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Device for preparing nanofibers on large scale by utilizing electrostatic spinning process and preparation method

An electrospinning process, nanofiber technology, applied in fiber processing, textile and papermaking, filament/thread forming, etc., can solve the problems of single quality of nanofiber web, jet electrostatic interference, fixed number and position of needles, etc. The device has a simple structure, avoids needle blockage, and achieves the effect of morphological structure

Inactive Publication Date: 2015-01-07
XI'AN POLYTECHNIC UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The above methods have achieved varying degrees of success in increasing the yield of nanofibers, but they also have the following defects: For the multi-needle method, the distance between the needles should not be too small, otherwise it will easily form electrostatic interference between the jets and affect the volatilization of the solvent and the refinement of fiber diameter, and may cause needle clogging, and the number and position of needles are relatively fixed, which cannot be changed according to actual needs, and the quality of the obtained nanofiber web is relatively simple; The position is not fixed, and the convex curvature is unstable, so that the diameter uniformity of the final nanofiber is poor
In the porous tube method, although the position of the Taylor cone is relatively fixed, and the curvature of the droplet tip is relatively stable, the collection method is deposited along the circumferential direction, which limits the increase in the area of ​​the nanofibrous web.

Method used

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  • Device for preparing nanofibers on large scale by utilizing electrostatic spinning process and preparation method
  • Device for preparing nanofibers on large scale by utilizing electrostatic spinning process and preparation method
  • Device for preparing nanofibers on large scale by utilizing electrostatic spinning process and preparation method

Examples

Experimental program
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Effect test

Embodiment 1

[0056] The polyacrylonitrile (PAN) (M w =100,000g·mol -1 ) Dissolved in N,N-dimethylformamide (DMF) to prepare a spinning solution with a concentration of 15wt%; in an environment with room temperature and relative humidity of 35%, inject the spinning solution into the storage tank , The metal electrode at the bottom of the reservoir is connected to the positive electrode of the high-voltage generator, the applied voltage is 10kV, the receiving distance (the distance between the spinneret and the base material layer) is 10cm, and the spinning time is 8h. Under this condition, electrostatic After spinning, a uniform nanofiber web attached to the surface of the base material was obtained, and the nanofiber web was peeled off. The square meter weight of the nanofiber web was measured to be about 51.85g·m -2 .

Embodiment 2

[0058] Dissolve polyvinyl alcohol (PVA) 1788 type powder in distilled water at 70°C to form a spinning solution with a concentration of 16wt%; in an environment with room temperature and relative humidity of 55%, pour the spinning solution into the storage tank The metal electrode at the bottom of the reservoir is connected to the positive electrode of the high-voltage generator, the applied voltage is 14kV, the receiving distance (the distance between the spinneret and the base material layer) is 14cm, and the spinning time is 10h. Electrospinning obtains a uniform nanofiber network attached to the surface of the base material. After peeling it off, the square meter weight of the nanofiber network is about 73.61g·m. -2 .

Embodiment 3

[0060] Put polyethylene oxide (PEO) (M w =3×10 5 g·mol -1 1) Dissolve in distilled water at 60°C to prepare a spinning solution with a concentration of 13wt%; in an environment of room temperature and relative humidity of 45%, inject the spinning solution into the storage tank, and the metal electrode at the bottom of the storage tank Connected to the positive pole of the high-voltage generator, the applied voltage is 12kV, the receiving distance (the distance between the spinneret and the base material layer) is 12cm, and the spinning time is 9h. Electrospinning is carried out under these conditions to obtain adhesion to the substrate The uniform nanofiber network on the surface of the material is peeled off, and the measured weight per square meter of the nanofiber network is about 54.88g·m -2 .

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Abstract

The invention discloses a system for preparing nanofibers on a large scale by utilizing the electrostatic spinning process and a preparation method. The system comprises a vertical electrostatic spinning device, a substrate layer is arranged on the top of the vertical electrostatic spinning device, both ends of the substrate layer are respectively wound on a roller, both rollers are connected with motors, a collector is arranged on the top of the substrate layer, the vertical electrostatic spinning device comprises a reservoir, a lower needle plate and an upper needle plate are arranged in the reservoir, both ends of the two needle plates are respectively connected with a link mechanism through limit wheels, one end of the link mechanism is connected with a cam driving mechanism, the other end of the link mechanism is connected with a spring, spinning jets are arranged on the needle plates, metal electrodes are arranged on the bottom of the reservoir, and are connected with the anode of a direct-current high voltage generator and the lower ends of the spinning jets, and the cathode of the direct-current high voltage generator is grounded and connected with the collector. The invention also discloses the method for preparing nanofibers by utilizing the system. The system has a simple structure and high expansibility, the diameter uniformity of the prepared nanofibers is good, and the nanofibers can be widely used in fields, such as filtration, medical chemical and energy.

Description

Technical field [0001] The invention belongs to the technical field of electrospinning, and relates to a device for preparing nanofibers on a large scale by using an electrospinning process. The invention also relates to a method for preparing nanofibers by using the device. Background technique [0002] Nanofibers have a great specific surface area and length-to-diameter ratio, fine microstructure, extremely high porosity, extremely strong interpenetration with other substances, excellent flexibility, adsorption, filtration, and adhesion And heat preservation, as well as power, light, electricity, heat, magnetism and other properties. These remarkable properties make nanofibers have great application prospects in many important fields, such as: super filter materials, ion exchange system absorption and separation materials, exhaust and industrial sewage treatment materials, gas masks, protective clothing, waterproof and breathable fabrics, sound absorption Noise materials, comp...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01D5/00
Inventor 刘呈坤张建春来侃孙润军陈美玉姚穆
Owner XI'AN POLYTECHNIC UNIVERSITY
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