PVD (Physical Vapor Deposition) two-color wire drawing treatment method of workpiece surface

A technology of workpiece surface and treatment method, which is applied in metal material coating process, ion implantation plating, coating, etc., can solve the problems of environmental pollution, unstable black hard film structure, and exposure of workpiece base due to wire drawing force, and achieve The effect of low ionization rate

Active Publication Date: 2014-06-25
NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Although electroplating on the surface of products can obtain highly anti-corrosion, high wear-resistant and highly decorative coatings, there are recognized shortcomings in the electroplating process: a large amount of waste water containing harmful chemicals is produced, which seriously pollutes the environment, so it is urgent to improve
[0007] (1) When the drawing force is small, the surface black film cannot be destroyed, and when the drawing force is increased, it is easy to destroy the bottom film and the surface black film at the same time to expose the base of the workpiece;
[0008] (2) When using PVD technology to deposit the black film on the surface, the blackness of the black film is often adjusted by adjusting the flow rate of carbon source gas and nitrogen gas. However, in actual operation, there are often unstable flow control and uneven gas distribution i

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] In this embodiment, PVD two-color wire drawing treatment is carried out on the surface of the workpiece to obtain a bronze two-color surface, which specifically includes the following steps:

[0026] (1) Using PVD technology to deposit ZrN bottom film on the surface of the workpiece;

[0027] (2) Place the workpiece processed in step (1) in the vacuum chamber of the magnetron sputtering device, introduce Ar gas, use graphite as the target material, turn on the magnetron sputtering source, and apply pulse negative bias to the workpiece substrate -50V, sputtering graphite target, depositing a graphite-like layer of 300nm on the surface of the ZrN underlying film of the workpiece;

[0028] After testing, the Lab values ​​of this type of graphite layer are 51.12, -0.14, -0.16;

[0029] (3) The wire drawing wheel is used to perform wire drawing on the surface of the workpiece. The wire drawing wheel destroys the surface graphite-like layer, exposing the underlying film, and...

Embodiment 2

[0031] In this embodiment, PVD two-color wire drawing treatment is carried out on the surface of the workpiece to obtain an ancient nickel two-color surface, which specifically includes the following steps:

[0032] (1) Using PVD technology to deposit a CrN bottom film on the surface of the workpiece;

[0033] (2) Place the workpiece processed in step (1) in the vacuum chamber of the magnetron sputtering device, introduce Ar gas, use graphite as the target material, turn on the magnetron sputtering source, and apply pulse negative bias to the workpiece substrate -50V, sputtering graphite target, depositing 500nm graphite-like layer on the surface of the CrN bottom film of the workpiece;

[0034] After testing, the Lab values ​​of this type of graphite layer are 49.46, -0.08, -0.09;

[0035] (3) Use a wire-drawing wheel to perform wire-drawing treatment on the surface of the workpiece. The wire-drawing wheel destroys the surface graphite-like layer, exposing the underlying fil...

Embodiment 3

[0037] In this embodiment, PVD two-color wire drawing treatment is carried out on the surface of the workpiece to obtain a red and bronze two-color surface, which specifically includes the following steps:

[0038] (1) Using PVD technology to deposit Cu underlying film on the surface of the workpiece;

[0039] (2) Place the workpiece processed in step (1) in the vacuum chamber of the magnetron sputtering device, introduce Ar gas, use graphite as the target material, turn on the magnetron sputtering source, and apply pulse negative bias to the workpiece substrate -30V, sputtering graphite target, depositing 800nm ​​graphite-like layer on the surface of the Cu underlying film of the workpiece;

[0040] After testing, the Lab values ​​of this type of graphite layer are 42.56, -0.07, -0.06;

[0041] (3) Use a wire-drawing wheel to perform wire-drawing treatment on the surface of the workpiece. The wire-drawing wheel destroys the surface graphite-like layer, exposing the underlyin...

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PUM

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Abstract

The invention provides a PVD (Physical Vapor Deposition) two-color wire drawing treatment method of a workpiece surface. The PVD two-color wire drawing treatment method comprises the following steps: depositing a bottom layer membrane on the workpiece surface by adopting a PVD technology; then sputtering and depositing a graphite-like layer serving as a black membrane on the surface of the bottom layer membrane by using a magnetron sputtering method and using graphite as a target; and finally carrying out wire drawing treatment so as to obtain a two-color membrane. Compared with conventional metal carbide and the like serving as the black membrane, the graphite-like layer serving as the black membrane has the advantages that the graphite-like layer has good binding force with the base layer membrane on the one hand and has relatively low hardness and good toughness in comparison with the metal carbide membrane on the other hand, so that the separation of the graphite-like layer and the base layer membrane is easy to realize; the two-color membrane is obtained through wire drawing treatment; and the phenomenon that the black membrane cannot be pulled off or the two layers of membranes are pulled off simultaneously is avoided.

Description

technical field [0001] The invention belongs to the technical field of surface treatment, and in particular relates to a PVD two-color wire drawing treatment method on the surface of a workpiece. Background technique [0002] With the improvement of people's living standards, consumer products industries such as household appliances, automobiles, and electronics have developed rapidly. At the same time, people have also put forward diversified demands on the appearance of products. It is an essential element of sales, and greatly increases the added value of various products. At present, products with an antique two-color appearance are popular year by year at home and abroad, especially in the high-end product market. [0003] The antique surface treatment of the product mainly adopts the process of electroplating brass, copper, or bronze on the surface of the product to form a dark brown oxide film, and then using wire drawing technology to destroy part of the dark brown ...

Claims

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Application Information

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IPC IPC(8): C23C14/35C23C14/06C23C14/58
Inventor 张栋汪爱英柯培玲孙丽丽
Owner NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI
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