The invention discloses a preparation method of an Ag-
Mn doped ZnSe and ZnS core-shell structure
quantum dot. The preparation method comprises the following steps of adopting a
mixed solution of zincacetate and
silver acetate as a
core formation precursor, adding high-activity
sodium hydrogen selenide at the temperature of 80-100 DEG C to obtain an Ag-doped ZnSe
nanocrystal core; and then adopting a
mixed solution of
zinc acetate and
manganese acetate as a shell layer precursor, adding
sodium sulfide at the temperature of 80-100 DEG C to obtain an Mn-doped ZnS shell layer. According to the preparation method provided by the invention, by adopting the
zinc acetate, the
silver acetate and the
manganese acetate, the cost is low, and the
reaction rate is easily controlled; only by adding a very small amount of an alkaline solution, a pH value can be regulated into a strong alkaline range; the
nanocrystal core and the shell layer are prepared by adopting a one-pot method respectively, so that the operation step is simplified, and the preparation method is liable to popularization and large-scale production; the core and the shell adopting a ZnSe / ZnS
quantum dot are doped with Ag+ and Mn2+ respectively, and an Ag:ZnSe / Mn:ZnS
quantum dot is prepared; a single
fluorescence peak, different double
fluorescence peak combination or three
fluorescence peaks are provided, so that white fluorescence can be modulated; the structure has a
white light emitting ability, and a fluorescence material is provided to the field of
white light LED.