Color filter, liquid crystal display components and color filter manufacturing method
A technology for a color filter and a manufacturing method, which are applied in the field of color filters and can solve the problems of deterioration of coloring patterns, poor reliability, and reduced display quality of liquid crystal display elements.
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example 1
[0773] [[I] Synthesis of Alkali Soluble Resin (IA)]
[0774] 5 parts by mass of 2,2'-azobis(2,4-dimethylvaleronitrile) and 220 parts by mass of diethylene glycol methyl ethyl ether were placed in a flask equipped with a condenser and a stirrer. Next, 18 mass parts of methacrylic acid as (I-1) compound, 14 mass parts of 2-methylglycidyl methacrylate and 20 mass parts of glycidyl methacrylate as (1-2) compound were charged. Parts, 10 parts by mass of styrene as (I-4) compound, tricyclic methacrylic acid [5.2.1.0 2,6 ] 23 parts by mass of decane-8-yl ester and 15 parts by mass of methyl methacrylate, after nitrogen substitution, the temperature of the solution was raised to 70° C. while gently stirring, and the temperature was maintained for 5 hours to perform polymerization. Thus, a solution containing the alkali-soluble resin (IA) as a copolymer was obtained. The solid content concentration of the obtained polymer solution was 31.5%, and the Mw of the alkali-soluble resin (IA...
example 2
[0776] [[I] Synthesis of alkali-soluble resin (IB)]
[0777] 4 mass parts of AIBN and 300 mass parts of diethylene glycol methyl ethyl ether are charged into a flask with a condenser tube and a stirrer, followed by 23 mass parts of methacrylic acid as (I-1) compound, as (I-4) 10 parts by mass of styrene, 32 parts by mass of benzyl methacrylate and 35 parts by mass of methyl methacrylate of the compound were further charged with 2.7 parts by mass of α-methylstyrene dimer, and stirred slowly while stirring The temperature of the solution was raised to 80° C., maintained at this temperature for 4 hours, then raised to 100° C., and polymerized at this temperature for 1 hour to obtain a solution containing a copolymer. The solid content concentration of the obtained polymer solution was 24.9%, and Mw was 12,500. Next, 1.1 parts by mass of tetrabutylammonium bromide and 0.05 parts by mass of 4-methoxyphenol as a polymerization inhibitor were added to the obtained solution containin...
example 3
[0779] [Preparation of coloring composition]
[0780] Ethylene oxide-modified dipentaerythritol hexaacrylate (II-1) as a polymerizable compound (II-1) and polyfunctional acrylic acid were mixed with 90 parts by mass of the alkali-soluble resin (IA) as a copolymer obtained in Example 1. A mixture of ester compounds (KAYARAD (registered trademark) DPHA-40H, Nippon Kayaku Co., Ltd.) (II-2) mixture (mixing ratio ((II-1) / (II-2)) = 4) 100 parts by mass, as [III] 2-methyl-1-(4-methylthienyl)-2-morpholinopropan-1-one (Irgacure 907, Ciba Specialty Chemical Co., Ltd.) of polymerization initiator (III-1) 25 Parts by mass, 100 parts by mass of red colorant (IV-1) containing red dye as [IV] colorant, pentaerythritol tetrakis(3-mercaptopropionate) ester (V-1) and 3- Mixture of ethyl sulfanilate (V-2) (mixing ratio ((V-1) / (V-2)=5)) 6 parts by mass, alkali-soluble resin obtained in Example 2 as another alkali-soluble resin (IB) 10 parts by mass. Next, cyclohexanone was used as a solvent, a...
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