High-strength glass fiber composition

A glass composition and glass fiber technology, applied in glass manufacturing equipment, manufacturing tools, etc., can solve the problems of high liquidus temperature, increase production cost, poisoning of platinum bushings, etc. The effect of reducing the pressure of use

Inactive Publication Date: 2012-11-21
TAISHAN FIBERGLASS INC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Such as U.S. Patent 3402055, its tensile strength is significantly higher than that of alkali-free glass fiber, but its liquidus temperature is as high as 1471°C, and the temperature of the wire drawing bushing is as high as 1571°C, making production very difficult, which increases the impact of glass liquid on kiln refractory materials. The corrosion of the platinum bushing shortens the life of the platinum bushing and greatly increases its production cost, so it is difficult to popula

Method used

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  • High-strength glass fiber composition

Examples

Experimental program
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Effect test

Embodiment 1

[0023] After the alumina after removing impurities is fully calcined at about 1100 ° C, the moisture content is controlled within 1.0%, the iron content is not about 0.15%, and the particle size is controlled at 200 meshes;

[0024] The blast furnace slag that has been quenched at a high temperature above 1300°C from the steelmaking blast furnace is processed by the iron removal system, and the iron content is detected and controlled to be less than or equal to 0.3%. While grinding, a certain amount of oxidizing compound is added according to the redox property of the blast furnace slag, such as sulfate (about 1 ton of blast furnace slag is added with 1 to 10Kg of oxidizing compound).

[0025] Weigh 150Kg of calcined alumina, 100Kg of ground blast furnace slag, detect its composition, add 130Kg of magnesia, 30Kg of quicklime, 620Kg of silica sand and other mineral raw materials to prepare about 1 ton of batch materials as shown in Table 1, and calculate according to the formula ...

Embodiment 2

[0026] Example 2, take by weighing 225Kg calcined alumina, 80Kg ground blast furnace slag as in Example 1, detect its composition, calculate according to formula, add mineral raw materials such as 98Kg magnesium oxide 55Kg unslaked lime, 559Kg silica sand and be mixed with composition as table 1 About 1 ton of batch material is melted in the tank kiln to melt and draw glass fibers. The glass fiberization temperature is 1358°C, △T 93°C, elastic modulus is 94.2Gpa, and tensile strength is 4610Mpa.

Embodiment 3

[0027] Example 3, take by weighing 175Kg calcined alumina, 60Kg ground blast furnace slag as in Example 1, detect its composition, calculate according to formula, add mineral raw materials such as 122Kg magnesium oxide 27Kg unslaked lime, 600Kg silica sand and be mixed with composition as table 1 About 1 ton of batch material is melted in the tank kiln to melt and draw glass fibers. The glass fiberization temperature is 1349°C, △T 81°C, the elastic modulus is 93.8Gpa, and the tensile strength is 4550Mpa.

[0028]

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Abstract

The invention relates to a high-strength glass fiber which has an excellent mechanical property and a product of the glass fiber. The high-strength glass fiber can serve as an ideal enhancing base material of a high-performance composite material and is applied widely in the fields of windmill blades, space shuttles and the like, which have high requirements for the specific strength and the specific elasticity modulus. The system is characterized in that calcinated aluminum oxide serves as on of the raw materials, impurities in glass compositions are reduced, the diathermancy of molten glass is improved, the energy consumption is reduced, and the stability of glass fiber drawing operation is improved greatly. The glass fiber with the compositions is required to be produced by direct drawing on a specific tank furnace, the electric boosting input energy of the tank furnace accounts for more than 20% of the total energy input, and more than 60% of the electric boosting energy is applied to raw material melting areas. The fiber mainly comprises 56-65 wt.% of SiO2, 18.5-25.8 wt.% of Al2O3, 11.5-23.0 wt.% of RO (RO is sum of CaO, MgO, SrO and BaO), 0.1-1.0 wt.% of CeO2 and 0.1-0.8 wt.% of Li2O.

Description

technical field [0001] The invention relates to a high-strength glass fiber with excellent mechanical properties, which can be used in the field of high-performance composite materials where ordinary glass fibers are difficult to meet the requirements of strength and stiffness. The present invention also relates to high strength fiberglass articles. Background technique [0002] The most common glass composition used to make continuous glass fiber strands is alkali-free glass, which can be used to reinforce resins to obtain composite materials with excellent properties. However, as the application field of alkali-free glass fiber is expanding day by day, the current mechanical properties of alkali-free glass fiber are far from meeting the requirements of light military weapons, aviation parts, special-purpose automobile parts and wind power generation. It is necessary to find composite materials suitable for higher strength, corrosion resistance and high temperature resista...

Claims

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Application Information

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IPC IPC(8): C03C6/10C03C13/00C03B37/02
CPCC03C13/00C03C1/00C03C3/087C03C3/091C03C3/095
Inventor 张志法刘颖赵恒刚李永艳寿业菲徐言超孟宪明王加芳
Owner TAISHAN FIBERGLASS INC
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