Waterborne tackifying resin exclusively used for cigarette holder glue and preparation method thereof
A technology of tackifying resin and cigarette holder, which is applied in the direction of rosin adhesive, chemical modification of natural resin, adhesive type, etc. It can solve the problems of poor plastic bonding performance and low water resistance, and achieve the improvement of plastic adhesion. Poor bonding performance and low water resistance, stable emulsion performance, and easy industrial production
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Embodiment 1
[0026] Raw materials and dosage
[0027] 45 kg of rosin; additives: 0.35 kg of triethyl phosphite and triphenyl phosphite, 0.5 kg of diphenyl-decyl phosphite, 0.5 kg of antioxidant 1010, 0.6 kg of zinc oxide; polyols: 3 kg of glycerin, 3 kg of diethylene glycol; 8 kg of sodium dodecylbenzenesulfonate; 40 kg of hot pure water at 95°C;
[0028] Its production steps are:
[0029] A, add 45 kilograms of rosin and 0.35 kilogram of triethyl phosphite and triphenyl phosphite, 0.5 kilogram of antioxidant 1010 in the four-necked flask that electric stirrer, dropping device, reflux condenser, thermometer are housed, Heating at a constant temperature to 200°C, stirring rapidly to dissolve it fully, and obtaining a modified rosin copolymer;
[0030] B. Slowly add 3 kilograms of glycerin, 3 kilograms of diethylene glycol and 0.3 kilogram of zinc oxide to the modified rosin copolymer obtained in step A for modification, and the temperature in the flask is controlled at 270° C. to obtain m...
Embodiment 2
[0033] Raw materials and dosage
[0034] 50 kg of rosin; additives: 0.35 kg of tris[2,4-di-tert-butylphenyl] phosphite, 0.5 kg of diphenyldecyl phosphite, 0.5 kg of antioxidant 1076, 0.6 kg of magnesium oxide, β( 3',5'-di-tert-butyl-4'-hydroxyphenyl) octadecyl propionate 0.5 kg; polyols: glycerin 3 kg, pentaerythritol 3 kg; sodium dodecylbenzenesulfonate 8 kg; 95°C 48 kg of hot pure water;
[0035] Its production steps are:
[0036] A. Add 50 kg of rosin and 0.35 kg of tris[2,4-di-tert-butylphenyl]phosphite, 0.5 kg Antioxidant 1076, heated to 200°C at constant temperature, stirred rapidly to dissolve it fully, and obtained modified rosin copolymer;
[0037] B. Slowly add 3 kg of glycerin, 3 kg of pentaerythritol, 0.3 kg of magnesium oxide, and 0.5 kg of β (3', 5'-di-tert-butyl-4'-hydroxyphenyl) to the modified rosin copolymer obtained in step A Octadecyl propionate is modified, and the temperature in the flask is controlled at 270° C. to obtain modified rosin ester copolym...
Embodiment 3
[0040] Raw materials and dosage
[0041] 50 kg of rosin; additives: 0.85 kg of triphenyl phosphite and tris[2,4-di-tert-butylphenyl] phosphite, 0.5 kg of monophenyldidecyl phosphite, 0.5 kg of antioxidant 1098, oxidation 0.6 kg of zinc and magnesium oxide, 0.5 kg of dilauryl thiodipropionate; polyols: 3 kg of glycerin, 3 kg of trimethylol propanol; 8 kg of sodium dodecylbenzenesulfonate; hot pure water at 95°C 50 kg;
[0042] Its production steps are:
[0043] A. Add 50 kilograms of rosin and 0.85 kilograms of triphenyl phosphite and three [2,4-di-tert-butylphenyl] in a four-necked flask equipped with an electric stirrer, a dripping device, a reflux condenser, and a thermometer Phosphite, 0.5% antioxidant 1098, heated at a constant temperature to 195°C-205°C, stirred rapidly to dissolve it fully, and obtained a modified rosin copolymer;
[0044] B, slowly add 3 kilograms of glycerol and 3 kilograms of trimethylol propanol and 0.3 kilograms of zinc oxide and magnesium oxide,...
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