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Method for recovering valuable metal from metallurgical slag materials

A technology of valuable metals and metallurgical slag, applied in the direction of improving process efficiency, etc., can solve the problems of low metal recovery rate, high energy consumption, and low efficiency of beneficiation and enrichment in pyrometallurgy, and achieve high production efficiency and recovery rate High, adaptable effect

Inactive Publication Date: 2012-07-04
WUHAN UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The metal recovery rate of pyrometallurgy is not high, and the energy consumption is high
Due to the variable properties of metallurgical slag and the ultra-fine particle size of valuable metals, the efficiency of wet leaching or beneficiation is low

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] A method for recovering valuable metals in metallurgical slag. First, mix 100 parts by mass of metallurgical slag with 0.1 to 1 part by mass of activator, then heat and activate at an activation temperature of 1400 to 1600°C; and then recover valuable metals by beneficiation.

[0016] In this embodiment: the metallurgical slag material is nickel slag; the activator is carbonate of alkaline earth metal.

[0017] The recovery rate of iron in this embodiment is 62-65%, the recovery rate of copper, lead, zinc, nickel and cobalt is 70-73%, the recovery rate of rare earth metal is 60-63%, and the recovery rate of vanadium and titanium is 55-58%. , The recovery rate of precious metals is 60~63%.

Embodiment 2

[0019] A method for recovering valuable metals in metallurgical slag. In this embodiment, except that the activator is the fluoride of alkaline earth metal, the others are the same as in Embodiment 1.

[0020] The recovery rate of iron in this embodiment is 60-63%, the recovery rate of copper, lead, zinc, nickel and cobalt is 67-70%, the recovery rate of rare earth metal is 58-61%, and the recovery rate of vanadium and titanium is 53-56%. , The precious metal recovery rate is 55~58%.

Embodiment 3

[0022] A method for recovering valuable metals in metallurgical slag. First, mix 100 parts by mass of metallurgical slag with 1 to 10 parts by mass of activator, then heat and activate at an activation temperature of 1000 to 1400°C; and then recover valuable metals by beneficiation.

[0023] In this embodiment: the metallurgical slag material is lead slag; the activator is alkali metal silicate.

[0024] The recovery rate of iron in this embodiment is 73-75%, the recovery rate of copper, lead, zinc, nickel and cobalt is 78-81%, the recovery rate of rare earth metal is 80-83%, and the recovery rate of vanadium and titanium is 78-81%. , The recovery rate of precious metals is 82~84%.

[0025]

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PUM

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Abstract

The invention relates to a method for recovering valuable metals from metallurgical slag materials. The invention adopts a technical scheme that the method comprises: mixing 100 mass parts of metallurgical slag with 0.1 to 100 mass parts of an activating agent; heating and activating the mixture at the activation temperature of 200 to 1,600 DEG C; and recovering the valuable metals by an ore dressing process or wet-process metallurgical process. The metallurgical slag materials may be more than one of copper slag, lead slag, zinc slag, titanium slag, vanadium slag, nickel slag and rare earth smelting slag; the chemical activating agent may be more than one of an alkali metal oxide, an alkaline earth metal oxide, an alkali metal hydroxide, an alkaline earth hydroxide, an alkali metal carbonate, an alkali metal silicate, an alkaline earth metal carbonate, an alkali metal bicarbonate, an alkali metal fluoride, an alkaline earth metal fluoride and ammonium fluoride. The method has the characteristics of simple process, high adaptability and high production efficiency, and can be widely used for recovering noble metals from metallurgical slag materials.

Description

technical field [0001] The invention belongs to the technical field of comprehensive recovery of valuable metals. Specifically relates to a method for recovering valuable metals in metallurgical slag. Background technique [0002] A large amount of metallurgical slag is produced in the process of metal smelting, which contains a certain amount of valuable metals. For example, copper smelting slag (copper slag) not only contains a large amount of iron, but also contains a small amount of non-ferrous metals such as copper, lead, zinc, nickel, cobalt, and tin, and also contains precious metals such as gold, silver, platinum, palladium, osmium, and rhenium. Rare earth or rare metals such as yttrium, gallium, and germanium; and zinc smelting slag (zinc slag) not only contains a large amount of ferrous metal iron, but also contains some non-ferrous metals such as copper, lead, zinc, cadmium, and gold, silver, etc. Precious metals and rare metals such as gallium and indium. Anot...

Claims

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Application Information

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IPC IPC(8): C22B7/04
CPCY02P10/20
Inventor 黄自力冯定五
Owner WUHAN UNIV OF SCI & TECH
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