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35results about How to "Has ion conductivity" patented technology

High-toughness self-repairing physical hydrogel based on dual ion coordination and preparation method thereof

The invention discloses high-toughness self-repairing physical hydrogel based on dual ion coordination and a preparation method thereof. The physical hydrogel has multi-crosslinking sites. The preparation method of the high-toughness self-repairing physical hydrogel comprises the following steps: dissolving N-carboxyethyl chitosan (CEC), acrylic acid (AA), an FeCl3 water solution and a CaCl2 watersolution into de-ionized water according to a certain ratio and carrying out ultrasonic treatment to obtain a uniform and transparent solution; then carrying out vacuum deoxygenation on the solution;adding an ammonium persulfate (APS) water solution and a catalyst N,N,N',N'-tetramethyldiethylamine (TEMED) in sequence under the protection of nitrogen gas; reacting for at least 4h under the condition of 30 to 50 DEG C, so as to prepare the physical hydrogel. The physical hydrogel provided by the invention has excellent mechanical properties and self-repairing properties; metal ions are introduced so that the gel has certain ionic conductivity; furthermore, an application range of the chitosan based self-repairing hydrogel is expanded; the high-toughness self-repairing physical hydrogel ishopefully applied to fields including wearable flexible electronic devices, soft-bodied robots, biomedicines, aerospace and the like.
Owner:ZHEJIANG UNIV

Cathode slurry of lithium ion batteries on production line and preparation method of cathode slurry

The invention belongs to the technical field of lithium ion batteries and particularly relates to cathode slurry of the lithium ion batteries on a production line and a preparation method of the cathode slurry. The cathode slurry comprises 179 parts of cathode active substance, 4 parts of conductive agent and 17 parts of lithium polyacrylate, wherein the lithium polyacrylate is used as the adhesive. Compared with a traditional adhesive, the lithium polyacrylate has ionic conductivity and can integrally the conductivity of the cathode slurry. The cathode slurry is prepared by a subsection ball milling method, the materials are sufficiently stirred to avoid slurry settling, and accordingly the dispersing performance of the cathode slurry is increased greatly. The cathode slurry has the advantages that the cathode slurry is good in dispersity, moderate in viscosity, good in conductivity, low in cost, green, environmentally friendly and widely applicable to the production line for producing lithium ion batteries, the process of the cathode slurry is optimized, and the production efficiency of the lithium ion batteries can be increased while the overall performance of the produced lithium ion batteries can be increased.
Owner:GUANGDONG UNIV OF TECH

Preparation method of polydopamine-coated sodium ion battery positive electrode material

A preparation method of a polydopamine-coated sodium ion battery positive electrode material comprises the following steps: 1, preparing an MxFeyMnz (OH) 2 precursor through a coprecipitation method, 0 < x < = 0.5, 0 < = y < = 0.33, 0 < z < = 0.5, x + y + z = 1, and M is a transition metal ion; 2, mixing the precursor and a sodium source according to a molar ratio of 1: (1-1.1); the preparation method comprises the following steps: mixing the raw materials, sintering at a high temperature of 850-1100 DEG C for 10-20 hours to obtain the positive electrode material with the general formula of NaaMxFeyMnzO2, and a is more than 0.67 and less than 1.1; 3, adding the positive electrode material into the dispersing solvent, stirring and dispersing to obtain a first turbid liquid, and enabling the concentration of the positive electrode material in the first turbid liquid to be 0.1-0.5 g / mL; when the pH value of the first suspension is stabilized at 8-12, adding dopamine hydrochloride, and reacting for 10-30 hours at normal temperature and normal pressure in a dry environment to obtain a second suspension; and 4, filtering, washing and drying the second suspension to obtain the polydopamine-coated sodium ion battery positive electrode material. The coating layer is high in uniformity and excellent in storage performance in air, the thickness of the polymer coating layer is adjustable, the side reaction of the positive electrode material in electrolyte can be effectively inhibited in the circulation process, and the circulation stability of the sodium ion battery is improved.
Owner:南通金通储能动力新材料有限公司

Lithium titanate composite anode material and preparation method thereof

The invention discloses a lithium titanate composite anode material and a preparation method thereof. A coating layer coats the outside of the lithium titanate material; and the coating layer is a mixture of LiAlO2 and SiOx. The LiAlO2 on the surface of the anode material has ionic conductivity; the SiOx forms a solid electrolyte in the charge and discharge processes; the LiAlO2 and the SiOx are beneficial to improvement of the capacity and the rate capability of the anode material; the composite LiAlO2/SiOx coating layer on the surface covers surface-active sites of the lithium titanate material; and reductive decomposition of the electrolyte is inhibited, so that a gas generated when the composite anode material is used as the anode material for a lithium-ion battery is reduced; and the service lifetime is effectively prolonged. The method is an effective path which can improve the capacity and the rate capability of the lithium titanate composite anode material, can prolong the cycle lifetime and can inhibit gas production of the lithium titanate composite anode material; and the method is friendly to environment, simple in process, low in cost and suitable for large-scale production, and has a wide market prospect.
Owner:SHANDONG ZHAOWEN NEW ENERGY TECH CO LTD

Preparation method and application of a crown ether modified polyaniline solid electrolyte membrane

The invention discloses a preparation method of a crown ether modified polyaniline solid electrolyte membrane and its application in solid batteries, belonging to the technical field of solid batteries. The key points of the technical scheme of the present invention are: reacting the crown ether compound with a chlorosulfonating reagent to obtain a crown ether sulfonyl chloride, then reacting the crown ether sulfonyl chloride with polyaniline to obtain polyaniline with a crown ether group in the side chain, and then Polyaniline containing crown ether groups in the side chain is reacted with lithium salt to prepare crown ether sulfonyl chloride grafted polyaniline lithium ion complex, and finally the crown ether sulfonyl chloride grafted polyaniline lithium ion complex is mixed with polyaniline and coated Cover on the substrate, dry naturally and then vacuum dry to obtain the crown ether modified polyaniline solid electrolyte membrane. The crown ether modified polyaniline solid electrolyte membrane prepared by the invention has the advantages of high ion conductivity and elastic interface contact, and the assembled solid state battery exhibits good electrochemical performance and is suitable for industrial popularization and application.
Owner:河南电池研究院有限公司 +1

A kind of lithium titanate composite negative electrode material and preparation method thereof

The invention discloses a lithium titanate composite anode material and a preparation method thereof. A coating layer coats the outside of the lithium titanate material; and the coating layer is a mixture of LiAlO2 and SiOx. The LiAlO2 on the surface of the anode material has ionic conductivity; the SiOx forms a solid electrolyte in the charge and discharge processes; the LiAlO2 and the SiOx are beneficial to improvement of the capacity and the rate capability of the anode material; the composite LiAlO2 / SiOx coating layer on the surface covers surface-active sites of the lithium titanate material; and reductive decomposition of the electrolyte is inhibited, so that a gas generated when the composite anode material is used as the anode material for a lithium-ion battery is reduced; and the service lifetime is effectively prolonged. The method is an effective path which can improve the capacity and the rate capability of the lithium titanate composite anode material, can prolong the cycle lifetime and can inhibit gas production of the lithium titanate composite anode material; and the method is friendly to environment, simple in process, low in cost and suitable for large-scale production, and has a wide market prospect.
Owner:SHANDONG ZHAOWEN NEW ENERGY TECH CO LTD
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