Alkylene fluorene and thieno[3, 4-b]pyrazine containing polymer, preparation method thereof and organic solar cell
A technology containing alkylene fluorene and polymer, applied in the field of optoelectronic materials, can solve problems such as low conversion efficiency
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Embodiment 1
[0070] A polymer containing alkylene fluorene and thieno[3,4-b]pyrazine, denoted as polymer P1 (n=10), the structural formula is as follows:
[0071]
[0072] The preparation steps of P1 are as follows:
[0073] (1) Preparation of 2,7-dibromo-9-bis(thiomethyl)methylenefluorene (compound D1):
[0074]
[0075] At room temperature under the protection of nitrogen, add 1L of anhydrous dimethyl sulfoxide (DMSO) dissolved in 2,7-dibromofluorene (48.6g, 0.15mol) into the reaction flask, and add it under the condition of uniform stirring (33.6g, 0.30mol) Potassium tert-butoxide, then inject (9mL, 0.15mol) carbon disulfide with a syringe and stir for 10 minutes, then slowly add 0.15mol, 9.3mL methyl iodide with a dropping funnel for 5 minutes and then continue The reaction was stirred for 4 hours. After the reaction, the resultant was poured into an ice-water mixture, and then 2 mL of concentrated ammonia water was added to remove unreacted methyl iodide. Then filter, wash th...
Embodiment 2
[0088] A polymer containing alkylene fluorene and thieno[3,4-b]pyrazine, denoted as polymer P2 (n=100), the structural formula is as follows:
[0089]
[0090] The preparation steps of P2 are as follows:
[0091] (1) Preparation of 2,7-dibromo-9-bis(thiomethyl)methylenefluorene:
[0092] The specific operation is basically the same as in Example 1, except that the molar weight of 2,7-dibromofluorene is 0.3mol, 97.2g, and the molar weight of potassium tert-butoxide is 0.72mol, 80.6g; the molar weight of carbon disulfide 0.36mol, 21.7mL, and stirred and reacted for 20 minutes; and the molar amount of 0.36mol, 22.4mL of methyl iodide was added dropwise with a dropping funnel for 10 minutes, and then stirred and reacted for 6 hours.
[0093] (2) Preparation of 2,7-dibromo-9-bis(2-ethylhexyl)methylenefluorene (compound C2):
[0094]
[0095] Under the condition of -5°C and nitrogen protection, take 0.02mol prepared in step 1 reaction, 8.56g 2,7-dibromo-9-bis(thiomethyl)meth...
Embodiment 3
[0105] A polymer containing alkylene fluorene and thieno[3,4-b]pyrazine, denoted as polymer P3 (n=71), the structural formula is as follows:
[0106]
[0107] (1) Preparation of 2,7-dibromo-9-bis(thiomethyl)methylenefluorene:
[0108] The specific operation is basically the same as in Example 1, except that the molar weight of 2,7-dibromofluorene is 0.02mol (6.48g), the molar weight of potassium tert-butoxide is 0.044mol (4.928g); The molar weight is 0.022 mol (1.3 mL), and the reaction is stirred for 15 minutes; and the molar weight of 0.022 mol (1.4 mL) of methyl iodide is added dropwise for 8 minutes with a dropping funnel, and the reaction is stirred for 5 hours.
[0109] (2) Preparation of 2,7-dibromo-9-dibutylmethylenefluorene (compound C3):
[0110]
[0111] Under the condition of -8°C and nitrogen protection, take the 2,7-dibromo-9-bis(thiomethyl)methylene fluorene (0.02mol, 8.56g) prepared in step 1 reaction and dissolve it in 150mL of anhydrous THF solvent an...
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