A kind of magnetic phenolic humic acid resin and preparation method thereof

A technology of phenolic humic acid and water-soluble phenolic resin, applied in separation methods, chemical instruments and methods, other chemical processes, etc., can solve the problems of negative application and sustainable development, high energy consumption, high processing cost, and achieve increased repetition The effect of regeneration and utilization times, high separation efficiency and fast reaction speed

Inactive Publication Date: 2015-12-02
LIAOCHENG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This determines that there will be secondary pollution after chemical treatment, such as the generation of a large amount of waste residue, and there is no good disposal method for the treatment of these waste residues, so there is a huge impact on its application in engineering and sustainable development. Negative effects
[0004] The solvent extraction method in the physical chemical method, the loss of solvent in the extraction process and the large energy consumption in the regeneration process are the limitations of this method; the ion exchange method has low energy consumption, simple operation and good treatment effect, but the treatment cost is relatively high. high

Method used

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  • A kind of magnetic phenolic humic acid resin and preparation method thereof
  • A kind of magnetic phenolic humic acid resin and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Embodiment 1 A kind of magnetic phenolic humic acid resin, preparation method is:

[0027] (1) Preparation of ferrofluid: 10 grams of Fe 2 (SO 4 ) 3 , 5.2 g FeSO 4 ·7H 2 O was dissolved in 100ml of water three times, after the dissolution was complete, 1.8g of oleic acid was added, and then 100ml of water was added, and the prepared NaOH solution was added dropwise to the solution until the pH value of the solution was 13. The above solution was put into a microwave synthesizer for reaction, and the reaction temperature of the microwave synthesizer was controlled at 65° C., the power was 600 W, and the reaction time was 30 minutes. Finally the reaction product was dialyzed for 4 days.

[0028] (2) Preparation of water-soluble phenolic resin: add 45 grams of phenol and 45 grams of formaldehyde to the reaction bottle, start stirring, and heat up to dissolve; adjust the pH to 9-10 with 20% NaOH solution, and raise the reaction temperature to 85°C for reaction After 4...

Embodiment 2

[0031] A kind of magnetic phenolic humic acid resin of embodiment 2, preparation method is:

[0032] (1) Preparation of magnetic fluid: 12 grams of Fe 2 (SO 4 ) 3 , 5.4 g FeSO 4 ·7H 2 O was dissolved in 100ml of water three times, after the dissolution was complete, 2.0g of oleic acid was added, and then 100ml of water was added, and the prepared NaOH solution was added dropwise to the solution until the pH value of the solution was 13. The above solution was put into a microwave synthesizer for reaction, and the reaction temperature of the microwave synthesizer was controlled at 65° C., the power was 600 W, and the reaction time was 30 minutes. Finally the reaction product was dialyzed for 4 days.

[0033] Preparation of water-soluble phenolic resin: Add 50 grams of phenol and 50 grams of formaldehyde to the reaction bottle, start stirring, raise the temperature to 60°C until dissolved; adjust the pH to 9-10 with 20% NaOH solution, raise the reaction temperature to 85°C ...

Embodiment 3

[0036] Embodiment 3 A kind of magnetic phenolic humic acid resin, the preparation method is:

[0037] (1) Preparation of magnetic fluid: 14 grams of Fe2(SO4)3, 5.8 grams of FeSO4 7H2O were dissolved in 100ml of water three times, after the dissolution was complete, 2.3 grams of oleic acid was added, then 100ml of water was added, and the solution was added dropwise to configure NaOH solution to pH 13. The above solution was put into a microwave synthesizer for reaction, and the reaction temperature of the microwave synthesizer was controlled at 65° C., the power was 600 W, and the reaction time was 30 minutes. Finally the reaction product was dialyzed for 4 days.

[0038] (2) Preparation of water-soluble phenolic resin: Add 60 grams of phenol and 60 grams of formaldehyde to the reaction bottle, start stirring, and heat up to dissolve; use 20% NaOH solution to adjust the pH to 9-10, and raise the reaction temperature to 85°C for reaction After 30-60 minutes, add formaldehyde ...

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Abstract

The invention relates to magnetic phenol formaldehyde-humic acid resin and a preparation method thereof. The preparation method for the magnetic phenol formaldehyde-humic acid resin comprises the following steps of adding a sulfonated sodium humate solution into water-soluble phenol formaldehyde resin, uniformly stirring the mixed solution, adding magnetic fluid, stirring for mixing, heating the mixed solution to 100 DEG C, performing cross-linking reaction for 30 to 90 minutes at constant temperature, activating the magnetic phenol formaldehyde-humic acid resin in a calcium acetate solution, filtering and drying. According to the magnetic phenol formaldehyde-humic acid resin and the preparation method thereof, the magnetic phenol formaldehyde-humic acid resin can be prepared, is high in Cu<2+> ion adsorption performance, and can be used for removing copper ions from wastewater; the resin adsorbed with the copper ions is easy to regenerate, and can be separated by adopting an external magnetic field.

Description

technical field [0001] The invention relates to an adsorption resin, especially a production method of a magnetic phenolic humic acid resin and its application in removing copper ions in industrial wastewater treatment. Background technique [0002] The discharge of industrial wastewater is the main source of water pollution, and the excessive discharge of heavy metal ions in the water is very harmful to the environment, and its pollution problem has attracted increasing attention. According to the nature of heavy metal ions in industrial wastewater, scientific and reasonable methods are adopted for treatment. "Common Treatment Methods for Heavy Metal Ions in Industrial Wastewater" in "Guangzhou Chemical Industry" 2011 Volume 39 Issue 5 "Common Treatment Methods for Heavy Metal Ions in Industrial Wastewater" discusses chemical methods, physical chemical methods and biochemical methods. Made a detailed elaboration. [0003] Chemical methods include chemical precipitation and...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/30B01J20/26B01J20/34C02F1/28C02F1/62
Inventor 崔慧陶绪泉王怀生李连之冯传义魏忠琛樊娜陈汪洋
Owner LIAOCHENG UNIV
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