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Method for comprehensively recycling and using baric waste slag in refined aluminum production process

A production process and barium waste slag technology, which is applied in the field of barium-containing waste slag in the comprehensive recovery and utilization of refined aluminum production process, can solve the problems of environmental safety impact, waste of resources, etc.

Inactive Publication Date: 2013-06-26
青海省安全生产科学技术中心 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

During the storage process of soluble barium-containing waste residue, the soluble barium salt will be transferred to groundwater and surface water after rainwater infiltration, which will have a great impact on the surrounding environmental safety and also cause a waste of resources

Method used

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  • Method for comprehensively recycling and using baric waste slag in refined aluminum production process
  • Method for comprehensively recycling and using baric waste slag in refined aluminum production process
  • Method for comprehensively recycling and using baric waste slag in refined aluminum production process

Examples

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Effect test

Embodiment 1

[0047] Example 1 like Figure 1~5 As shown, a method for comprehensively recycling barium-containing waste slag in the production process of refined aluminum, the method is composed of fluoride ion recovery process, leachate separation process, iron-aluminum separation process, and sodium-barium separation process. in

[0048] The fluoride ion recovery process refers to firstly mixing the barium-containing waste slag and calcium chloride in the production process of refined aluminum according to the mass ratio of 1:0.2 to form a mixture and then pass it through the feeder 11 into the pickling tank 12, add water and stir evenly with an electric mixer, the hydrochloric acid from the hydrochloric acid storage tank Pump into pickling tank 12 in 14, every liter of mixed solution needs to add the hydrochloric acid that mass concentration is 36% to be 180 g, obtain pickling liquid after pickling 2.0 h; The ratio (kg / L) is 1:2; the pickling liquid is pumped into the filter...

Embodiment 2

[0052] Example 2 like Figure 1~5 As shown, a method for comprehensively recycling barium-containing waste slag in the production process of refined aluminum, the method is composed of fluoride ion recovery process, leachate separation process, iron-aluminum separation process, and sodium-barium separation process. in

[0053] The fluoride ion recovery process refers to first mixing the barium-containing waste slag and calcium chloride in the production process of refined aluminum at a mass ratio of 1: 1 to form a mixture and then pass it through the feeder 11 into the pickling tank 12, add water and stir evenly with an electric mixer, the hydrochloric acid from the hydrochloric acid storage tank Pump into pickling tank 12 in 14, every liter of mixed solution needs to add the hydrochloric acid that mass concentration is 36% to be 450 g, obtain pickling liquid after pickling 0.5 h; The ratio (kg / L) is 1: 10; the pickling solution is pumped into the filter press 1...

Embodiment 3

[0057] Example 3 like Figure 1~5 As shown, a method for comprehensively recycling barium-containing waste slag in the production process of refined aluminum, the method is composed of fluoride ion recovery process, leachate separation process, iron-aluminum separation process, and sodium-barium separation process. in

[0058] The fluoride ion recovery process refers to firstly mixing the barium-containing waste slag and calcium chloride in the production process of refined aluminum at a mass ratio of 1:0.6 to form a mixture and then pass it through the feeder 11 into the pickling tank 12, add water and stir evenly with an electric mixer, the hydrochloric acid from the hydrochloric acid storage tank Pump into pickling tank 12 in 14, every liter of mixed solution needs to add the hydrochloric acid that mass concentration is 36% to be 320 g, obtain pickling liquid after pickling 1.5 h; The ratio (kg / L) is 1:6; the pickling solution is pumped into the filter press ...

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Abstract

The invention relates to a method for comprehensively recycling and using baric waste slag in a refined aluminum production process, wherein the method is composed of a fluorine ion recycling technology, a leaching liquid separation technology, an iron-aluminum separation technology and a sodium-barium separation technology. The method provided by the invention is easy to control and operate; andaccording to the method, the baric waste slag generated in the refined aluminum production process can be separated into calcium fluoride, barium chloride, sodium chloride and aluminum hydroxide, so that various major elements in the baric waste slag generated in the refined aluminum production process are separated and recycled, therefore the purposes of comprehensively and cyclically utilizing resources, saving energy, reducing emission, reducing environmental pollution and improving production safety are achieved.

Description

technical field [0001] The invention relates to the field of refined aluminum production, in particular to a method for comprehensively recycling barium-containing waste slag in the refined aluminum production process. Background technique [0002] At present, the mature process of refined aluminum electrolysis at home and abroad is the three-layer liquid refined aluminum electrolysis process, and the chlorofluoroelectrolyte system is usually used as the electrolyte in the refined aluminum electrolysis. [0003] As one of the main electrolytes in the three-layer liquid refined aluminum electrolysis process, barium chloride plays an irreplaceable role in the production of refined aluminum. The three-layer liquid refined aluminum electrolysis process has relatively strict requirements on the electrolyte. The electrolyte must have the characteristics of moderate density, low volatility, good conductivity, and low primary crystal temperature. Barium chloride works together with...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22B7/04C22B3/10C22B3/22C22B3/46C25C3/24
CPCY02P10/20
Inventor 景燕马军贾永忠王小华姚颖孙进贺李磊林鹏程田素燕吕学海尹刚
Owner 青海省安全生产科学技术中心