Chlorinated polyvinyl chloride modified material and preparation method thereof

A technology for chlorinated polyvinyl chloride and modified materials, applied in the field of chlorinated polyvinyl chloride modified materials and their preparation, can solve the problem of low mechanical properties, low impact strength, low thermal stability effect, low thermal stability, etc. problems, to achieve the effect of improving impact strength, improving surface finish, and overcoming high melt viscosity

Active Publication Date: 2013-05-15
HEILONGJIANG XINDA ENTERPRISE GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, with the increase of chlorine content, while some performances are improved, some performances are also lacking: (1) Due to the high melt viscosity of chlorinated polyvinyl chloride materials and the difficulty in processing and molding, the surface finish of its products Poor, and some mechanical properties (such as impact strength) are low
(2) Although the heat resistance of the material has been improved, the thermal stability is not high
Wherein the embodiment 1,2,4 of Chinese patent literature CN102532763A disclo

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1)

[0023] The chlorinated polyvinyl chloride modified material of the present embodiment is made of the following components by weight:

[0024] 100kg of injection molding grade chlorinated polyvinyl chloride resin;

[0025] 1kg of calcium stearate, 1.5kg of polyethylene wax and 1.7kg of ultra-high molecular weight polysiloxane; wherein the polyethylene wax adopts a low molecular weight polyethylene wax with a molecular weight of 2000; the ultra-high molecular weight polysiloxane adopts It is the GM-100 silicone plastic additive produced by Bluestar (Chengdu) New Material Co., Ltd.;

[0026] 7kg of methyl tin mercaptide and 1.2kg of calcium / zinc composite stabilizer; the calcium / zinc composite stabilizer is CZW-70 non-toxic calcium / zinc composite stabilizer produced by Nanjing Weigede Plastic Technology Co., Ltd. ;

[0027] 7kg of active nano calcium carbonate;

[0028]12 kg of methyl methacrylate-butadiene-styrene copolymer (MBS);

[0029] 6kg of acrylic copolymer (ACR);

...

Embodiment 2~ Embodiment 4)

[0038] Each embodiment is basically the same as Embodiment 1, and the differences are shown in Table 1.

[0039] Table 1

[0040]

[0041] .

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Abstract

The invention discloses a chlorinated polyvinyl chloride modified material and a preparation method thereof. The chlorinated polyvinyl chloride modified material is prepared from the following components in parts by weight: 100 parts of chlorinated polyvinyl chloride resin, 1-5 parts of compound lubricating agent, 5-10 parts of complex heat stabilizer, 5-15 parts of filling agent, 5-20 parts of toughening agent, 3-10 parts of processing agent and 0.5-3 parts of pigment. The preparation method comprises the following steps of: weighing various components according to a recipe for later use; pouring the chlorinated polyvinyl chloride resin into a high-speed mixer to be mixed, then filling the complex heat stabilizer, adding the compound lubricating agent, the filling agent, the toughening agent, the processing agent and the pigment to mix until the temperature reaches 105 DEG C-120 DEG C, discharging and cooling; and melting and extruding the cooled mixed material, and hot cutting to obtain the chlorinated polyvinyl chloride modified material. Problems of large melt viscosity and difficult formation machining are overcome through chlorinated polyvinyl chloride modification, and the obtained product has high shock strength, good surface smoothness and high thermal stability.

Description

technical field [0001] The invention relates to a polymer composite material and a preparation method thereof, in particular to a chlorinated polyvinyl chloride modified material and a preparation method thereof. Background technique [0002] Chlorinated polyvinyl chloride (CPVC) is obtained by chlorinating polyvinyl chloride (PVC). After chlorination modification, the chlorine content of the material is increased from 56.7% to 63% to 68%, which increases the polarity of the molecular bond, the intermolecular force, and the chemical stability of the material, which improves the mechanical properties and durability of the material. Chemical corrosion performance and flame retardant performance have been greatly improved. Moreover, after chlorination modification, the Vicat softening temperature increased from 72°C to 82°C to 90°C to 125°C, which increased the heat resistance of the material by 20% to 40%. Therefore, chlorinated polyvinyl chloride has excellent chemical corr...

Claims

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Application Information

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IPC IPC(8): C08L27/24C08L23/06C08L83/04C08K13/06C08K5/098C08K5/58C08K3/26C08K3/22B29C47/92B29C48/92
Inventor 周健丁海林陈志健顾玲玲毛佳敏徐泽平
Owner HEILONGJIANG XINDA ENTERPRISE GRP
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