Ammonia storage mixture porous solid sample block containing ceramic fibers and preparation method thereof
A ceramic fiber, porous solid technology, applied in the preparation/separation of ammonia, alkali metal compounds, chemical instruments and methods, etc., can solve the problems of no clear claim details, no addition ratio, and technical personnel unable to implement, etc. Achieve good physical adsorption and surface chemical activity, meet application requirements, improve viscosity and adsorption capacity
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Embodiment 1
[0015] Mix 54wt% of industrial anhydrous strontium chloride powder, 6wt% of ceramic fiber, 12wt% of industrial clay, 20wt% of deionized water and 8wt% of industrial alcohol to form a mixture, and mix it evenly with a mixer for 1h. A semi-dry mixed powder is formed; the powder is added to an openable airtight container, mechanically shaken for 30 minutes, and then dried for 1 hour at 80°C and a vacuum of 1Kpa to obtain a ceramic fiber containing 8wt% The porous solid sample block of the ammonia storage active mixture.
[0016] Fill the 10g porous solid sample with ammonia in a natural ventilated environment. Put the openable airtight container into a tank of cooling water with a sufficient amount of water in advance, connect the ammonia cylinder, and pass the pressure reducing valve and drying system. , Slowly carry out ammonia filling within the pressure range of 0.1Mpa, and the ammonia filling time is 3h; after ammonia filling, the mass of the sample block is 13.8g, that is, 3.8...
Embodiment 2
[0018] Mix 80wt% of industrial anhydrous strontium chloride powder, 10wt% of ceramic fiber, 4wt% of industrial clay, 3wt% of deionized water and 3wt% of industrial alcohol, and mix it evenly with a mixer. The mixing time is 5h. Semi-dry mixed powder; the powder is added to an openable airtight container and mechanically shaken for 40 minutes, and then at 60 ℃, the vacuum degree is 10 -1 After drying for 4 hours under the condition of Kpa, a porous solid sample of ammonia storage active mixture containing 10.6wt% ceramic fiber can be obtained 。
[0019] Fill the 10g porous solid sample with ammonia in a natural ventilated environment. Put the openable airtight container into a tank of cooling water with a sufficient amount of water in advance, connect the ammonia cylinder, and pass the pressure reducing valve and drying system. , Slowly carry out ammonia filling within the pressure range of 0.1Mpa, and the ammonia filling time is 4h; after ammonia filling, the mass of the sample bl...
Embodiment 3
[0021] Mix 70wt% of industrial anhydrous strontium chloride powder, 15wt% of ceramic fiber, 5wt% of industrial clay, 5wt% of deionized water and 5wt% of industrial alcohol, and mix it evenly with a mixer. The mixing time is 10h. Semi-dry mixed powder; this powder is added to an openable airtight container, mechanically shaken for 60 minutes, and then dried at 100°C for 4 hours to obtain a porous ammonia storage active mixture containing 16.7wt% ceramic fiber Solid sample 。
[0022] Fill the 10g porous solid sample with ammonia in a natural ventilated environment. Put the openable airtight container into a tank of cooling water with a sufficient amount of water in advance, connect the ammonia cylinder, and pass the pressure reducing valve and drying system. , Slowly carry out ammonia filling within the pressure range of 0.2Mpa, and the ammonia filling time is 3h; after ammonia filling, the mass of the sample block is 14g, that is, 4g ammonia gas is adsorbed. Then the sample block...
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