Light emitting diode (LED) encapsulation adhesive composition

A technology of LED packaging and composition, applied in the direction of adhesives, adhesive additives, non-polymer adhesive additives, etc., can solve the problems of decreased strength, poor light transmittance, yellowing, etc.

Active Publication Date: 2012-08-22
RUNHE ORGANICSILICONE NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] Traditional semiconductor components are packaged with epoxy resin, but yellowing will occur during use, which will make the light transmittance worse. The epoxy resin will become brittle and its strength will decrease after repeated use.
In order to solve the above problems, silicone-modified epoxy resin composition, silica gel, etc. are used as packaging materials for semiconductor elements, w

Method used

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  • Light emitting diode (LED) encapsulation adhesive composition
  • Light emitting diode (LED) encapsulation adhesive composition

Examples

Experimental program
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preparation example Construction

[0023] One, the preparation of polysiloxane A

[0024] The general structural formula that the present invention relates to polysiloxane A is:

[0025]

[0026] where R 1 Is an alkyl group, such as methyl, ethyl, propyl, butyl, etc., preferably methyl; R 2 Is alkyl or alkenyl, such as methyl, vinyl, allyl, butenyl, etc., preferably vinyl; R 3 Aryl, such as phenyl, tolyl, naphthyl, etc., preferably phenyl. a+b+c+d+e=100, a=1~20, b=0~20, c=0~20, d=0~20, e=30~60.

[0027] The preparation method of the present invention relates to polysiloxane A: add catalyst, solvent, end-capping agent, methyl siloxane, methyl vinyl siloxane, phenyl siloxane dropwise while stirring at room temperature or under heating Phenyltrialkoxysilane, after dripping phenyltrialkoxysilane, react at room temperature or under heating for 3~18 hours, stand still, separate the upper layer of acid water, add water to the lower oil phase, wash the oil phase into the middle properties, and then at 150 ° C,...

Embodiment 1

[0034] Put 20g of 30% sulfuric acid, 54g of toluene, 40g of hexamethyldisiloxane, 22g of octamethylcyclotetrasiloxane and 26g of tetramethyltetravinylcyclotetrasiloxane into a four-necked bottle, start stirring, Slowly add phenyltrimethoxysilane dropwise, after dripping 178g of phenyltrimethoxysilane, react at room temperature for 18 hours, stand still, separate the upper layer of acid water, add water to the lower oil phase, and wash the oil phase to neutral , and then at 150 ° C, -0.099Mpa to pull out the low fraction to obtain a colorless and transparent product A1.

Embodiment 2

[0036] Put 25g of 30% sulfuric acid, 107g of toluene, 30g of hexamethyldisiloxane, 88g of dimethyldimethoxysilane and 49g of tetramethyltetravinylcyclotetrasiloxane into a four-necked bottle, and put it under reflux Turn on the stirring tube, start to slowly add phenyltrimethoxysilane dropwise, after dripping 400g of phenyltrimethoxysilane, stir at room temperature for 16 hours, stand still, remove the upper layer of acid water, and wash the lower layer of oil phase with water , wash the oil phase to neutrality, and then pull out the low fraction at 150°C and -0.099Mpa to obtain a colorless and transparent product A2.

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Abstract

The invention relates to a light emitting diode (LED) encapsulation adhesive composition, which comprises the following components of polysiloxane A, polysiloxane B, a curing accelerator C and a solidification inhibitor D, wherein each molecule of the polysiloxane A comprises at least one alkylene and one aromatic group which are connected with silicon, each molecule of the polysiloxane B comprises at least two hydrogen atoms and aromatic groups, the at least two hydrogen atoms and aromatic groups are connected with the silicon, the composition comprises, by weight, 30-70 parts of the polysiloxane A, 30-70 parts of the polysiloxane B, 0.001-0.003 part of the curing accelerator C and 0.001-0.003 part of the solidification inhibitor D, and the molar mass of the aromatic groups which are connected with the silicon in the polysiloxane A and the polysiloxane B are over 40% of that of total groups. The LED encapsulation adhesive composition has the advantages of being high in index of refraction, transmittance and physical strength, anti-yellowing, anti-ultraviolet and heat aging resistant.

Description

technical field [0001] The invention relates to an LED packaging glue composition. Background technique [0002] Traditional semiconductor components are packaged with epoxy resin, but yellowing will occur during use, resulting in poor light transmission. The epoxy resin tends to become brittle and its strength decreases during repeated use. In order to solve the above problems, silicone-modified epoxy resin composition, silica gel, etc. are used as packaging materials for semiconductor elements, which improves the UV and thermal aging resistance. However, with the continuous increase in the power of semiconductor elements, silicone modified The epoxy resin encapsulation material still cannot meet the requirements of semiconductor components, and the introduction of phenyl group into the semiconductor encapsulation adhesive raw material involved in the present invention solves the above problems better. For LED lights, due to the high refractive index of GaN chips, in order...

Claims

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Application Information

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IPC IPC(8): C09J183/07C09J183/05C09J11/06C09K3/10H01L33/56
Inventor 许银根
Owner RUNHE ORGANICSILICONE NEW MATERIAL
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