Beneficiation method of white tungsten tailing
A beneficiation method and tailings technology, applied in chemical instruments and methods, wet separation, solid separation, etc., can solve the problems of low recovery rate and grade of tungsten ore, and achieve the effect of improving the recovery rate and grade
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Embodiment 1
[0040] 1) Take 500g of scheelite tailings, add water to the tungsten ore, adjust the tungsten ore into a tungsten slurry with a mass concentration of 33%, add 4g of a dispersant solution with a mass concentration of 5%, that is, take the amount at 400g / t.
[0041] 2) Take 5g of cornstarch, 60°C, 100ml of distilled water, stir at a constant temperature for 40min to form a cornstarch slurry; cool down the cornstarch slurry to 50°C, add 1mmol of cerium ammonium nitrate and 1mmol of potassium persulfate as a composite initiator, and continue stirring 5min; add 10ml of oleic acid, stir and make it react for 3 hours to form a water-soluble flocculant; add absolute ethanol to the water-soluble flocculant, suction filter and wash the water-soluble flocculant to obtain a starch graft copolymer; The crude product of the starch graft copolymer that obtains is as in Soxhlet extractor, with acetone as solvent, after it is extracted 24 hours, removes homopolymer, then it is dried to constant...
Embodiment 2
[0046] 1) Take 500g of scheelite tailings, add water to the tungsten ore, adjust the tungsten ore into a tungsten slurry with a mass concentration of 35%, add 6.5g of a dispersant solution with a mass concentration of 5%, that is, take the amount at 650g / t.
[0047] Take 10g of cornstarch, 70°C, 125ml of distilled water, stir at a constant temperature for 50min to form a cornstarch slurry; cool the cornstarch slurry to 50°C, add 1.5mmol of cerium ammonium nitrate and 1.5mmol of potassium persulfate as a composite initiator, and continue stirring 8min; add 15ml of oleic acid, stir and make it react for 3 hours to form a water-soluble flocculant; add absolute ethanol to the water-soluble flocculant, suction filter and wash the water-soluble flocculant to obtain a starch graft copolymer; The crude product of the starch graft copolymer that obtains is as in Soxhlet extractor, with acetone as solvent, after it is extracted 24 hours, removes homopolymer, then it is dried to constant ...
Embodiment 3
[0052] 1) Take 500g of scheelite tailings, add water to the tungsten ore, adjust the tungsten ore into a tungsten slurry with a mass concentration of 38%, add 9g of a dispersant solution with a mass concentration of 5%, that is, take the amount at 900g / t.
[0053] Take 15g of cornstarch, 90°C, 150ml of distilled water, and stir at a constant temperature for 70min to form a cornstarch slurry; cool the cornstarch slurry to 50°C, add 2mmol of cerium ammonium nitrate and 2mmol of potassium persulfate as a composite initiator, and continue stirring for 10min; Add the oleic acid of 20ml, make it react 3 hours after stirring, form water-soluble flocculant; Add dehydrated alcohol to water-soluble flocculant, suction filter and wash water-soluble flocculant, obtain starch graft copolymer; Will obtain The crude product of the starch graft copolymer was placed in a Soxhlet extractor, with acetone as a solvent, after it was extracted for 24 hours, the homopolymer was removed, and then it w...
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