Anti-aging lubricating nylon-66 material with appropriate rigidness and flexibility
An anti-aging and nylon technology, applied in the field of engineering plastics modification and engineering plastics rigid-tough balance modification, can solve the problems of nylon materials such as anti-aging properties, processing properties, poor anti-aging properties, and high rigidity, etc., and achieve excellent performance. Effects of physical and mechanical properties, excellent anti-aging properties, and excellent tribological properties
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Embodiment 1
[0029] Nylon 66 with a viscosity of 2.7: 100 parts by mass; glycidyl methacrylate grafted SEBS with a grafting rate of 0.75%: 10 parts by mass; a particle size of 1000 mesh talcum powder: 10 parts by mass; molybdenum disulfide: 2 Parts by mass; channel carbon black: 4 parts by mass; compounding of antioxidant 1098 and antioxidant 168 (1:1): 0.5 parts by mass; oleamide: 2 parts by mass.
[0030] Weigh the raw materials according to the weight ratio of the above components, put them into the high mixer and mix for 5 minutes, put the mixed raw materials into the screw machine to extrude and granulate, the speed of the screw machine is 200 rpm, and the processing temperature is 240-280 °C , to obtain the anti-aging lubricating nylon 66 material involved in the present invention, the tensile strength measured by the national standard is 70MPa, the elongation at break is 30%, the flexural strength is 70MPa, the flexural modulus is 2.5GPa, and the friction coefficient is 0.17.
Embodiment 2
[0032] Nylon 66 with a viscosity of 2.5: 100 parts by mass; glycidyl methacrylate grafted SEBS with a grafting rate of 0.50%: 5 parts by mass; a particle size of 200 mesh talcum powder: 15 parts by mass; molybdenum disulfide: 8 Parts by mass; channel carbon black: 3 parts by mass; antioxidant 1098: 0.5 parts by mass; oleamide: 5 parts by mass.
[0033] The preparation method is the same as in Example 1. The tensile strength measured according to the national standard is 60MPa, the elongation at break is 36%, the bending strength is 74MPa, the bending modulus is 2.2GPa, and the friction coefficient is 0.16.
[0034] After 3500h (temperature 50℃, humidity 95%RH) heat aging, the tensile strength decreased from 60MPa to 53MPa, the bending strength decreased from 75MPa to 66MPa, and the notched impact strength decreased from 6.7kJ / m 2 down to 6.4kJ / m 2 .
Embodiment 3
[0036] Nylon 66 with a viscosity of 3.5: 100 parts by mass; glycidyl methacrylate grafted SEBS with a grafting rate of 1.0%: 25 parts by mass; a particle diameter of 750 mesh talcum powder: 50 parts by mass; molybdenum disulfide: 4 parts by mass; channel carbon black: 5 parts by mass; compounding of antioxidant 1098 and antioxidant 168 (1:1): 1 part by mass; oleamide: 4 parts by mass.
[0037] The preparation method is the same as in Example 1. The tensile strength measured according to the national standard is 74MPa, the elongation at break is 35%, the bending strength is 73MPa, the bending modulus is 2.2GPa, and the friction coefficient is 0.17.
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