Heavy metal-contaminated soil solidifying agent and application method thereof

A technology of heavy metal contaminated soil and curing agent, applied in chemical instruments and methods, applications, solid waste management and other directions, can solve the problems of accelerated heavy metal ion leaching, pollution of human living environment, large amount of curing agent added, etc., to reduce porosity , the effect of reducing environmental pollution and solving treatment problems

Active Publication Date: 2014-06-04
INST OF ROCK AND SOIL MECHANICS - CHINESE ACAD OF SCI
View PDF5 Cites 46 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current curing and stabilization treatment technology has the following problems: 1) The amount of curing agent added is too large; 2) The cracking caused by the long-term stress load and dry-wet cycle of the cured body accelerates the leaching of heavy metal ions in the cured body; 3. ) high environmental risk
[0004] There are many sugar factories in Sichuan and Guangxi in my country, and there is a large amount of bagasse, which belongs to fiber in terms of its composition and is the waste of sugar factories; most of the cellulose-rich straw is burned as waste or only used as fuel , not only caused a waste of natural resources, but also polluted the deteriorating human living environment, which urgently needs a more effective straw treatment method

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Heavy metal-contaminated soil solidifying agent and application method thereof
  • Heavy metal-contaminated soil solidifying agent and application method thereof
  • Heavy metal-contaminated soil solidifying agent and application method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment example 1

[0053] The moisture content of the heavy metal-contaminated soil to be treated was measured by drying method to be 15%, and the weight of the heavy metal-contaminated soil was 300kg. When solidified, the moisture content of the heavy metal-contaminated soil slurry was 100%. According to the formula (1), the amount of water added was calculated as 182.61kg, according to the formula (2), the dry weight of heavy metal-contaminated soil is 260.87kg. Mix 182.61kg of weighed water with heavy metal-contaminated soil, stir for 5 minutes to form heavy metal-contaminated soil slurry, then dissolve 2.61kg of sodium sulfide in the heavy metal-contaminated soil slurry, and stir for 5 minutes; add 13.04kg of biological Carbon, stir again for 5 minutes; after 30 minutes, add 26.09kg bagasse fiber and 26.09kg cement, and stir vigorously for 20 minutes.

Embodiment example 2

[0055] The moisture content of the heavy metal-contaminated soil to be treated was measured by the drying method to be 18%, and the weight of the heavy metal-contaminated soil was 300kg. When solidified, the moisture content of the heavy metal-contaminated soil slurry was 110%. According to the formula (1), the amount of water added was calculated as 188.14kg, according to the formula (2), the dry weight of heavy metal-contaminated soil is 254.24kg. Mix the weighed 188.14kg of water with the heavy metal contaminated soil, stir for 7 minutes to form a heavy metal contaminated soil slurry, then dissolve 2.54kg of potassium dihydrogen phosphate in the heavy metal contaminated soil slurry, and stir for 7 minutes; add 12.71 kg of biochar, and stir again for 7 minutes; after 30 minutes, add 25.42kg of straw fiber and 25.42kg of lime, and stir vigorously for 20 minutes.

Embodiment example 3

[0057] The moisture content of the heavy metal-contaminated soil to be treated was measured by the drying method to be 21%, and the weight of the heavy metal-contaminated soil was 300kg. When solidified, the moisture content of the heavy metal-contaminated soil slurry was 120%. According to the formula (1), the amount of water added was calculated as 193.39kg, according to the formula (2), the dry weight of heavy metal-contaminated soil is 247.93kg. Mix the weighed 193.39kg of water with the heavy metal contaminated soil, stir for 8 minutes to form a heavy metal contaminated soil slurry, then dissolve 2.48kg of sodium sulfide in the heavy metal contaminated soil slurry, and stir for 8 minutes; add 12.40kg of biological Carbon, stir again for 8 minutes; after 30 minutes, add 24.79kg bagasse fiber and 24.79kg gypsum, and stir vigorously for 20 minutes.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
particle size (mesh)aaaaaaaaaa
Login to view more

Abstract

The invention discloses a heavy metal-contaminated soil solidifying agent and an application method thereof. The solidifying agent comprises the following components by mass: on the basis of the dry weight of heavy metal-contaminated soil, 10 to 15% of a binding material, 5% of biochar, 10% of vegetable fiber and 1% of a stabilizing agent. The components are added according a sequence of the stabilizing agent-the biochar-the vegetable fiber-the binding material. Addition of the chemical stabilizing agent and the biochar in the process of stabilization enables heavy metals to be absorbed and passivated and to lose mobility; preparation of heavy metal-contaminated soil slurry provides conditions for a later chemical reaction; the whole processing process is free of dust pollution and discharging of unwanted sewage. Addition of the vegetable fiber enables cracking of heavy metal-contaminated soil solidified by using a conventional solidifying agent to be effectively prevented and endurance of a solidified body to be improved. The method provided by the invention has the advantages of strong operability, low cost, extensive applicability, a high resource utilization rate, low environmental risk and easy large-scale popularization.

Description

technical field [0001] The invention discloses a solidifying agent for heavy metal polluted soil and a using method thereof, and belongs to the technical field of engineering materials and environmental engineering. Background technique [0002] With the acceleration of urbanization and industrialization, more and more land is polluted by heavy metals, the strategic layout of cities has been readjusted, and a large number of heavy metal legacy sites are in urgent need of treatment. At present, nearly 20 million hectares of arable land are polluted by heavy metals such as chromium, cadmium, arsenic, and lead in my country. It is estimated that 12 million tons of grains are polluted by soil every year, causing direct economic losses of more than 20 billion yuan. The remediation and treatment methods of heavy metal contaminated soil mainly include solidification and stabilization, leaching, electrokinetic remediation, phytoremediation, vitrification and steam extraction. one. ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/00C04B28/10C04B28/14C04B18/24C09K17/50
CPCY02W30/91
Inventor 薛强王平李江山李振泽陈亿军
Owner INST OF ROCK AND SOIL MECHANICS - CHINESE ACAD OF SCI
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products