Release agent, its preparation method and release paper prepared from the same

A technology of release agent and release coating, which is applied in the direction of special paper, textiles, papermaking, paper, etc., can solve the problem that it is not suitable for large-scale industrial production of release paper, high production cost of release paper, and lack of market competitiveness. problems, to achieve the effect of short heat curing treatment time, low requirements for equipment and operators, and high production efficiency

Inactive Publication Date: 2012-12-12
浙江池河科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] (1) Organosilicone resin release agents use relatively expensive silicone and platinum catalysts as raw materials. During the production process, the curing of the release coating using this type of release agent requires a high temperature above 140°C. Strict equipment requirements lead to high production costs of release paper based on this type of release agent and lack of market competitiveness;
[0009] (2) The release paper produced with polyvinyl alcohol chromium salt as release agent has the risk of chromium pollution to the environment;
[0010] (3) The thermal curing speed of the release coating is slow with the release agent of amino alkyd resin, and the production efficiency is low, so it is not suitable for large-scale industrial production of release paper

Method used

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  • Release agent, its preparation method and release paper prepared from the same
  • Release agent, its preparation method and release paper prepared from the same
  • Release agent, its preparation method and release paper prepared from the same

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0049] The preparation of release agent: get 200g stearic acid, 100g ammonium zirconium carbonate aqueous solution (the mass percentage concentration of ammonium zirconium carbonate aqueous solution is 30%), 700g mass fraction is the polyvinyl alcohol aqueous solution of 8% (the degree of polymerization of polyvinyl alcohol is 1700, degree of alcoholysis 98% to 100%), after mixing evenly, heat to 70°C to 75°C, keep warm for 1h, cool to room temperature and discharge to obtain a white emulsion-like release agent.

[0050] Preparation of release paper: uniformly coat conventional styrene-acrylic latex (Shanghai Zhenzhou Chemical Group Coating Co., Ltd., model A-62), calcium carbonate dispersion (Shunde District, Foshan City) Coating Co., Ltd.), lubricant (Zhejiang Hexin Technology Co., Ltd., model CH / RH346K), dispersant (Zhejiang Hexin Technology Co., Ltd., model CH / FS218M). After drying, complete the release base paper 1 primer treatment, forming a primer layer 2 on one side of...

Embodiment 2

[0052] The preparation of release agent: get 300g stearic acid, 150g ammonium zirconium carbonate aqueous solution (the mass percentage concentration of ammonium zirconium carbonate aqueous solution is 30%), 550g mass fraction is the polyvinyl alcohol aqueous solution of 8% (the degree of polymerization of polyvinyl alcohol is 1700, degree of alcoholysis 98% to 100%), after mixing evenly, heat to 70°C to 75°C, keep warm for 1h, cool to room temperature and discharge to obtain a white emulsion-like release agent.

[0053] The release paper was prepared according to the method of Example 1, except that the heat curing treatment temperature was 120° C., and the heat curing treatment time was 2.5 minutes.

Embodiment 3

[0055] The preparation of release agent: get 300g stearic acid, 150g aqueous solution of potassium zirconium carbonate (the mass percent concentration of aqueous solution of potassium zirconium carbonate is 30%), 550g mass fraction is the polyvinyl alcohol aqueous solution of 8% (the degree of polymerization of polyvinyl alcohol is 1700, degree of alcoholysis 98% to 100%), after mixing evenly, heat to 70°C to 75°C, keep warm for 1h, cool to room temperature and discharge to obtain a white emulsion-like release agent.

[0056] The release paper was prepared according to the method of Example 1, except that the heat curing treatment temperature was 120° C., and the heat curing treatment time was 2.5 minutes.

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Abstract

The invention discloses a release agent, which comprises the following raw materials by weight part: 10-50 of fatty acid; 5-20 of a zirconium saline solution; and 30-70 of a polyvinyl alcohol aqueous solution. The invention also discloses a preparation method of the release agent, and the method comprises the following steps of: mixing the fatty acid, the zirconium saline solution and the polyvinyl alcohol aqueous solution uniformly, heating the mixture to 60DEG C-80DEG C, conducting heat preservation for 0.5h-1h, and cooling the mixture to room temperature, thus obtaining the release agent. The invention also discloses release paper, which is composed of release base paper and a ground coat as well as a release coat that are successively attached to one side of the release base paper surface. The release coat is formed by subjecting the release agent to coating and heat curing treatments. The release agent provided in the invention has cheap and easily available raw materials. The preparation method of the release agent is simple, and has small pollution to the environment. The release paper prepared from the release agent has a short heat curing time, so that the release agent is suitable for industrialized production.

Description

technical field [0001] The invention relates to the field of artificial leather processing and manufacturing, in particular to a release agent, a preparation method thereof, and a release paper prepared by using the release agent. Background technique [0002] Release paper, also known as release paper, is a special coated anti-adhesive paper, which can prevent prepreg from sticking and protect prepreg from contamination. [0003] Usually, during the manufacture of artificial leather (such as polyurethane synthetic leather and PVC artificial leather), release paper is used as a carrier and a temporary template. The release paper used in the production of artificial leather usually has a double-layer structure: The first layer is the release base paper as the substrate, and the second layer is the release coating. The general manufacturing method is to first coat a layer of primer on the release base paper to prevent the penetration of the release agent, and then coat the re...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D129/04C09D7/12D21H27/00
Inventor 陈冬平
Owner 浙江池河科技有限公司
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