System for preparing nanofibers on large scale by utilizing electrostatic spinning process and preparation method

An electrospinning process and nanofiber technology, applied in fiber processing, textiles and papermaking, filament/thread forming, etc., can solve the problems of fixed number and position of needles, single quality of nanofiber web, jet static interference, etc., to achieve Realize the effect of morphological structure, simple device structure and avoid needle clogging

Inactive Publication Date: 2013-02-27
XI'AN POLYTECHNIC UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The above methods have achieved varying degrees of success in increasing the yield of nanofibers, but they also have the following defects: For the multi-needle method, the distance between the needles should not be too small, otherwise it will easily form electrostatic interference between the jets and affect the volatilization of the solvent and the refinement of fiber diameter, and may cause needle clogging, and the number and position of needles are relatively fixed, which cannot be changed according to actual needs, and the quality of the obtained nanofiber web is relatively simple; The position is not fixed, and the convex curvature is unstable, so that the diameter uniformity of the final nanofiber is poor
In the porous tube method, although the position of the Taylor cone is relatively fixed, and the curvature of the droplet tip is relatively stable, the collection method is deposited along the circumferential direction, which limits the increase in the area of ​​the nanofibrous web.

Method used

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  • System for preparing nanofibers on large scale by utilizing electrostatic spinning process and preparation method
  • System for preparing nanofibers on large scale by utilizing electrostatic spinning process and preparation method
  • System for preparing nanofibers on large scale by utilizing electrostatic spinning process and preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0056] Polyacrylonitrile (PAN) (M w =100,000g·mol -1 ) was dissolved in N,N-dimethylformamide (DMF) to prepare a spinning solution with a concentration of 15wt%; at room temperature and a relative humidity of 35%, the spinning solution was injected into the storage tank , the metal electrode at the bottom of the liquid storage tank is connected to the positive pole of the high-voltage generator, the applied voltage is 10kV, the receiving distance (the distance between the spinneret and the base material layer) is 10cm, and the spinning time is 8h. After spinning, a uniform nanofibrous web attached to the surface of the base material was obtained, which was removed, and the square meter weight of the nanofibrous web was measured to be about 51.85g m -2 .

Embodiment 2

[0058] Dissolve polyvinyl alcohol (PVA) 1788 powder in distilled water at 70°C to prepare a spinning solution with a concentration of 16wt%; inject the spinning solution into the storage tank at room temperature and relative humidity of 55% Among them, the metal electrode at the bottom of the liquid storage tank is connected to the positive pole of the high voltage generator, the applied voltage is 14kV, the receiving distance (the distance between the spinneret and the base material layer) is 14cm, and the spinning time is 10h, under these conditions Electrospinning obtained a uniform nanofibrous web attached to the surface of the base material, which was removed, and the square meter weight of the nanofibrous web was measured to be about 73.61g m -2 .

Embodiment 3

[0060] Polyethylene oxide (PEO) (M w =3×10 5 g·mol -1 ) was dissolved in 60°C distilled water to prepare a spinning solution with a concentration of 13wt%; at room temperature and a relative humidity of 45%, the spinning solution was injected into the storage tank, and the metal electrode at the bottom of the storage tank Connect to the positive pole of the high-voltage generator, the applied voltage is 12kV, the receiving distance (the distance between the spinneret and the substrate material layer) is 12cm, and the spinning time is 9h. Electrospinning is carried out under these conditions to obtain the The uniform nanofibrous web on the surface of the material is peeled off, and the measured square meter weight of the nanofibrous web is about 54.88g m -2 .

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Abstract

The invention discloses a system for preparing nanofibers on a large scale by utilizing the electrostatic spinning process and a preparation method. The system comprises a vertical electrostatic spinning device, a substrate layer is arranged on the top of the vertical electrostatic spinning device, both ends of the substrate layer are respectively wound on a roller, both rollers are connected with motors, a collector is arranged on the top of the substrate layer, the vertical electrostatic spinning device comprises a reservoir, a lower needle plate and an upper needle plate are arranged in the reservoir, both ends of the two needle plates are respectively connected with a link mechanism through limit wheels, one end of the link mechanism is connected with a cam driving mechanism, the other end of the link mechanism is connected with a spring, spinning jets are arranged on the needle plates, metal electrodes are arranged on the bottom of the reservoir, and are connected with the anode of a direct-current high voltage generator and the lower ends of the spinning jets, and the cathode of the direct-current high voltage generator is grounded and connected with the collector. The invention also discloses the method for preparing nanofibers by utilizing the system. The system has a simple structure and high expansibility, the diameter uniformity of the prepared nanofibers is good, and the nanofibers can be widely used in fields, such as filtration, medical chemical and energy.

Description

technical field [0001] The invention belongs to the technical field of electrospinning, and relates to a device for large-scale preparation of nanofibers by using an electrospinning process, and also relates to a method for preparing nanofibers by using the above device. Background technique [0002] Nanofibers have a large specific surface area and length-to-diameter ratio, fine microstructure, high porosity, strong interpenetration with other substances, excellent flexibility, adsorption, filterability, and adhesion And thermal insulation, as well as force, light, electricity, heat, magnetic and other properties. These remarkable properties make nanofibers have great application prospects in many important fields, such as: super filter materials, ion exchange system absorption and separation materials, tail gas and industrial sewage treatment materials, gas masks, protective clothing, waterproof and breathable fabrics, sound-absorbing materials, etc. Noise materials, comp...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01D5/00
Inventor 刘呈坤张建春来侃孙润军陈美玉姚穆
Owner XI'AN POLYTECHNIC UNIVERSITY
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