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Rare-earth-ion-doped LiLaCl4 microcrystalline glass and preparation method thereof

A technology of glass-ceramics and rare-earth ions, which is applied in the field of rare-earth-ion-doped LiLaCl4 glass-ceramics and its preparation, can solve problems such as difficulty in growing large-sized crystals, affecting practical applications, and deliquescent crystals, achieving superior scintillation performance, Low production cost and good mechanical properties

Active Publication Date: 2014-07-30
湖州优研知识产权服务有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Scintillation crystals generally have the advantages of radiation resistance, fast decay, and high light output, but scintillation crystals also have the following serious disadvantages: difficult to prepare, expensive
But LiLaCl 4 The crystal is easy to deliquescence, the mechanical properties are poor, and it is easy to be cleaved into flakes. It is difficult to grow large-sized crystals, and the high price affects its practical application.

Method used

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  • Rare-earth-ion-doped LiLaCl4 microcrystalline glass and preparation method thereof
  • Rare-earth-ion-doped LiLaCl4 microcrystalline glass and preparation method thereof
  • Rare-earth-ion-doped LiLaCl4 microcrystalline glass and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Embodiment 1: Table 1 shows the glass formula and the first crystallization temperature value of Embodiment 1.

[0024] Table 1

[0025]

[0026] The specific preparation process is as follows: in the first step, weigh 50 grams of analytically pure raw materials according to the formula in Table 1, add 3 grams of NH 4 HF 2 , 3 g NH 4 HCl 2 , Mix the raw materials evenly and pour them into a quartz crucible to melt. The melting temperature is 1300°C and keep warm for 2 hours. Hours later, cool down to 50°C at a rate of 10°C / hour, turn off the power supply of the muffle furnace to automatically cool down to room temperature, and take out the glass; in the second step, according to the experimental data of thermal analysis (DTA) of the glass, the first crystallization temperature of 715 ℃, heat-treat the prepared glass in a precision annealing furnace in nitrogen at 734°C for 7 hours, then cool down to 50°C at a rate of 5°C / hour, turn off the power of the precision...

Embodiment 2

[0028] Embodiment 2: Table 2 shows the glass formula and the first crystallization temperature value of Embodiment 2.

[0029] Table 2

[0030]

[0031] The specific preparation process is as follows: in the first step, weigh 50 grams of analytically pure raw materials according to the formula in Table 2, add 3 grams of NH 4 HF 2 , 3 g NH 4 HCl 2, Mix the raw materials evenly and pour them into a corundum crucible for melting, the melting temperature is 1450°C, keep warm for 1 hour, pour the glass melt into a cast iron mold, then place it in a muffle furnace for annealing, and keep warm at the glass transition temperature Tg for 2 Hours later, cool down to 50°C at a rate of 10°C / hour, turn off the power supply of the muffle furnace to automatically cool down to room temperature, and take out the glass; in the second step, according to the glass thermal analysis (DTA) experimental data, the first crystallization temperature of 717 ℃, heat-treat the prepared glass in a p...

Embodiment 3

[0033] Embodiment 3: Table 3 shows the glass formula and the first crystallization temperature value of Embodiment 3.

[0034] table 3

[0035]

[0036] The specific preparation process is as follows: in the first step, weigh 50 grams of analytically pure raw materials according to the formula in Table 3, add 3 grams of NH 4 HF 2 , 3 g NH 4 HCl 2 , Mix the raw materials evenly and pour them into a quartz crucible to melt, the melting temperature is 1400°C, keep warm for 1.5 hours, pour the glass melt into a cast iron mold, then place it in a muffle furnace for annealing, and keep warm at the glass transition temperature Tg for 2 Hours later, the temperature was lowered to 50° C. at a rate of 10° C. / hour, the power of the muffle furnace was turned off and the temperature was automatically lowered to room temperature, and the glass was taken out. In the second step, according to the glass thermal analysis (DTA) experimental data, the first crystallization temperature is ...

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Abstract

The invention discloses a rare-earth-ion-doped LiLaCl4 microcrystalline glass and a preparation method thereof. The microcrystalline glass is composed of the following components in percentage by mole: 35-45 mol% of P2O5, 15-23 mol% of Nb2O5, 16-24 mol% of SrF2, 15-20 mol% of LiLaCl4 and 1-4 mol% of LnCl3. The LnCl3 is CeCl3, EuCl3, TbCl3, PrCl3 or NdCl3. The preparation method comprises the following steps: preparing P2O5-Nb2O5-SrF2-LiLaCl4-LnCl3 glass by a fusion process, and carrying out heat treatment to obtain the transparent LiLaCl4 microcrystalline glass. The LiLaCl4 microcrystalline glass has the advantages of deliquescence resistance, favorable mechanical properties, higher short-wavelength blue-violet light transmission rate, strong light output, quick attenuation, favorable energy resolution, favorable time resolution and the like. The preparation method of the microcrystalline glass is simple and lower in production cost.

Description

technical field [0001] The present invention relates to a rare earth ion doped glass ceramics, in particular to a rare earth ion doped LiLaCl used as a scintillation material 4 Glass-ceramic and its preparation method. Background technique [0002] Scintillation material is a light functional material that can emit visible light under the excitation of high-energy rays (such as x-rays, γ-rays) or other radioactive particles. It is widely used in nuclear medicine diagnosis, high-energy physics and nuclear physics experimental research, industry and geology. exploration and other fields. Depending on the application field, the requirements for scintillators are also different, but in general scintillator materials should have the following characteristics: high luminous efficiency, fast fluorescence decay, high density, low cost and good radiation resistance. Scintillation crystals generally have the advantages of radiation resistance, fast decay, and high light output, but ...

Claims

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Application Information

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IPC IPC(8): C03C10/16
Inventor 王倩张约品夏海平杨斌张为欢欧阳绍业
Owner 湖州优研知识产权服务有限公司
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