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High-performance metal ceramic cladding material and preparation method thereof

A technology of cermets and cladding materials, which is applied in the field of wear resistance and corrosion resistance, can solve the problems of expensive equipment, large investment, and no reports, and achieve the effect of good metallurgical bonding, high bonding strength, and low manufacturing cost

Inactive Publication Date: 2014-08-13
XIANGTAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But for Mo 2 NiB 2 The study of ternary boride coating has not been reported yet
[0004] At present, the main methods of coating include thermal spraying, vapor deposition, laser cladding and other preparation technologies. Although the coatings prepared by these processes effectively improve the hardness, wear resistance and corrosion resistance of the metal substrate surface, but The preparation process is complicated, the equipment is expensive, and the investment is relatively large

Method used

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  • High-performance metal ceramic cladding material and preparation method thereof
  • High-performance metal ceramic cladding material and preparation method thereof
  • High-performance metal ceramic cladding material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] The raw material composition of the coating of table 1 embodiment 1

[0027]

[0028] The main performance of table 2 embodiment 1 cladding material

[0029]

[0030] The composition of coating materials is shown in Table 1. All the raw materials are mixed according to the ratio in Table 1 to form a mixture and then added to the ball mill tank to form a mixture of 40% dehydrated ethanol and 5% polyethylene glycol in the weight ratio of the above mixture. The liquid is the ball milling medium, the stainless steel ball is the ball, the ball to material ratio is 6:1, and the ball is milled for 12 hours. After the slurry is passed through a 100 mesh sieve, it is brushed on the surface of the purified metal substrate (Q235 steel). After a little drying, it is directly placed Sintering in a vacuum furnace with a heating rate of 4°C / min in the low-temperature stage and 8°C / min in the high-temperature stage. After holding at 1260°C for 30 minutes, it is cooled to room te...

Embodiment 2

[0032] The raw material composition of the cladding of table 3 embodiment 2

[0033]

[0034] Table 4 embodiment 2 main properties of cladding material

[0035]

[0036] The composition of coating materials is shown in Table 3. Each raw material is matched with the ratio in Table 3 to form a mixture and then added to the ball mill tank. The absolute ethanol that accounts for 30% of the above mixture by weight is used as a ball mill medium, and cemented carbide balls are grinding balls. The ball-to-material ratio is 3: 1. Ball milled for 24 hours, the resulting slurry was dried in a vacuum oven at 85°C for 5 hours, passed through a 200-mesh sieve, and pressed into a unidirectional rigid mold with a molding pressure of 350MPa and a holding time of 0.5 minutes, and then the green body was stacked Press it on the surface of the metal substrate coated with PVA glue, and finally sinter the obtained sample in a vacuum furnace. The temperature rise rate is 4.5°C / min in the temp...

Embodiment 3

[0038] The raw material composition of the cladding of table 5 embodiment 3

[0039]

[0040] The main performance of table 6 embodiment 3 cladding material

[0041]

[0042] The composition of coating materials is shown in Table 5. Each raw material is matched with the ratio in Table 5 to form a mixture and then added to the ball mill tank. The absolute ethanol that accounts for 50% of the above mixture by weight is used as a ball mill medium, and cemented carbide balls are grinding balls. The ball-to-material ratio is 4: 1. Ball milled for 24 hours, the resulting slurry was dried in a vacuum oven at 80°C for 8 hours, passed through a 200-mesh sieve, and pressed into a one-way rigid mold with a molding pressure of 400 MPa and a holding time of 2 minutes, and then the green body was stacked Press it on the surface of the metal substrate coated with PVA glue, and finally sinter the obtained sample in a vacuum furnace. The temperature rise rate is 4.5°C / min in the tempera...

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Abstract

The invention relates to a high-performance metal ceramic cladding material and a preparation method thereof. The high-performance metal ceramic cladding material disclosed by the invention comprises the following components in mass percentage: 45-65% of Mo, 30-50% of Ni, 4.5-6.5% of B, 0-5% of V, 0.1-0.8% of C, and 0-1.5% of Mo2C. The preparation method of the high-performance metal ceramic cladding material disclosed by the invention comprises the following steps: weighing the mixture of the components according to the mass percentage, then, carrying out ball-milling and mixing by adding absolute ethyl alcohol the weight of which is 30-50% of that of the mixture, after drying and sieving through a 200-mesh sieve, pressing and forming, adhering, and carrying out liquid-phase sintering; or, weighing the mixture of the components according to the mass percentage, then, carrying out ball-milling and mixing by adding an organic additive the weight of which is 35-55% of that of the mixture, after sieving slurry through a 100-mesh sieve, brush-coating the slurry on a metal substrate, then, drying, and carrying out liquid-phase sintering. The preparation method disclosed by the invention is simple in process, lower in cost and convenient for operation; a cladding layer is firmly combined with the metal substrate; the thickness of the cladding layer can achieve 10 mm; the high-performance metal ceramic cladding material disclosed by the invention can be widely applied in the fields, such as wear resistance and corrosion resistance.

Description

technical field [0001] The invention relates to a ternary boride high-performance cermet cladding material and a preparation method thereof, which are mainly used in the field of wear resistance and corrosion resistance. Background technique [0002] With the development of industrial technology and the high speed and high precision of equipment, products are required to have a long life and higher wear resistance and corrosion resistance. Borides have a high melting point, high hardness, and stable chemical properties. They are favorable candidates for wear-resistant and corrosion-resistant materials. However, due to the low sinterability of binary borides, the development and application of binary borides are limited. Japanese scholars have successfully prepared ternary boride cermets by in-situ reaction liquid phase sintering method. This material not only has high hardness, but also has good corrosion resistance. It is a new type of wear-resistant and corrosion-resistant...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C19/03C22C27/04C22C30/00B22F7/02
Inventor 谢浪李小波高小庆易理
Owner XIANGTAN UNIV