Washing agent and washing process for Solar solar cell silicon wafer washing agent and washing process thereof

A technology of cleaning agent for solar cells and silicon wafers, applied in the directions of detergent compounding agent, detergent composition, surface active detergent composition, etc., can solve the problems of difficult control, large amount of thinning, poor process stability, etc. Increased decontamination ability, improved yield, and low equipment requirements

Active Publication Date: 2013-03-06
绍兴拓邦新能源股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Rough polishing uses a higher concentration of sodium hydroxide solution to react with silicon wafers. Although the surface damage layer can be removed and surface pollutants can be removed to a certain extent, after rough polishing, the surface solution of silicon wafers remains more alkali, and the amount of thinning is very small. Large, difficult to control, and have a great impact on s

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] 1. Prepare solar cell silicon wafer cleaning solution:

[0028] Take a 5L glass beaker, add 4L deionized water, then add 0.025g triethanolamine oleate, 0.059g isomeric alcohol polyoxyethylene ether, 0.072g sodium acetate, 0.056g sodium carbonate, 0.064g sodium sulfate and 0.28g sodium silicate , stir evenly, and prepare a cleaning agent; add 80L of deionized water to the pre-cleaning tank, and add 4L of the above-mentioned cleaning agent to obtain a cleaning solution.

[0029] 2. Surface cleaning of silicon wafers for solar cells:

[0030] At room temperature, add 400pcs of silicon wafers into the cleaning solution for cleaning for 3 minutes, then put them into deionized water for rinsing, and then replenish the cleaning solution. Add 72ml of cleaning agent after every 20 batches of cleaning, and then circulate the rehydration. Complete mass production.

Embodiment 2

[0032] 1. Prepare solar cell silicon wafer cleaning solution:

[0033] Take a 10L glass beaker, add 5L deionized water, then add 0.04g triethanolamine oleate, 0.01g sodium lauryl sulfate, 0.1g sodium acetate, 0.092g sodium carbonate, 0.095g sodium sulfate and 0.07g sodium silicate, Stir evenly, and prepare a cleaning agent; add 100L deionized water to the pre-cleaning tank, and add 5L of the above-mentioned cleaning agent to obtain a cleaning solution.

[0034] 2. Surface cleaning of silicon wafers for solar cells:

[0035] At room temperature, add 400pcs of silicon wafers into the cleaning solution for cleaning for 4 minutes, then put them into deionized water for rinsing, and then replenish the cleaning solution, and add 100ml of cleaning agent after every 20 batches of cleaning, so as to circulate the rehydration Complete mass production.

Embodiment 3

[0037] 1. Prepare solar cell silicon wafer cleaning solution:

[0038] Take a 10L glass beaker, add 6L deionized water, then add 0.03g Triton X-100, 0.24g sodium acetate, 0.27g sodium carbonate, 0.18g sodium sulfate and 0.15g sodium silicate, stir well, and prepare a cleaning agent ; Add 150L of deionized water to the pre-cleaning tank, and add 6L of the cleaning agent prepared above to obtain the cleaning solution.

[0039] 2. Surface cleaning of silicon wafers for solar cells:

[0040] At room temperature, add 400pcs of silicon wafers into the cleaning solution for cleaning for 6 minutes, then put them into deionized water for rinsing, and then replenish the cleaning solution. After every 20 batches of cleaning, add 105ml of cleaning agent, and then circulate the rehydration. Complete mass production.

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PUM

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Abstract

The invention relates to a solar cell silicon wafer washing agent and a washing process for a solar cell silicon wafer thereof, and belongs to the technical field of solar cell production. The solar cell silicon wafer washing agent for the solar cell silicon wafer is composed of the following constituents: 0.5% to 3% of surface active agent, 2.1% to 13% of inorganic salt, 1% to 5% of organic salt, and the rest is of deionized water. The washing process comprises the following steps of (1) mixing the surface active agent, the inorganic salt, the organic salt and the deionized water according to the percentage by weight to prepare the solar cell silicon wafer washing agent; (2) adding the deionized water of 20-25 times volume into the washing agent prepared in the step (1), and uniformly stirring to obtain the solar cell silicon wafer washing liquid; and (3) placing silicon wafers into the solar cell silicon wafer washing liquid prepared in the step (2) at normal temperature. According to the solar cell silicon wafer washing agent and the washing process for the solar cell silicon wafer disclosed by the invention, the similarity-intermiscibility theory is used for the surface contaminants of the silicon wafer, a good decontamination effect is achieved, the surface of the silicon wafer is not corroded, the quality of crystalline silicon solar cells and the rate of finished products are improved, so that the production costs of the cell is reduced.

Description

technical field [0001] The invention relates to a solar cell silicon wafer cleaning agent and a cleaning process, which is applied in the solar cell production process and belongs to the technical field of solar cell production. Background technique [0002] In the production process of monocrystalline silicon solar cells, damage layers, alkali, salt, organic pollution, metal impurities and dust will be generated on the surface of silicon wafers during the production process of monocrystalline silicon, such as slicing and cleaning. Among them, the damaged layer and metal impurities can be effectively removed during the texturing and subsequent pickling process, while the dust and organic pollution are difficult to remove during the texturing reaction, and will hinder the crystal direction corrosion of the silicon wafer surface, causing obvious color difference , increase the reflectivity, reduce the texture quality and affect the overall texture effect of the silicon wafer. ...

Claims

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Application Information

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IPC IPC(8): C11D1/83C11D1/37C11D1/72C11D3/20C11D3/10C11D3/08C11D3/04
Inventor 李一鸣张震华王建新
Owner 绍兴拓邦新能源股份有限公司
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