As shown, the high-reflectivity cathode electrode layer 1 adopts a silver thin film electrode, the photosensitive layer 2 adopts a pentacene thin film, the metal nanoparticle layer 3 is a gold nanoparticle, and the transparent anode electrode layer 4 adopts an ITO stripe electrode, and its square resistance is 15 ohms / □, the transparent insulating substrate 5 is made of quartz glass.

[0052] Its specific preparation method is as follows:

[0053] (1) Select polished quartz glass with a thickness of 1.5mm as the transparent insulating substrate 5, and use an ultrasonic method to clean the quartz glass for 2-2.5 hours;

[0054] (2) adopt the method for sputtering to grow one deck ITO conductive thin film on one surface of quartz glass, and the thickness of ITO thin film is 80nm;

[0055] (3) Photoetching the ITO conductive film into the required stripe electrode pattern as the anode of the solar cell; as the transparent anode electrode layer 4, that is, ...

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Abstract

The invention discloses a single-layer organic solar cell, which comprises a transparent insulating substrate, a transparent anode electrode layer, a metal nanoparticle layer, a photosensitive layer and a cathode electrode layer sequentially stacked on the transparent insulating substrate. The work function value of the metal nanoparticles in the particle layer is higher than that of the transparent anode electrode layer. The metal nanoparticle layer is set in the single-layer organic solar cell of the present invention, thereby further enhancing the built-in electric field of the single-layer organic solar cell device, thereby improving the exciton splitting efficiency of the pair, and finally improving the efficiency of the single-layer organic solar cell. Energy conversion efficiency; the preparation method of a single-layer organic solar cell device uses stable sputtering and vacuum evaporation to form each layer of the solar cell device in sequence, so that the connections between the layers are tight and firm, so that the solar cell device The performance is stable, the production efficiency is high, and it is suitable for industrial production.

Description

technical field [0001] The invention belongs to the technical field of photoelectric conversion devices, and in particular relates to a single-layer organic solar cell and a preparation method thereof. Background technique [0002] A solar cell is a photovoltaic device that converts light energy into electricity. Since Bell Laboratories reported inorganic solar cells with an efficiency of 4% in 1954, solar cells have developed rapidly in the past half a century, and a "green energy revolution" has been set off worldwide. After the 1990s, photovoltaic devices such as gallium arsenide and cadmium telluride have been developed in the family of inorganic solar cells. However, until today, the high cost is the primary problem limiting the large-scale application of inorganic semiconductor solar cells. However, the cost problem is mainly caused by the inorganic materials themselves, so only the real low-cost green energy is an effective way to solve the energy problem. [0003]...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L51/42H01L51/46H01L51/48
CPCY02E10/549
Inventor 周明杰黄杰孙晓宇
Owner OCEANS KING LIGHTING SCI&TECH CO LTD
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