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Ammonia storage mixture porous solid sample block containing ceramic fibers and preparation method thereof

A ceramic fiber, porous solid technology, applied in the preparation/separation of ammonia, alkali metal compounds, chemical instruments and methods, etc., can solve the problems of no clear claim details, no addition ratio, and technical personnel unable to implement, etc. Achieve good physical adsorption and surface chemical activity, meet application requirements, improve viscosity and adsorption capacity

Active Publication Date: 2012-10-17
CHINA FIRST AUTOMOBILE
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, this patent uses solid material for direct compression molding, uses a binder, only states that it may be a silica fiber binder, and does not have a dosage ratio, and other claims and examples only declare solid materials It may include granular materials, porous materials, crystalline materials, amorphous materials or their combinations. Without clear claim details, it is almost impossible for those skilled in the industry to implement

Method used

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  • Ammonia storage mixture porous solid sample block containing ceramic fibers and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0015] Mix 54wt% of industrial anhydrous strontium chloride powder, 6wt% of ceramic fiber, 12wt% of industrial clay, 20wt% of deionized water and 8wt% of industrial alcohol to form a mixture, and mix it evenly with a mixer for 1h. A semi-dry mixed powder is formed; the powder is added to an openable airtight container, mechanically shaken for 30 minutes, and then dried for 1 hour at 80°C and a vacuum of 1Kpa to obtain a ceramic fiber containing 8wt% The porous solid sample block of the ammonia storage active mixture.

[0016] Fill the 10g porous solid sample with ammonia in a natural ventilated environment. Put the openable airtight container into a tank of cooling water with a sufficient amount of water in advance, connect the ammonia cylinder, and pass the pressure reducing valve and drying system. , Slowly carry out ammonia filling within the pressure range of 0.1Mpa, and the ammonia filling time is 3h; after ammonia filling, the mass of the sample block is 13.8g, that is, 3.8...

Embodiment 2

[0018] Mix 80wt% of industrial anhydrous strontium chloride powder, 10wt% of ceramic fiber, 4wt% of industrial clay, 3wt% of deionized water and 3wt% of industrial alcohol, and mix it evenly with a mixer. The mixing time is 5h. Semi-dry mixed powder; the powder is added to an openable airtight container and mechanically shaken for 40 minutes, and then at 60 ℃, the vacuum degree is 10 -1 After drying for 4 hours under the condition of Kpa, a porous solid sample of ammonia storage active mixture containing 10.6wt% ceramic fiber can be obtained 。

[0019] Fill the 10g porous solid sample with ammonia in a natural ventilated environment. Put the openable airtight container into a tank of cooling water with a sufficient amount of water in advance, connect the ammonia cylinder, and pass the pressure reducing valve and drying system. , Slowly carry out ammonia filling within the pressure range of 0.1Mpa, and the ammonia filling time is 4h; after ammonia filling, the mass of the sample bl...

Embodiment 3

[0021] Mix 70wt% of industrial anhydrous strontium chloride powder, 15wt% of ceramic fiber, 5wt% of industrial clay, 5wt% of deionized water and 5wt% of industrial alcohol, and mix it evenly with a mixer. The mixing time is 10h. Semi-dry mixed powder; this powder is added to an openable airtight container, mechanically shaken for 60 minutes, and then dried at 100°C for 4 hours to obtain a porous ammonia storage active mixture containing 16.7wt% ceramic fiber Solid sample 。

[0022] Fill the 10g porous solid sample with ammonia in a natural ventilated environment. Put the openable airtight container into a tank of cooling water with a sufficient amount of water in advance, connect the ammonia cylinder, and pass the pressure reducing valve and drying system. , Slowly carry out ammonia filling within the pressure range of 0.2Mpa, and the ammonia filling time is 3h; after ammonia filling, the mass of the sample block is 14g, that is, 4g ammonia gas is adsorbed. Then the sample block...

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Abstract

The invention relates to an ammonia storage mixture porous solid sample block containing ceramic fibers. The ammonia storage mixture porous solid sample block is prepared by mixing anhydrous strontium chloride, the ceramic fibers and industrial clay, and is characterized in that a preparation method comprises the following specific steps that: the industrial anhydrous strontium chloride salt powder, the ceramic fibers, the industrial clay, the deionized water and the industrial alcohol are stirred uniformly through a stirring machine so as to form semi-dry mixed powder; and the powder is added into an openable sealed container for mechanical vibration and drying. The prepared ammonia storage mixture porous solid sample block has a super strong absorption ability, and furthermore, is stable in structure and high in mechanical strength; during the process of preparing the ammonia storage mixture porous solid sample block, the industrial clay in proper quantity is further added; as the clay mineral has plasticity after being wetted by water, the clay mineral can be transformed and kept in an original shape for a long term under smaller pressure; the specific surface area is large; the grains have electronegativity; good physical adsorbability and surface chemical activity are provided; and the viscosity and the absorption ability of the mixture porous solid sample block after being dried can be further improved.

Description

technical field [0001] The invention relates to a porous solid sample block of an ammonia storage mixture containing ceramic fibers and a preparation method thereof, which is applied to a vehicle tail gas post-treatment system and a fuel cell system. Background technique [0002] Energy crisis and environmental pollution are two very difficult problems that human beings must face in the 21st century. People still face many problems in the selection of technical means to meet the emission standards of traditional vehicles and the fuel supply technology of new energy vehicles. problem. [0003] The traditional exhaust gas after-treatment system of internal combustion engine vehicles relies on the precise supply of urea reducing agent and decomposes it into ammonia gas at the front end of the catalyst to remove NOX hazards, so as to purify the exhaust gas and achieve the vehicle's National 4 or above standards. However, in actual use, there are many shortcomings and difficulti...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/12B01J20/28B01J20/30C01C1/02
Inventor 张克金崔龙姜涛王丹王金星安宇鹏于力娜许德超
Owner CHINA FIRST AUTOMOBILE