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Solar glass antireflection antifouling paint and production method thereof

A technology of solar glass and anti-fouling coating, applied in the direction of coating, etc., can solve the problems of poor weather resistance of solar anti-reflection glass, easy alkaline hydrolysis, contradictory technical indicators of weather resistance and anti-reflection rate, etc., and achieve high weather resistance , not easy to accumulate, high anti-reflection effect

Inactive Publication Date: 2014-03-12
TIANJIN ZHONGKE CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The object of the present invention is to provide a solar glass anti-reflection and antifouling coating with high weather resistance and high anti-reflection rate and its production method to solve the conflict between the existing technical indicators of anti-reflection coatings for solar glass and weather resistance and anti-reflection rate problems to stabilize and improve solar cell power generation efficiency and reduce solar cell maintenance and management costs
[0007] The study found that the main reason for the poor weather resistance of solar anti-reflective glass is that the glass matrix is ​​prone to alkaline hydrolysis under hot and humid conditions

Method used

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  • Solar glass antireflection antifouling paint and production method thereof
  • Solar glass antireflection antifouling paint and production method thereof
  • Solar glass antireflection antifouling paint and production method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0037] Add 800 g of deionized water to a 2000 mL reactor equipped with a mechanical stirrer, a thermometer, a dropping funnel and a condenser tube, add 150 g of alkaline silica sol with a mass percentage concentration of 25% under stirring, and use a mass percentage concentration of 20% % dilute phosphoric acid to adjust the silica hydrosol to PH9-10, filter to remove insoluble impurities, and obtain transparent silica hydrosol A; add 45g of ethyl silicate, and stir the reaction at 20-30°C for 4-8 hours to Ethyl silicate is completely dissolved, and aged at room temperature for 12 hours to form a slightly blue silica hydrosol B; then adjust the hydrosol to PH2-3 with a 20% mass percent concentration of phosphoric acid solution, and then heat it at 60-80°C Under vacuum distillation, remove about 10% solvent, obtain silicon dioxide hydrosol C; add mass percentage concentration and be 1.0g of lauric acid diethanolamide surfactant, form silicon dioxide hydrosol D; Add mass percenta...

Embodiment 2

[0042] Add 800 g of deionized water to a 2000 mL reactor equipped with a mechanical stirrer, a thermometer, a dropping funnel and a condenser tube, add 150 g of alkaline silica sol with a mass percentage concentration of 25% under stirring, and use a mass percentage concentration of 20% % dilute phosphoric acid to adjust the silica hydrosol to PH9-10, filter to remove insoluble impurities, and obtain transparent silica hydrosol A; add 45g of tetraethyl orthosilicate, stir and react at 20-30°C for 4-8 hours Until the ethyl silicate is completely dissolved, age at room temperature for 12 hours to form a slightly blue silica hydrosol B; then use a 20% mass percent concentration of dilute phosphoric acid solution to adjust the hydrosol to PH2-3, and then in 60-80 Remove about 10% of the solvent by vacuum distillation at °C to obtain silica hydrosol C; add 1.0 g of 10% lauric acid diethanolamide surfactant to form silica hydrosol D; add phosphoric acid with a concentration of 5% by ...

Embodiment 3

[0047] Add 800g of deionized water to a 2000mL reactor equipped with a mechanical stirrer, a thermometer, a dropping funnel, and a condenser tube, add 100g of 25% alkaline silica sol under stirring, and adjust with dilute phosphoric acid with a concentration of 20% by mass. Silica hydrosol to PH9-10, filter to remove insoluble impurities to obtain transparent silica hydrosol A; add 90g of ethyl silicate, stir and react at 20-30°C for 4-8 hours until the ethyl silicate is complete Dissolve and age at room temperature for 12 hours to form slightly blue silica hydrosol B; then adjust the hydrosol to PH2-3 with 20% dilute phosphoric acid solution, and then remove about 10% of the solvent by vacuum distillation at 60-80°C to obtain Silica hydrosol C; add 1.0 g of 10% lauric acid diethanolamide surfactant to form silica hydrosol D; add 5% aluminum dihydrogen phosphate hydrosol 40g , stirring and dissolving to form a silicon-aluminum composite hydrosol E; add 20 g of newly prepared s...

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Abstract

The invention discloses solar glass antireflection antifouling paint with high antireflection performance and high weather resistance and a production method of the solar glass antireflection antifouling paint. The solar glass antireflection antifouling paint is prepared from alkaline silica gel, poly SiO2, aluminium dihydrogen phosphate, silicon phosphate, phosphoric acid, a surfactant and deionized water. The production method comprises the following steps: a porous silicon dioxide core generated in ethyl silicate hydrolysis is covered with another hard silicon dioxide shell, silicon dioxide particles in the paint have a core-shell structure, the silicon dioxide core formation and the silicon dioxide shell covering are carried out at the same time, aluminium dihydrogen phosphate and silicate phosphate are used as a silicon dioxide curing agent to enhance the weather resistance of an antireflection membrane. The problem that antireflection performance and the weather resisting performance of conventional solar glass self-cleaning antireflection paint can offset each other is solved, the power generating efficiency of a solar cell can be improved and stabilized greatly, and the maintenance management cost of the solar cell can be reduced.

Description

technical field [0001] The invention relates to an antireflection and antifouling coating for solar glass and a production method thereof, in particular to an antireflection and antifouling coating for solar glass with high weather resistance and high antireflection containing aluminum phosphate and silicon phosphate curing agent and a production method thereof, which belongs to the new materials and new energy fields. Background technique [0002] Crystalline silicon solar cell modules are generally composed of solar glass cover plate coated with anti-reflection film, solar cell silicon wafer, battery back plate and EVA film, which are glued and pressed together, and then installed into a fixed frame. The visible light transmittance of solar cell module packaging glass is generally 91.6%, and the single surface reflectance of solar glass is about 4%. If the surface of the solar glass is coated with an anti-reflection film with a thickness of 120-150nm, the transmittance of...

Claims

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Application Information

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IPC IPC(8): C09D1/00C09D7/12C03C17/23
Inventor 李建生刘炳光王韬王伟伟白俊学
Owner TIANJIN ZHONGKE CHEM
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