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Fire retardant

A technology of flame retardants and accelerators, applied in the field of flame retardants, can solve the problems of reduced mechanical properties of flame retardant materials, poor compatibility of polymer matrix, etc., to achieve improved compatibility, good compatibility, and improved carbon formation speed effect

Inactive Publication Date: 2013-01-09
SHANDONG CHANGXING GROUP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Red phosphorus and ammonium polyphosphate are common components of phosphorus-based flame retardants and nitrogen-phosphorus composite intumescent flame retardants. Due to the high phosphorus content, the flame retardant effect is good and the flame retardant efficiency is also high. Ammonium polyphosphate also has chemical Good stability, low hygroscopicity, excellent dispersibility, small specific gravity, low toxicity, etc., but red phosphorus and ammonium polyphosphate have the defect of poor compatibility with the polymer matrix, resulting in a decrease in the mechanical properties of flame retardant materials

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] A flame retardant, the percentage of each component in the total weight of the flame retardant is: epoxy resin coated ammonium polyphosphate 50%, pentaerythritol 12%, melamine 5%, coated red phosphorus 10%, magnesium hydroxide 5% , aluminum hydroxide 8%, zinc borate 5%, silicon dioxide 1%, titanium dioxide 1%, nickel silicate 0.5%, manganese silicate 1.5%, γ-aminopropyltriethoxysilane 1%.

Embodiment 2

[0021] A flame retardant, the percentage of each component in the total weight of the flame retardant is: epoxy resin coated ammonium polyphosphate 45%, pentaerythritol 15%, melamine 3%, coated red phosphorus 7%, magnesium hydroxide 7% , aluminum hydroxide 10%, zinc borate 6%, silicon dioxide 1%, titanium dioxide 1%, nickel silicate 1%, manganese silicate 3%, γ-methacryloxytrimethoxysilane 1%.

Embodiment 3

[0023] A flame retardant, the percentage of each component in the total weight of the flame retardant is: epoxy resin coated ammonium polyphosphate 55%, pentaerythritol 10%, melamine 4%, coated red phosphorus 5%, magnesium hydroxide 6% , aluminum hydroxide 5%, zinc borate 7%, silicon dioxide 1.5%, titanium dioxide 1.5%, nickel silicate 0.5%, manganese silicate 1.5%, N-β-aminoethyl-γ-aminopropyltrimethoxy Silane 3%.

[0024] In order to investigate the flame retardant effect of the flame retardant of the present invention, the products of Examples 1-3 are added to polyamide-6 (nylon 6) according to the addition amount of 25% (wt), and compared with no flame retardant Compared with polyamide-6, JF-3 type oxygen index instrument is used to test the oxygen index and vertical combustion performance according to GB2406-80 standard and UL-94 standard, and test the tensile strength of the sample according to GB / T 1039-92 standard performance. The test results show that the vertical ...

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Abstract

The invention discloses a fire retardant, belonging to the field of fire-proof technology. The fire retardant comprises the components by weight percent: 45-55% of epoxy resin coated ammonium polyphosphate, 10-15% of pentaerythritol, 3-5% of melamine, 5-10% of coated red phosphorus, 5-10% of magnesium hydroxide, 5-10% of aluminium hydroxide, 5-10% of zinc borate, 1-5% of carbon formation accelerator, 1-5% of smoke suppression agent and 0.5-3% of coupling reagent. The fire retardant is capable of inhibiting flame combustion and smoldering, can be smeared or sprayed onto any object so as to guarantee the object to be only carbonized without burning, has good compatibility with material, can be evenly dispersed on the material which is prevented from burning, and has better affinity; the fire retardant is high in stability, so that the physical and technical performances of the material mixed with the fire retardant are not influenced; and the fire retardant causes less smoke during burning and does not generate poisonous gas, thus belonging to environment-friendly fire retardant and being added into materials such as plastics, paint, and rubber.

Description

technical field [0001] The invention relates to the field of flame retardant technology, in particular to a flame retardant. Background technique [0002] At present, the polymer material industry is developing rapidly and its application fields are constantly expanding. However, it has the characteristics of flammability. In fields with high safety requirements, such as chemical building materials, electronic appliances, transportation, aerospace, daily furniture, interior decoration And other fields, the application of flame retardant polymer materials is increasing. [0003] Flame retardants added to polymer materials are mainly divided into halogen-based flame retardants, phosphorus-based flame retardants, nitrogen-phosphorus composite intumescent flame retardants, and inorganic flame retardants. Red phosphorus and ammonium polyphosphate are common components of phosphorus-based flame retardants and nitrogen-phosphorus composite intumescent flame retardants. Due to the ...

Claims

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Application Information

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IPC IPC(8): C08K13/06C08K9/10C08K3/32C08K5/053C08K5/3492C08K3/02C08K3/22C08K3/38C08K3/36C08K3/34C08L77/02
Inventor 朱玉国
Owner SHANDONG CHANGXING GROUP
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