Soft type halogen-free flame-retardant cable material and preparation method thereof

A kind of flame retardant cable material and soft technology, applied in the direction of insulated cables, cables, circuits, etc., can solve the problems affecting the physical and mechanical properties and processing of cable materials, and achieve the effect of improved softness, high softness and good flame retardant performance

Active Publication Date: 2014-01-22
JIANGSU ETERN +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the demand for halogen-free low-smoke soft halogen-free flame-retardant cable materials is increasing. At present, most of the production of halogen-free low-smoke soft halogen-free flame-retardant cable materials is to add a large amount of acetylene carbon black to polyolefin substrates. or acetylene carbon black to achieve the flame retardant effect, however, the addition of a large amount of inorganic materials affects the physical and mechanical properties and processing of cable materials

Method used

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  • Soft type halogen-free flame-retardant cable material and preparation method thereof

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Experimental program
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Effect test

Embodiment Construction

[0012] A soft halogen-free flame-retardant cable material, prepared from the following component raw materials (kg):

[0013] Polyolefin resin 30, thermoplastic elastomer 9, silicone rubber compound 5, hexamethylphosphoric triamide 4, compatibilizer 3, magnesium hydroxide 45, aluminum hypophosphite 20, zinc borate 5, stearic acid 5, Silane coupling agent KH560 0.8, antioxidant 168 0.4, dimethylaminoethyl methacrylate 2, modified filler 18.

[0014] Wherein, the modified filler is prepared by the following method:

[0015] Calcinate the diatomite at 550°C for 3.5 hours, take it out, add 3% sodium hydroxide solution and grind it for 1.5 hours, then add 13% hydrochloric acid solution, adjust the pH value to 4-5, and age for 12 hours. Add sodium hydroxide solution to adjust the pH of the grinding liquid to be neutral, filter and dry to obtain filler powder, then, add camphor essential oil equivalent to 1% of powder weight, 1% nano-carbon, 2% aluminum hypophosphite , after grindi...

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Abstract

The invention provides a soft type halogen-free flame-retardant cable material prepared from the following raw materials in parts by weight: 20-40 parts of polyolefin resin, 8-10 parts of a thermoplastic elastomer, 5-6 parts of organosilicone mixed compound, 3-5 parts of hexamethylphosphoramide, 2-4 parts of a compatibilizer, 40-50 parts of magnesium hydroxide, 3-6 parts of zinc borate, 4-6 parts of stearic acid, 0.4-1.2 parts of a silane coupling agent KH560, 0.1-0.5 part of an antioxidant 168, 15-25 parts of aluminium hypophosphite, 1-2 parts of dimethylaminoethyl methacrylate, and 15-20 parts of a modified filler. The soft type halogen-free flame-retardant cable material adopts the low-hardness thermoplastic elastomer to be blended with the polyolefin resin, besides the good mechanical performance is kept, and the cable material softness degree is greatly improved so as to expand the use scope of the cable material.

Description

technical field [0001] The invention relates to the field of cable materials, in particular to a soft halogen-free flame-retardant cable material and a preparation method thereof. Background technique [0002] Wire and cable are indispensable and important materials in industrial and agricultural production and modern life. my country is the world's largest producer of wire and cable. The wire and cable industry occupies a very important position in my country's national economy. However, at present, the market The cable material is not resistant to high temperature and aging, and the material turns yellow and becomes brittle after the aging test. There are more and more fires caused by aging wires. How to reduce the incidence of fire and the death rate in the event of fire, low smoke, halogen-free, flame retardant, and environmental protection have also become the development direction of the wire and cable industry. Among them, the demand for halogen-free low-smoke soft ha...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/00C08L101/00C08L83/04C08K13/06C08K9/06C08K9/04C08K9/02C08K3/34C08K3/22C08K3/38C08K5/09C08K5/5313H01B3/30H01B3/46H01B3/44H01B7/295
CPCC08L23/00C08L2201/02C08L2201/22C08L2203/202C08L2205/03C08L2207/04H01B3/441C08L101/12C08L83/04C08K13/06C08K9/06C08K9/04C08K9/02C08K3/34C08K2003/2224C08K3/38C08K5/09C08K3/32
Inventor 何成龙何源
Owner JIANGSU ETERN
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