Aluminum-carbon-copper microelectrolysis filler and preparation method thereof

A production method and micro-electrolysis technology, applied in chemical instruments and methods, water/sewage treatment, water/sludge/sewage treatment, etc., can solve the problems of poor sewage treatment effect, long time, heavy workload, etc. Achieve the effect of not easy to be lost with water flow, large specific surface area and strong processing capacity

Inactive Publication Date: 2014-08-13
TIANJIN RUNJIE INNOVATION ENVIRONMENTAL PROTECTION TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Traditionally, the micro-electrolysis materials used in the micro-electrolysis process are generally iron filings and charcoal, which need to be activated by adding acid and alkali before use, and it is easy to passivate and harden during use , and because iron and carbon are in physical contact, it is easy to form an isolation layer between them, so that the micro-electrolysis cannot continue and loses its effect. efficiency
In addition, the small surface area of ​​traditional micro-electrolytic materials also makes it take a long time for wastewater treatment, which increases the investment cost per ton of water. Although the block micro-electrolytic fillers made of iron powder and carbon powder that appeared later can make up for the above-mentioned defects of micro-electrolytic fillers, However, the treatment effect on sewage and wastewater with complex components is not good, which seriously affects the utilization and promotion of micro-electrolysis technology.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0053] A preparation method of aluminum-carbon-copper micro-electrolytic filler, comprising the following steps:

[0054] (i) Treatment of activated carbon raw materials

[0055] 35kg of activated carbon raw materials were pulverized and ball milled to a powder with a particle size of 0.5 mm;

[0056] (ii) Mixing of activated carbon and aluminum powder

[0057] Add 50kg of aluminum powder and 15kg of copper powder with a particle size of 100 mesh to the powdered activated carbon raw material, so that the activated carbon raw material is fully mixed with the aluminum powder and copper powder;

[0058] (ⅲ) Stamping

[0059]Add the mixture obtained in step (ii) into the mould, and use a press to press the mixture into spherical particles with a particle size of 10mm under a pressure of 500MPa~1000Mpa;

[0060] (ⅳ) Carbonization and activation of activated carbon raw materials

[0061] Dry the spherical particles obtained in step (Ⅲ) at 300°C to carbonize the active carbon raw...

Embodiment 2

[0063] A preparation method of aluminum-carbon-copper micro-electrolytic filler, comprising the following steps:

[0064] (i) Treatment of activated carbon raw materials

[0065] 50kg of activated carbon raw material is pulverized and ball milled to a powder with a particle size of 0.8mm;

[0066] (ii) Mixing of activated carbon and aluminum powder

[0067] Add 40kg aluminum powder and 10kg copper powder with a particle size of 200 mesh to the powdered activated carbon raw material, so that the activated carbon raw material is fully mixed with the aluminum powder and copper powder;

[0068] (ⅲ) Stamping

[0069] Add the mixture obtained in step (ii) into the mold, and use a press to punch the mixture into elliptical particles with a particle size of 20mm under a pressure of 500MPa~1000Mpa;

[0070] (ⅳ) Carbonization and activation of activated carbon raw materials

[0071] Dry the elliptical particles obtained in step (Ⅲ) at 300°C to carbonize the activated carbon raw mate...

Embodiment 3

[0073] A preparation method of aluminum-carbon-copper micro-electrolytic filler, comprising the following steps:

[0074] (i) Treatment of activated carbon raw materials

[0075] Grinding and ball milling 60kg of activated carbon raw material to a powder with a particle size of 1.0 mm;

[0076] (ii) Mixing of activated carbon with aluminum powder and copper powder

[0077] Add 35kg of aluminum powder and 5kg of copper powder with a particle size of 300 meshes to the powdered activated carbon raw material to fully mix the activated carbon raw material with the aluminum powder and copper powder;

[0078] (ⅲ) Stamping

[0079] Add the mixture obtained in step (ii) into the mold, and use a press to punch the mixture into hollow columnar particles with a particle size of 30mm under a pressure of 500MPa~1000Mpa;

[0080] (ⅳ) Carbonization and activation of activated carbon raw materials

[0081] Dry the hollow columnar particles obtained in step (iii) at 300°C to carbonize the a...

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Abstract

The invention discloses an aluminum-carbon-copper microelectrolysis filler and a preparation method thereof. The preparation method comprises the following steps: (I) treatment of an active carbon raw material; (II) mixing of active carbon, aluminum powder and copper powder; (III) press forming; and (IV) carbonization and activation of the active carbon raw material. The invention provides the preparation method of the aluminum-carbon-copper microelectrolysis filler; compared with a method of directly using carbon granules and aluminum granules as fillers, the method for preparing the aluminum-carbon-copper microelectrolysis filler is not influenced by different specific gravities and has the advantage that aluminum, copper and carbon are in mutual surface contact maximally; compared with a method for directly using the carbon granules and aluminum and copper granules as the fillers, the method for preparing the aluminum-carbon-copper microelectrolysis filler has the advantages of large quantity of primary cells formed by the fillers with same volume, high generated microcurrent and high processing capacity; and furthermore, the aluminum-carbon-copper microelectrolysis filler prepared through the method disclosed by the invention is in a block shape, stable in character and difficult to lose along with water flows.

Description

technical field [0001] The invention belongs to the field of waste water or sewage treatment, and in particular relates to an aluminum-carbon-copper micro-electrolytic filler and a preparation method thereof. Background technique [0002] Micro-electrolysis technology is currently an ideal process for treating high-concentration organic wastewater, also known as internal electrolysis. It uses the micro-electrolytic material filled in the wastewater to generate a 1.2V potential difference to electrolyze the wastewater to degrade organic pollutants without electricity. [0003] The working principle of micro-electrolysis technology is: when the system passes water, countless micro-battery systems will be formed in the device, forming an electric field in its action space. The new ecological [H] , Fe produced in the process 2+ It can undergo oxidation-reduction reactions with many components in wastewater, such as chromophoric groups or auxochromic groups that can destroy co...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/461
Inventor 郝聿铭郝守余
Owner TIANJIN RUNJIE INNOVATION ENVIRONMENTAL PROTECTION TECH
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