Expandable polystyrene particles with high foaming ratio and preparation method thereof
An expandable polystyrene, high-foaming technology, applied in the field of foamed resin raw materials and its preparation, can solve the problems of high density of foamed plastics, damaged by packaging, and high production costs, and achieves strong toughness, easy expansion, and raw materials. less effect
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Embodiment 1
[0032] First select 90 parts of styrene, 100 parts of soft water, 0.1 parts of nucleating agent, 1.2 parts of calcium phosphate, 0.3 parts of benzoyl peroxide, 0.1 parts of tert-butyl peroxybenzoate, 0.3 parts of white Oil, 0.3 parts of chain force regulator, 7.0 parts of pentane and 0.15 parts of surface lubricant. Wherein, the said lubricant is mixed according to the weight ratio of zinc stearate: glyceryl stearate=40:60.
[0033] Then, add soft water into the reaction kettle, and while stirring evenly, add calcium phosphate, styrene, benzoyl peroxide, tert-butyl peroxybenzoate, nucleating agent, white oil, and molecular chain force modifier in sequence , and heat the materials in the reactor according to the heating rate of 0.8° C. / min. When the temperature rises to 85°C, keep the constant temperature for 400 minutes to make the material form particles with a particle size of 30-12 mesh.
[0034] Afterwards, pentane was added, and the reactor was continued to be heated, s...
Embodiment 2
[0039] First select 100 parts of styrene, 110 parts of soft water, 0.2 parts of nucleating agent, 1.4 parts of calcium phosphate, 0.4 parts of benzoyl peroxide, 0.2 parts of tert-butyl peroxybenzoate, 0.4 parts of white Oil, 0.4 parts of chain force regulator, 7.5 parts of pentane and 0.2 parts of surface lubricant. Wherein, the said lubricant is mixed according to the weight ratio of zinc stearate: glyceryl stearate=40:60.
[0040] Then, add soft water into the reaction kettle, and while stirring evenly, add calcium phosphate, styrene, benzoyl peroxide, tert-butyl peroxybenzoate, nucleating agent, white oil, and molecular chain force modifier in sequence , and the reactor was heated at a heating rate of 0.6° C. / min. When the temperature rises to 88°C, keep the constant temperature for 350 minutes to make the material form particles with a particle size of 30-12 mesh.
[0041] Afterwards, pentane was added, and the reactor was continued to be heated, so that the temperature ...
Embodiment 3
[0046] Select 110 parts of styrene, 120 parts of soft water, 0.3 parts of nucleating agent, 1.6 parts of calcium phosphate, 0.5 parts of benzoyl peroxide, 0.3 parts of tert-butyl peroxybenzoate, 0.6 parts of white oil , 0.5 parts of molecular chain force modifier, 8.0 parts of pentane and 0.3 parts of surface lubricant. Wherein, the said lubricant is mixed according to the weight ratio of zinc stearate: glyceryl stearate=40:60.
[0047] Then, add soft water into the reaction kettle, and while stirring evenly, add calcium phosphate, styrene, benzoyl peroxide, tert-butyl peroxybenzoate, nucleating agent, white oil, and molecular chain force modifier in sequence , and the reactor was heated at a heating rate of 0.5° C. / min. When the temperature rises to 90°C, keep the constant temperature for 300 minutes to make the material form particles with a particle size of 30-12 mesh.
[0048] Afterwards, pentane was added, and the reactor was continued to be heated, so that the temperat...
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