Preparing method for AKD (Alkyl Ketene Dimer) latex
A technology of emulsion and polyamide, applied in the direction of fiber dispersant addition, water repellent addition, no pigment coating, etc., can solve the problems of complicated waste paper sources, affecting paper drainage and forming, and uneconomical problems, and achieve improvement Sizing effect, dense microstructure, reducing the effect of false sizing
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Embodiment 1
[0044] Add 37.15g of acrylamide, 1.25g of acrylic acid, 2.75g of N,N-dimethylamine ethyl methacrylate, 8.14g of N,N-dimethyl-N-dodecylmethyl allyl into a 500mL reactor Hydroxyl ammonium chloride, 1.05g sodium methallylsulfonate, 1.42g hydrochloric acid (31wt%, wt% represents weight percentage, the same below) and 190g water, feed nitrogen, heat to 50 ° C, then add 10g8wt% Sodium persulfate aqueous solution and 2g 8wt% sodium bisulfite aqueous solution were gradually heated to 95°C within 2 hours, and the reaction was continued for 1 hour to obtain modified polyacrylamide 1 with a solid content of 20%.
[0045] Add 20g of dodecanedioic acid, 100g of adipic acid, and 84.3g of diethylenetriamine into a 500mL reactor, stir, heat to reflux under normal pressure, vacuumize and dehydrate after 6h, vacuum degree -0.097Mpa, when the temperature rises to At 180°C, stop vacuuming, continue to keep warm for 4 hours, then lower the temperature to 140°C, add 176g of water, and obtain polyam...
Embodiment 2
[0049] Add 113g of adipic acid and 84.3g of diethylenetriamine into a 500mL reactor, stir, heat to reflux under normal pressure, vacuumize and dehydrate after 5h, the vacuum degree is -0.098Mpa, when the temperature rises to 185°C, stop vacuuming , continue to keep warm for 3h, then lower the temperature to 140°C, and add 169g of water to obtain polyamide 2.
[0050] Add 24.8 g of 2,3-epoxypropyltrimethylammonium chloride to polyamide 2, heat to 60° C., and keep warm for 4 hours to obtain modified polyamide 2 with a solid content of 54%.
[0051] Weigh 7g of modified polyamide 2, 130g of modified polyacrylamide 1 (see Example 1 for the preparation method) and 190g of water in a 1000mL reactor, adjust the pH to 4.2, heat to 70°C, and add 130g of molten AKD , after pre-dispersion, perform homogenization treatment, then add 610g of ice water to dilute, and cool to below 20°C to obtain AKD emulsion 2 with a solid content of 15%.
Embodiment 3
[0053] Add 17.6g of sebacic acid, 100g of adipic acid, and 84.3g of diethylenetriamine into a 500mL reactor, stir, and heat to reflux under normal pressure. After 6h, vacuumize and dehydrate. The vacuum degree is -0.098Mpa. ℃, stop vacuuming, continue to keep warm for 4 hours, then lower the temperature to 140 ℃, add 176g of water, and obtain polyamide 3.
[0054] Add concentrated hydrochloric acid dropwise to polyamide 3, control the temperature below 10°C, adjust the pH value to 2.4, then add 44.5g hydrogen peroxide aqueous solution (50wt%), and then program the temperature at a rate of 10°C / h to 60 After 3 hours of heat preservation at ℃, the modified polyamide 3 was obtained with a solid content of 42%.
[0055] Weigh 11g of modified polyamide 3, 100g of modified polyacrylamide 1 (see Example 1 for the preparation method) and 200g of water in a 1000mL reactor, heat to 70°C, adjust the pH value to 2.0, and add 130g of molten AKD , after pre-dispersion, carry out homogeniza...
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