Foam sealing channeling composition, preparation method thereof and applications thereof
A technology of composition and foam, which is applied in the direction of drilling composition, chemical instruments and methods, earthwork drilling and mining, etc., can solve the problems of poor plugging effect and gas channeling, achieve the purpose of suppressing gas channeling, reducing surface tension, and easy The effect of forming and stabilizing foam
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Embodiment 1
[0027] Add 90g dodecylamine and 0.3% potassium hydroxide of amine weight to the reaction kettle, add 450g ethylene oxide, and react at 200°C for 1 hour; then add 60g sodium chloroacetate, continue to react at 50°C for 20 hours, and finally add hydrochloric acid Neutralize to pH <3, stand for stratification, add 30% by weight NaOH aqueous solution to the oil phase for neutralization to obtain anionic-nonionic foaming agent.
[0028] Dissolve dodecyl ammonium chloride and the anionic-nonionic foaming agent prepared by the present invention separately in water, stir for 30 minutes to prepare a 0.5% by weight aqueous solution, and then adjust the above-mentioned foaming agent to cationic: anionic-nonionic foaming agent mole Mix evenly at a ratio of 1:8 to obtain foaming agent composition 1, whose composition and structure are shown in Table 1.
[0029] The above-mentioned composition is mixed with the gas driving gas to form the desired foam channeling composition.
[0030]
Embodiment 2
[0032] Put 140g of eicosamine and 1% potassium hydroxide by weight of amine into the reactor, add 180g of ethylene oxide and 67g of propylene oxide, and react at 200°C for 10 hours; then add 90g of sodium chloroacetate and continue the reaction at 80°C. 8 Hours, finally add hydrochloric acid to neutralize to pH <3, stand for stratification, add 30% by weight NaOH aqueous solution to the oil phase for neutralization to obtain anionic-nonionic foaming agent.
[0033] The octadecylammonium bromide and the anionic-nonionic foaming agent prepared by the present invention were separately dissolved in water, stirred for 30 minutes to prepare a 0.5% by weight aqueous solution, and then the above-mentioned foaming agent was cation: anionic-nonionic foaming agent mole Mix evenly at a ratio of 1:10 to obtain foaming agent composition 2. Its composition and structure are shown in Table 1.
[0034] The above composition is mixed with the gas for gas drive to form the desired foam channeling sys...
Embodiment 3
[0037] Add 75g decylamine and 3% potassium hydroxide by weight of amine into the reaction kettle, add 315g ethylene oxide, 151g propylene oxide, and react at 150°C for 3 hours; then add 195g Br(CH 2 ) 5 COOH, continue to react at 100℃ for 1 hour, and finally add hydrochloric acid to neutralize to pH 3 ) 2 The aqueous solution is neutralized to obtain an anionic-nonionic foaming agent.
[0038] The tetradecyl ammonium chloride and the anionic-nonionic foaming agent prepared by the present invention are separately dissolved in water and stirred for 30 minutes to prepare a 0.5% by weight aqueous solution, and then the above-mentioned foaming agent is cation: anionic-nonionic foaming agent mole Mix evenly at a ratio of 1:1.4 to obtain foam composition 3, whose composition and structure are shown in Table 1.
[0039] The above composition is mixed with the gas for gas drive to form the desired foam channeling system.
[0040]
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