Waterborne acrylic macromolecular compound as well as preparation method and application thereof

A polymer compound and water-based acrylic technology, which can be used in biocide-containing paints, anti-fouling/underwater coatings, coatings, etc., and can solve the problems of high raw material costs and limited practical applications

Inactive Publication Date: 2013-02-06
OCEAN UNIV OF CHINA
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Although this type of polymer metal salt is environmentally friendl

Method used

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  • Waterborne acrylic macromolecular compound as well as preparation method and application thereof
  • Waterborne acrylic macromolecular compound as well as preparation method and application thereof
  • Waterborne acrylic macromolecular compound as well as preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0131] Embodiment 1: Preparation of water-based acrylic polymer compound

[0132] The implementation steps of this embodiment are as follows:

[0133] A. According to the weight ratio of the total amount of monomers to water of 1, 10 parts by weight of acrylamide, 10 parts by weight of hydroxyethyl acrylate, 30 parts by weight of acryloyloxyethyltrimethylammonium chloride and 5 parts by weight of acrylic acid dissolved in water to obtain a monomer mixture solution; then,

[0134] B. Add 0.005% azobisisobutylamidine hydrochloride initiator to the monomer mixture solution obtained in step A to obtain a monomer mixture solution containing the initiator; then,

[0135] C. Under stirring conditions, add the monomer mixture solution containing the initiator obtained in step B to 110 parts by weight of water within 0.5 hours at a temperature of 50°C for copolymerization to obtain the water-based acrylic acid Polymer compound SBM-1 solution;

[0136] The solid content of the aqueou...

Embodiment 2

[0138] Embodiment 2: Preparation of water-based acrylic polymer compound

[0139] The implementation steps of this embodiment are as follows:

[0140] A. According to the weight ratio of the total amount of monomers to water of 10, 40 parts by weight of methylol acrylamide, 30 parts by weight of hydroxypropyl acrylate, and 70 parts by weight of methacryloxyethyl dimethyl benzyl chloride Ammonium chloride and 35 parts by weight of methacrylic acid are dissolved in water to obtain a monomer mixture solution; then,

[0141] B, adding 1% azobisisobutylimidazoline hydrochloride initiator in the monomer mixture solution obtained in step A in terms of the total weight of the above monomers, to obtain a monomer mixture solution containing the initiator; then ,

[0142] C. Under the condition of stirring, drop the monomer mixture solution containing the initiator obtained in step B into 1100 parts by weight of water within 4 hours at a temperature of 70°C to carry out copolymerizatio...

Embodiment 3

[0144] Embodiment 3: Preparation of water-based acrylic polymer compound

[0145] The implementation steps of this embodiment are as follows:

[0146] A. According to the weight ratio of the total amount of monomers to water of 4, 20 parts by weight of hydroxyethylacrylamide, 40 parts by weight of hydroxybutyl acrylate, and 45 parts by weight of 3-acrylamidopropyltrimethylammonium chloride Dissolve in water with 15 parts by weight of methacrylic acid, obtain a kind of monomer mixture solution; Then,

[0147] B, adding 1% azodicyanovaleric acid initiator in the monomer mixture solution obtained in step A in terms of the total weight of the above-mentioned monomers, to obtain a monomer mixture solution containing the initiator; then,

[0148] C, under the condition of stirring, the monomer mixture solution containing the initiator obtained in step B is added dropwise to 520 parts by weight in 15% ethanol aqueous solution by weight to carry out copolymerization reaction at a tem...

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Abstract

The invention relates to a waterborne acrylic macromolecular compound and salts thereof, as well as preparation methods and applications thereof. The method comprises the following steps of: dissolving hydrophilic acrylic monomers containing amino, acrylic monomers containing hydroxyl, acrylic monomers containing quaternary ammonium salts and acrylic monomers containing carboxyl in water, then adding a water-soluble azo compound as an initiator, and dropwise adding the monomer hybrid solution containing the initiator to water or alcohol-water solution for copolymerization reaction. Stain-proof paints prepared by using metal salts of the waterborne acrylic macromolecular compound can effectively prevent adhesion of fouling organism in seawater, and have the advantage of being environment-friendly.

Description

【Technical field】 [0001] The invention belongs to the technical field of polymer materials. More specifically, the present invention relates to a water-based acrylic polymer compound, a preparation method of the compound, and an application of the compound. 【Background technique】 [0002] The surface of marine facilities immersed in seawater will form a complex biofouling layer due to biological action. This phenomenon of organisms attaching to the surface of marine installations and causing them to be adversely affected is called marine biofouling. Marine biofouling is extremely harmful. As far as ships are concerned, on the one hand, it will accelerate the corrosion of the hull and shorten the service life of the ship; on the other hand, it will increase the weight of the hull itself, which will increase the resistance of the ship's navigation, thereby reducing the speed of the ship and increasing fuel consumption. . According to statistics, when the marine biofouling r...

Claims

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Application Information

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IPC IPC(8): C08F220/34C08F220/56C08F220/28C08F220/06C08F4/04C08F2/10C08F220/58C08F220/60C08F8/44C09D133/02C09D133/14C09D5/16
Inventor 董磊闫雪峰于良民李昌诚姜晓晖李霞赵海洲张志明夏树伟倪春花
Owner OCEAN UNIV OF CHINA
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