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Method for preparing conductive high molecular material coated metal-based inert electrode material

A technology of conductive polymers and inert electrodes, which is applied in the manufacture of cables/conductors, circuits, electrical components, etc., can solve the problems of low conductivity of composite materials, achieve improved electrocatalytic activity, good metal anti-corrosion effect, and reduce energy consumption Effect

Active Publication Date: 2015-07-01
KUNMING HENDERA SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The conductive polymer materials prepared in this way have the common properties of conductive polymers and inorganic materials, but the conductivity of the prepared composite materials is still low, and the processed molding materials are still mainly coatings or films.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Step (1): Take a piece of lead-silver alloy test piece of 0.5cm×3cm×4cm, wash it with deionized water for 3 to 5 times, then soak it in acetone solution for 2 to 5 minutes, take out the test piece, and use Wash with hot water at a temperature of 80°C to 90°C for 1 to 3 times, then rinse with deionized water for 1 to 3 times, and then blow dry.

[0023] Step (2): Weigh 1.5g of polymethyl methacrylate (PMMA) and 0.5g of polyvinyl chloride (PVC), add to 40ml of tetrahydrofuran, seal with plastic wrap, and magnetically stir until dissolved (it takes about 60 minutes).

[0024] Step (3): Add 1.5g of polyaniline (PNAI) into 30ml of tetrahydrofuran under stirring and fully disperse. Then mix with the solution prepared in step (2), and ultrasonically disperse for 30 minutes. Continue to stir vigorously for about 50 minutes to fully mix and disperse the two (the total volume is about 60ml), continue to stir to evaporate the solvent, and heat it to 45°C to speed up the evaporati...

Embodiment 2

[0028] Step (1): Take a piece of aluminum test piece of 0.5cm×3cm×4cm, wash it with deionized water for 3 to 5 times, then soak it in acetone solution for 2 to 5 minutes, take out the test piece, and then use a temperature of Wash in hot water at 80°C to 90°C for 1 to 3 times, then rinse with deionized water for 1 to 3 times, and then blow dry.

[0029] Step (2): Weigh 2g of polymethyl methacrylate (PMMA) and 1g of polyvinyl chloride (PVC), add it to 80ml of chloroform several times, seal it with plastic wrap, and stir magnetically until dissolved (it takes about 140min) .

[0030] Step (3): Add 2.5g of polyaniline (PNAI) into 30ml of chloroform under stirring and fully disperse. Then mix with the solution prepared in step (2), and ultrasonically disperse for 30 minutes. Continue to stir vigorously for about 50 minutes to fully mix and disperse the two (the total volume is about 80ml), continue to stir to evaporate the solvent, and heat it to 60°C to speed up the evaporation...

Embodiment 3

[0034] Step (1): Take a 0.5cm×3cm×4cm titanium plate test piece, wash it with deionized water for 3 to 5 times, then soak it in acetone solution for 2 to 5 minutes, take out the test piece, and then use temperature Wash in hot water at 80°C to 90°C for 1 to 3 times, then rinse with deionized water for 1 to 3 times, and then blow dry.

[0035] Step (2): Weigh 1.5g polymethyl methacrylate (PMMA) and 0.5g polyvinyl chloride (PVC), add to 40ml tetrahydrofuran, seal with plastic wrap, and stir until dissolved (about 60min).

[0036] Step (3): Add 1.5g of polypyrrole (PPy) into 30ml of tetrahydrofuran under stirring and fully disperse. Then mix with the solution prepared in step (2), and ultrasonically disperse for 30 minutes. Continue to stir vigorously for about 50 minutes to fully mix and disperse the two (the total volume is about 60ml), continue to stir to evaporate the solvent, and heat it to 45°C to speed up the evaporation. Until the solution is volatilized until the solut...

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PUM

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Abstract

The invention discloses a method for preparing a conductive high molecular material coated metal-based inert electrode material. The method comprises the following three steps: (1) preparing a metal framework substrate; (2) preparing a conductive high molecular coating material; and (3) coating the conductive high molecular coating material on the metal framework substrate. The prepared conductive high molecular material coated metal-based inert electrode material can obviously improve the electrocatalytic activity of a plate electrode and the corrosion resistance of a polar plate and is particularly suitable for a chloride system or a sulfate system containing high chloride ion content; and the composite material can be used for inert anodes, battery electrodes, sensor devices, capacitor electrodes and the like in the wet metallurgical extraction process of nonferrous metals, and the energy consumption can be obviously reduced in the electrodeposition process of the nonferrous metals.

Description

technical field [0001] The invention relates to a preparation method of a metal-based inert electrode material coated with a conductive polymer material, which is mainly used in an electrochemical process. Background technique [0002] Conductive polymer materials (polyaniline, polypyrrole, polythiophene) have become one of the fastest-growing functional materials due to their good chemical stability, electrochemical reversibility, and excellent metal anti-corrosion properties. Based on conductive polymer materials, many new technologies are currently being developed, such as sensor elements, electrode materials, all-plastic metal anti-corrosion technology, ship anti-fouling technology, solar cells, electromagnetic shielding technology, anti-static technology, electrochromism and stealth technology etc. However, the conductive polymer materials obtained by chemical oxidation or electrochemical oxidation are all powders, which are difficult to form and process, and their ele...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01B13/00C09D179/02C09D179/04C09D165/00C09D133/12C09D127/06
Inventor 郭忠诚付仁春
Owner KUNMING HENDERA SCI & TECH
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