Preparation method of supported ultrafine amorphous metal nickel catalyst for realizing catalytic full hydrogenation of aromatic ring

A technology of amorphous metal and nickel catalyst, which is applied in the field of preparation of catalyzed full hydrogenation of aromatic ring supported ultrafine amorphous metal nickel catalyst, can solve the problem of low volatilization temperature, achieve complete hydrogenation, and easy preparation method and technology , the effect of mild preparation conditions

Inactive Publication Date: 2014-08-20
CHINA UNIV OF MINING & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, it is still not easy to directly prepare metal catalysts by using metal carbonyls or their supports, because the volatilization temperature of most metal carbonyls is much lower than the decomposition temperature.

Method used

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  • Preparation method of supported ultrafine amorphous metal nickel catalyst for realizing catalytic full hydrogenation of aromatic ring

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] 1. Supported ultrafine amorphous metal nickel catalyst that catalyzes full hydrogenation of aromatic rings:

[0026]Add 40 ml of petroleum ether and the β-Al 2 o 3 Carrier 4g, nickel carbonyl Ni(CO) 4 After 100 milliliters, cover the autoclave still body 6, and fix and seal by bolt 5. Open the valves of the gas inlet 3 and the gas outlet 4 of the reactor, and slowly feed high-purity nitrogen in the reactor for 0.1 hour to replace the air in the original reactor. Repeat the same operation three times for nitrogen replacement, open the gas inlet 3 valve of the reaction kettle and close the gas outlet 4 valve, and slowly introduce high-purity hydrogen from the gas inlet 3 to the pressure gauge 8 on the autoclave. After the pressure is 8MPa, close the air inlet 3 valve.

[0027] Under the hydrogen atmosphere, by adjusting the parameters of the control panel 10, the motor 1 is turned on and the magnetic stirrer 2 is driven to slowly stir the mixture of organic solven...

Embodiment 2

[0037] 1. Supported ultrafine amorphous metal nickel catalyst that catalyzes full hydrogenation of aromatic rings:

[0038] Add 200 ml of diethyl ether, 10 g of ZSM-5 zeolite carrier of the catalyst, nickel carbonyl Ni(CO) 4 After 60 milliliters, cover the inside of the autoclave kettle body 6, and fix and seal it by bolts 5. Open the valves of the gas inlet 3 and the gas outlet 4 of the reactor, and slowly feed high-purity nitrogen in the reactor for 0.1 hour to replace the air in the original reactor. Repeat the same operation three times for nitrogen replacement, open the gas inlet 3 valve of the reaction kettle and close the gas outlet 4 valve, and slowly introduce high-purity hydrogen from the gas inlet 3 to the pressure gauge 8 on the autoclave. pressed for 5MPa Finally close the air inlet 3 valve.

[0039] Under the hydrogen atmosphere, by adjusting the parameters of the control panel 10, turn on the motor 1 and drive the magnetic stirrer 2, slowly stir the mixt...

Embodiment 3

[0047] 1. Supported ultrafine amorphous metal nickel catalyst that catalyzes full hydrogenation of aromatic rings:

[0048] In the autoclave with the lid opened, 100 ml of methanol was added successively, and the catalyst TiO 2 Zeolite carrier 20g, nickel carbonyl Ni(CO) 40 Cover the inside of the autoclave body 6 with 10 milliliters, and fix and seal it with bolts 5 . Open the valves of the gas inlet 3 and the gas outlet 4 of the reaction kettle, and slowly feed high-purity nitrogen in the kettle body for 1 hour to replace the air in the original kettle. Repeat the same operation three times for nitrogen replacement, open the gas inlet 3 of the reaction kettle and close the valve of the gas outlet 4, and slowly introduce high-purity hydrogen from the gas inlet 3 until the pressure gauge 8 on the autoclave shows the initial pressure When it is 2MPa, the air inlet 3 is closed until it is closed.

[0049] Under the hydrogen atmosphere, by adjusting the parameters of the c...

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Abstract

A preparation method of a supported ultrafine amorphous metal nickel catalyst for realizing catalytic full hydrogenation of an aromatic ring comprises: sequentially adding 10-1000 milliliters of organic solvent, 1-40g of a catalyst carrier and 1-100 milliliters of nickel carbonyl into a high-pressure reaction kettle of which a cover is opened, and closing the cover; enabling high-purity nitrogen gas to slowly flow in through a gas inlet and then flow out through a gas outlet, slowly introducing high-purity hydrogen gas into the high-pressure reaction kettle to 2-8MPa through the gas inlet, and then closing a valve of the gas inlet; starting a motor to drive a magnetic stirrer, and sufficiently stirring and mixing at room temperature; and then, quickly heating while fast stirring to raise temperature to 70°C-280°C, keeping the temperature, and enabling the nickel carbonyl adsorbed on a surface of the carrier to be resolved into an elementary nickel substance and attached onto the surface of the carrier, thus preparing the supported ultrafine amorphous metal nickel catalyst for realizing catalytic full hydrogenation of an aromatic ring.

Description

technical field [0001] The content of the present invention relates to a preparation method of a catalytic aromatic ring full hydrogenation catalyst, especially a preparation method of a catalytic aromatic ring full hydrogenation supported ultrafine amorphous metal nickel catalyst. Background technique [0002] Owing to the shortage of petroleum and the increasingly heavy and inferior quality of refined petroleum, the technology of direct coal liquefaction and indirect liquefaction of coal to produce liquid fuels has been rapidly progressing and developing in China in recent years. How to solve the partial product obtained from direct coal liquefaction-high-concentration aromatics deep hydrogenation conversion into light components; how to solve the by-product obtained in the process of coal indirect liquefaction to produce ethanol gasoline-heavy benzene is effectively hydrogenated into high-quality liquid cleansing Fuel; How to solve a series of problems such as reducing th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J23/755B01J29/46C07C13/18C07C15/30C07C5/10
CPCB01J29/46C07C13/18C07C15/30B01J23/755C07C5/10B01J29/0333B01J29/03C07C2521/04C07C2521/06C07C2521/08C07C2523/755C07C2529/40C07C2529/70
Inventor 魏贤勇亓士超李占库王玉高李鹏柳方景宗志敏樊星赵云鹏赵炜
Owner CHINA UNIV OF MINING & TECH
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