System for preparing nanofibers on large scale by utilizing electrostatic spinning process and preparation method
An electrospinning process and nanofiber technology, applied in fiber processing, textiles and papermaking, filament/thread forming, etc., can solve the problems of fixed number and position of needles, single quality of nanofiber web, jet static interference, etc., to achieve Realize the effect of morphological structure, simple device structure and avoid needle clogging
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Embodiment 1
[0056] Polyacrylonitrile (PAN) (M w =100,000g·mol -1 ) was dissolved in N,N-dimethylformamide (DMF) to prepare a spinning solution with a concentration of 15wt%; at room temperature and a relative humidity of 35%, the spinning solution was injected into the storage tank , the metal electrode at the bottom of the liquid storage tank is connected to the positive pole of the high-voltage generator, the applied voltage is 10kV, the receiving distance (the distance between the spinneret and the base material layer) is 10cm, and the spinning time is 8h. After spinning, a uniform nanofibrous web attached to the surface of the base material was obtained, which was removed, and the square meter weight of the nanofibrous web was measured to be about 51.85g m -2 .
Embodiment 2
[0058] Dissolve polyvinyl alcohol (PVA) 1788 powder in distilled water at 70°C to prepare a spinning solution with a concentration of 16wt%; inject the spinning solution into the storage tank at room temperature and relative humidity of 55% Among them, the metal electrode at the bottom of the liquid storage tank is connected to the positive pole of the high voltage generator, the applied voltage is 14kV, the receiving distance (the distance between the spinneret and the base material layer) is 14cm, and the spinning time is 10h, under these conditions Electrospinning obtained a uniform nanofibrous web attached to the surface of the base material, which was removed, and the square meter weight of the nanofibrous web was measured to be about 73.61g m -2 .
Embodiment 3
[0060] Polyethylene oxide (PEO) (M w =3×10 5 g·mol -1 ) was dissolved in 60°C distilled water to prepare a spinning solution with a concentration of 13wt%; at room temperature and a relative humidity of 45%, the spinning solution was injected into the storage tank, and the metal electrode at the bottom of the storage tank Connect to the positive pole of the high-voltage generator, the applied voltage is 12kV, the receiving distance (the distance between the spinneret and the substrate material layer) is 12cm, and the spinning time is 9h. Electrospinning is carried out under these conditions to obtain the The uniform nanofibrous web on the surface of the material is peeled off, and the measured square meter weight of the nanofibrous web is about 54.88g m -2 .
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